Berkelium is a
synthetic chemical element; it has
symbol
A symbol is a mark, Sign (semiotics), sign, or word that indicates, signifies, or is understood as representing an idea, physical object, object, or wikt:relationship, relationship. Symbols allow people to go beyond what is known or seen by cr ...
Bk and
atomic number
The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of its atomic nucleus. For ordinary nuclei composed of protons and neutrons, this is equal to the proton number (''n''p) or the number of pro ...
97. It is a member of the
actinide
The actinide () or actinoid () series encompasses at least the 14 metallic chemical elements in the 5f series, with atomic numbers from 89 to 102, actinium through nobelium. Number 103, lawrencium, is also generally included despite being part ...
and
transuranium element series. It is named after the city of
Berkeley, California
Berkeley ( ) is a city on the eastern shore of San Francisco Bay in northern Alameda County, California, United States. It is named after the 18th-century Anglo-Irish bishop and philosopher George Berkeley. It borders the cities of Oakland, Cali ...
, the location of the
Lawrence Berkeley National Laboratory
Lawrence Berkeley National Laboratory (LBNL, Berkeley Lab) is a Federally funded research and development centers, federally funded research and development center in the Berkeley Hills, hills of Berkeley, California, United States. Established i ...
(then the
University of California
The University of California (UC) is a public university, public Land-grant university, land-grant research university, research university system in the U.S. state of California. Headquartered in Oakland, California, Oakland, the system is co ...
Radiation Laboratory) where it was discovered in December 1949. Berkelium was the fifth
transuranium element discovered after
neptunium
Neptunium is a chemical element; it has chemical symbol, symbol Np and atomic number 93. A radioactivity, radioactive actinide metal, neptunium is the first transuranic element. It is named after Neptune, the planet beyond Uranus in the Solar Syste ...
,
plutonium
Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four ...
,
curium and
americium
Americium is a synthetic element, synthetic chemical element; it has Chemical symbol, symbol Am and atomic number 95. It is radioactive and a transuranic member of the actinide series in the periodic table, located under the lanthanide element e ...
.
The major
isotope
Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their Atomic nucleus, nuclei) and position in the periodic table (and hence belong to the same chemica ...
of berkelium,
249Bk, is synthesized in minute quantities in dedicated high-flux
nuclear reactor
A nuclear reactor is a device used to initiate and control a Nuclear fission, fission nuclear chain reaction. They are used for Nuclear power, commercial electricity, nuclear marine propulsion, marine propulsion, Weapons-grade plutonium, weapons ...
s, mainly at the
Oak Ridge National Laboratory
Oak Ridge National Laboratory (ORNL) is a federally funded research and development centers, federally funded research and development center in Oak Ridge, Tennessee, United States. Founded in 1943, the laboratory is sponsored by the United Sta ...
in
Tennessee
Tennessee (, ), officially the State of Tennessee, is a landlocked U.S. state, state in the Southeastern United States, Southeastern region of the United States. It borders Kentucky to the north, Virginia to the northeast, North Carolina t ...
, United States, and at the
Research Institute of Atomic Reactors in
Dimitrovgrad, Russia
Dimitrovgrad (; ), formerly Melekkes, Melekes, and Melekess (; ; ) until 1972, is a city in Ulyanovsk Oblast, Russia. It is the administrative center of Melekessky District, although it is not within the district and is an independent city. Th ...
. The longest-lived and second-most important isotope,
247Bk, can be synthesized via irradiation of
244Cm with high-energy
alpha particle
Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay but may also be produce ...
s.
Just over one gram of berkelium has been produced in the United States since 1967. There is no practical application of berkelium outside scientific research which is mostly directed at the synthesis of heavier
transuranium elements and
superheavy element
Superheavy elements, also known as transactinide elements, transactinides, or super-heavy elements, or superheavies for short, are the chemical elements with atomic number greater than 104. The superheavy elements are those beyond the actinides in ...
s. A 22-milligram batch of berkelium-249 was prepared during a 250-day irradiation period and then purified for a further 90 days at Oak Ridge in 2009. This sample was used to synthesize the new element
tennessine
Tennessine is a synthetic element; it has Chemical symbol, symbol Ts and atomic number 117. It has the second-highest atomic number and joint-highest atomic mass of all known elements and is the penultimate element of the Period 7 element, 7th ...
for the first time in 2009 at the
Joint Institute for Nuclear Research,
Russia
Russia, or the Russian Federation, is a country spanning Eastern Europe and North Asia. It is the list of countries and dependencies by area, largest country in the world, and extends across Time in Russia, eleven time zones, sharing Borders ...
, after it was bombarded with
calcium-48 ions for 150 days. This was the culmination of the Russia–US collaboration on the synthesis of the heaviest elements on the periodic table.
Berkelium is a soft, silvery-white,
radioactive
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...
metal. The berkelium-249 isotope emits low-energy
electron
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
s and thus is relatively safe to handle. It decays with a
half-life Half-life is a mathematical and scientific description of exponential or gradual decay.
Half-life, half life or halflife may also refer to:
Film
* Half-Life (film), ''Half-Life'' (film), a 2008 independent film by Jennifer Phang
* ''Half Life: ...
of 330 days to
californium
Californium is a synthetic chemical element; it has symbol Cf and atomic number 98. It was first synthesized in 1950 at Lawrence Berkeley National Laboratory (then the University of California Radiation Laboratory) by bombarding curium with al ...
-249, which is a strong emitter of ionizing alpha particles. This gradual transformation is an important consideration when studying the properties of elemental berkelium and its chemical compounds, since the formation of californium brings not only chemical contamination, but also free-radical effects and self-heating from the emitted alpha particles.
Characteristics
Physical

Berkelium is a soft, silvery-white, radioactive
actinide
The actinide () or actinoid () series encompasses at least the 14 metallic chemical elements in the 5f series, with atomic numbers from 89 to 102, actinium through nobelium. Number 103, lawrencium, is also generally included despite being part ...
metal. In the
periodic table
The periodic table, also known as the periodic table of the elements, is an ordered arrangement of the chemical elements into rows (" periods") and columns (" groups"). It is an icon of chemistry and is widely used in physics and other s ...
, it is located to the right of the actinide
curium, to the left of the actinide
californium
Californium is a synthetic chemical element; it has symbol Cf and atomic number 98. It was first synthesized in 1950 at Lawrence Berkeley National Laboratory (then the University of California Radiation Laboratory) by bombarding curium with al ...
and below the lanthanide
terbium
Terbium is a chemical element; it has Symbol (chemistry), symbol Tb and atomic number 65. It is a silvery-white, rare earth element, rare earth metal that is malleable and ductile. The ninth member of the lanthanide series, terbium is a fairly ele ...
with which it shares many similarities in physical and chemical properties. Its density of 14.78 g/cm
3 lies between those of curium (13.52 g/cm
3) and californium (15.1 g/cm
3), as does its melting point of 986 °C, below that of curium (1340 °C) but higher than that of californium (900 °C).
Berkelium is relatively soft and has one of the lowest
bulk moduli among the actinides, at about 20
GPa (2 Pa).
ions shows two sharp
fluorescence
Fluorescence is one of two kinds of photoluminescence, the emission of light by a substance that has absorbed light or other electromagnetic radiation. When exposed to ultraviolet radiation, many substances will glow (fluoresce) with colore ...
peaks at 652
nanometer
330px, Different lengths as in respect to the Molecule">molecular scale.
The nanometre (international spelling as used by the International Bureau of Weights and Measures; SI symbol: nm), or nanometer (American spelling
Despite the va ...
s (red light) and 742 nanometers (deep red –
near-infrared
Infrared (IR; sometimes called infrared light) is electromagnetic radiation (EMR) with wavelengths longer than that of visible light but shorter than microwaves. The infrared spectral band begins with the waves that are just longer than those of ...
) due to internal transitions at the
f-electron shell. The relative intensity of these peaks depends on the excitation power and temperature of the sample. This emission can be observed, for example, after dispersing berkelium ions in a silicate glass, by melting the glass in presence of berkelium oxide or halide.
Between 70 K and room temperature, berkelium behaves as a
Curie–Weiss paramagnetic material with an effective magnetic moment of 9.69
Bohr magneton
In atomic physics, the Bohr magneton (symbol ) is a physical constant and the natural unit for expressing the magnetic moment of an electron caused by its orbital or spin angular momentum.
In SI units, the Bohr magneton is defined as
\mu_\mat ...
s (μ
B) and a
Curie temperature of 101 K. This magnetic moment is almost equal to the theoretical value of 9.72 μ
B calculated within the simple atomic
L-S coupling model. Upon cooling to about 34 K, berkelium undergoes a transition to an
antiferromagnetic state. The
enthalpy of dissolution in
hydrochloric acid
Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is ...
at standard conditions is −600 kJ/mol, from which the
standard enthalpy of formation (Δ
f''H''°) of aqueous ions is obtained as −601 kJ/mol. The
standard electrode potential
In electrochemistry, standard electrode potential E^\ominus, or E^\ominus_, is the electrode potential (a measure of the reducing power of any element or compound) which the IUPAC "Gold Book" defines as ''"the value of the standard emf ( electrom ...
/Bk is −2.01 V. The
ionization potential
In physics and chemistry, ionization energy (IE) is the minimum energy required to remove the most loosely bound electron of an isolated gaseous atom, positive ion, or molecule. The first ionization energy is quantitatively expressed as
:X(g) ...
of a neutral berkelium atom is 6.23 eV.
Allotropes
At ambient conditions, berkelium assumes its most stable α form which has a
hexagonal
In geometry, a hexagon (from Greek , , meaning "six", and , , meaning "corner, angle") is a six-sided polygon. The total of the internal angles of any simple (non-self-intersecting) hexagon is 720°.
Regular hexagon
A regular hexagon is d ...
symmetry,
space group
In mathematics, physics and chemistry, a space group is the symmetry group of a repeating pattern in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of the pattern that ...
''P6
3/mmc'', lattice parameters of 341
pm and 1107 pm. The crystal has a double-
hexagonal close packing structure with the layer sequence ABAC and so is
isotypic (having a similar structure) with α-lanthanum and α-forms of actinides beyond curium.
This crystal structure changes with pressure and temperature. When compressed at room temperature to 7 GPa, α-berkelium transforms to the β modification, which has a
face-centered cubic
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.
There are three main varieties o ...
(''fcc'') symmetry and space group ''Fmm''. This transition occurs without change in volume, but the
enthalpy
Enthalpy () is the sum of a thermodynamic system's internal energy and the product of its pressure and volume. It is a state function in thermodynamics used in many measurements in chemical, biological, and physical systems at a constant extern ...
increases by 3.66 kJ/mol. Upon further compression to 25 GPa, berkelium transforms to an
orthorhombic
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic Lattice (group), lattices result from stretching a cubic crystal system, cubic lattice along two of its orthogonal pairs by two different factors, res ...
γ-berkelium structure similar to that of α-uranium. This transition is accompanied by a 12% volume decrease and delocalization of the electrons at the
5f electron shell.
No further phase transitions are observed up to 57 GPa.
Upon heating, α-berkelium transforms into another phase with an ''fcc'' lattice (but slightly different from β-berkelium), space group ''Fmm'' and the
lattice constant of 500 pm; this ''fcc'' structure is equivalent to the closest packing with the sequence ABC. This phase is metastable and will gradually revert to the original α-berkelium phase at
room temperature.
The temperature of the
phase transition
In physics, chemistry, and other related fields like biology, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic Sta ...
is believed to be quite close to the melting point.
Chemical
Like all
actinide
The actinide () or actinoid () series encompasses at least the 14 metallic chemical elements in the 5f series, with atomic numbers from 89 to 102, actinium through nobelium. Number 103, lawrencium, is also generally included despite being part ...
s, berkelium dissolves in various aqueous inorganic acids, liberating gaseous
hydrogen
Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
and converting into the state. This
trivalent oxidation state
In chemistry, the oxidation state, or oxidation number, is the hypothetical Electrical charge, charge of an atom if all of its Chemical bond, bonds to other atoms are fully Ionic bond, ionic. It describes the degree of oxidation (loss of electrons ...
(+3) is the most stable, especially in aqueous solutions, but
tetravalent (+4),
pentavalent (+5),
and possibly
divalent
In chemistry, the valence (US spelling) or valency (British spelling) of an atom is a measure of its combining capacity with other atoms when it forms chemical compounds or molecules. Valence is generally understood to be the number of chemica ...
(+2) berkelium compounds are also known. The existence of divalent berkelium salts is uncertain and has only been reported in mixed
lanthanum(III) chloride-
strontium chloride
Strontium chloride (SrCl2) is a salt of strontium and chloride. It is a "typical" salt, forming neutral aqueous solutions. As with all compounds of strontium, this salt emits a bright red colour in flame, and is commonly used in fireworks to that ...
melts. A similar behavior is observed for the lanthanide analogue of berkelium,
terbium
Terbium is a chemical element; it has Symbol (chemistry), symbol Tb and atomic number 65. It is a silvery-white, rare earth element, rare earth metal that is malleable and ductile. The ninth member of the lanthanide series, terbium is a fairly ele ...
.
Aqueous solutions of ions are green in most acids. The color of ions is yellow in
hydrochloric acid
Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is ...
and orange-yellow in
sulfuric acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ...
. Berkelium does not react rapidly with
oxygen
Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
at room temperature, possibly due to the formation of a protective oxide layer surface. However, it reacts with molten metals,
hydrogen
Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
,
halogen
The halogens () are a group in the periodic table consisting of six chemically related elements: fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and the radioactive elements astatine (At) and tennessine (Ts), though some authors would ...
s,
chalcogen
The chalcogens (ore forming) ( ) are the chemical elements in group 16 of the periodic table. This group is also known as the oxygen family. Group 16 consists of the elements oxygen (O), sulfur (S), selenium (Se), tellurium (Te), and the rad ...
s and
pnictogen
, -
! colspan=2 style="text-align:left;" , ↓ Period
, -
! 2
,
, -
! 3
,
, -
! 4
,
, -
! 5
,
, -
! 6
,
, -
! 7
,
, -
, colspan="2",
----
''Legend''
A pnictogen ( or ; from "to choke" and -gen, "generator") is any ...
s to form various binary compounds.
In 2025 an
organometallic
Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkali, alkaline earth, and transition metals, and so ...
compound containing berkelium was synthesized from 0.3 mg of berkelium and named berkelocene.
Isotopes
Nineteen isotopes and six
nuclear isomer
A nuclear isomer is a metastable state of an atomic nucleus, in which one or more nucleons (protons or neutrons) occupy excited state levels (higher energy levels). "Metastable" describes nuclei whose excited states have Half-life, half-lives of ...
s (excited states of an isotope) of berkelium have been characterized, with mass numbers ranging from 233 to 253 (except 235 and 237).
All of them are radioactive. The longest
half-lives are observed for
247Bk (1,380 years),
248Bk (over 300 years), and
249Bk (330 days); the half-lives of the other isotopes range from microseconds to several days. The isotope which is the easiest to synthesize is berkelium-249. This emits mostly soft
β-particles which are inconvenient for detection. Its
alpha radiation
Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus). The parent nucleus transforms or "decays" into a daughter product, with a mass number that is reduced by four and an atom ...
is rather weak (1.45%) with respect to the β-radiation, but is sometimes used to detect this isotope. The second important berkelium isotope, berkelium-247, is an alpha-emitter, as are most actinide isotopes.
Occurrence
All berkelium isotopes have a half-life far too short to be
primordial. Therefore, any primordial berkelium − that is, berkelium present on the Earth during its formation − has decayed by now.
On Earth, berkelium is mostly concentrated in certain areas, which were used for the atmospheric
nuclear weapons tests between 1945 and 1980, as well as at the sites of nuclear incidents, such as the
Chernobyl disaster
On 26 April 1986, the no. 4 reactor of the Chernobyl Nuclear Power Plant, located near Pripyat, Ukrainian Soviet Socialist Republic, Ukrainian SSR, Soviet Union (now Ukraine), exploded. With dozens of direct casualties, it is one of only ...
,
Three Mile Island accident and
1968 Thule Air Base B-52 crash. Analysis of the debris at the testing site of the first
United States
The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...
' first
thermonuclear weapon
A thermonuclear weapon, fusion weapon or hydrogen bomb (H-bomb) is a second-generation nuclear weapon design. Its greater sophistication affords it vastly greater destructive power than first-generation nuclear bombs, a more compact size, a lowe ...
,
Ivy Mike
Ivy Mike was the code name, codename given to the first full-scale test of a Thermonuclear weapon, thermonuclear device, in which a significant fraction of the explosive nuclear weapon yield, yield comes from nuclear fusion.
Ivy Mike was detona ...
, (1 November 1952,
Enewetak Atoll), revealed high concentrations of various actinides, including berkelium. For reasons of military secrecy, this result was not published until 1956.
Nuclear reactors produce mostly, among the berkelium isotopes, berkelium-249. During the storage and before the fuel disposal, most of it
beta decay
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which an atomic nucleus emits a beta particle (fast energetic electron or positron), transforming into an isobar of that nuclide. For example, beta decay of a neutron ...
s to californium-249. The latter has a half-life of 351 years, which is relatively long compared to the half-lives of other isotopes produced in the reactor, and is therefore undesirable in the disposal products.
The
transuranium elements up to
fermium, including berkelium, should have been present in the
natural nuclear fission reactor at
Oklo, but no longer do so.
History

Although very small amounts of berkelium were possibly produced in previous nuclear experiments, it was
first intentionally synthesized, isolated and identified in December 1949 by
Glenn T. Seaborg,
Albert Ghiorso
Albert Ghiorso (July 15, 1915 – December 26, 2010) was an American nuclear scientist and co-discoverer of a record 12 chemical elements on the periodic table. His research career spanned six decades, from the early 1940s to the late 1990s.
Biog ...
,
Stanley Gerald Thompson, and
Kenneth Street Jr. They used the 60-inch
cyclotron
A cyclotron is a type of particle accelerator invented by Ernest Lawrence in 1929–1930 at the University of California, Berkeley, and patented in 1932. Lawrence, Ernest O. ''Method and apparatus for the acceleration of ions'', filed: Januar ...
at the
University of California, Berkeley
The University of California, Berkeley (UC Berkeley, Berkeley, Cal, or California), is a Public university, public Land-grant university, land-grant research university in Berkeley, California, United States. Founded in 1868 and named after t ...
. Similar to the nearly simultaneous discovery of
americium
Americium is a synthetic element, synthetic chemical element; it has Chemical symbol, symbol Am and atomic number 95. It is radioactive and a transuranic member of the actinide series in the periodic table, located under the lanthanide element e ...
(element 95) and
curium (element 96) in 1944, the new elements berkelium and
californium
Californium is a synthetic chemical element; it has symbol Cf and atomic number 98. It was first synthesized in 1950 at Lawrence Berkeley National Laboratory (then the University of California Radiation Laboratory) by bombarding curium with al ...
(element 98) were both produced in 1949–1950.
[Abstract]
/ref>
The name choice for element 97 followed the previous tradition of the Californian group to draw an analogy between the newly discovered actinide
The actinide () or actinoid () series encompasses at least the 14 metallic chemical elements in the 5f series, with atomic numbers from 89 to 102, actinium through nobelium. Number 103, lawrencium, is also generally included despite being part ...
and the lanthanide element positioned above it in the periodic table
The periodic table, also known as the periodic table of the elements, is an ordered arrangement of the chemical elements into rows (" periods") and columns (" groups"). It is an icon of chemistry and is widely used in physics and other s ...
. Previously, americium was named after a continent as its analogue europium
Europium is a chemical element; it has symbol Eu and atomic number 63. It is a silvery-white metal of the lanthanide series that reacts readily with air to form a dark oxide coating. Europium is the most chemically reactive, least dense, and soft ...
, and curium honored scientists Marie and Pierre Curie
Pierre Curie ( ; ; 15 May 1859 – 19 April 1906) was a French physicist, Radiochemistry, radiochemist, and a pioneer in crystallography, magnetism, piezoelectricity, and radioactivity. He shared the 1903 Nobel Prize in Physics with his wife, ...
as the lanthanide above it, gadolinium
Gadolinium is a chemical element; it has Symbol (chemistry), symbol Gd and atomic number 64. It is a silvery-white metal when oxidation is removed. Gadolinium is a malleable and ductile rare-earth element. It reacts with atmospheric oxygen or moi ...
, was named after the explorer of the rare-earth elements Johan Gadolin. Thus, the discovery report by the Berkeley group reads: "It is suggested that element 97 be given the name berkelium (symbol Bk) after the city of Berkeley in a manner similar to that used in naming its chemical homologue terbium
Terbium is a chemical element; it has Symbol (chemistry), symbol Tb and atomic number 65. It is a silvery-white, rare earth element, rare earth metal that is malleable and ductile. The ninth member of the lanthanide series, terbium is a fairly ele ...
(atomic number 65) whose name was derived from the town of Ytterby
Ytterby () is a village on the Swedish island of Resarö, in Vaxholm Municipality in the Stockholm archipelago. Today the residential area is dominated by suburban homes.
The name of the village translates to "outer village". Ytterby is the ...
, Sweden
Sweden, formally the Kingdom of Sweden, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. It borders Norway to the west and north, and Finland to the east. At , Sweden is the largest Nordic count ...
, where the rare earth minerals were first found." This tradition ended with berkelium, though, as the naming of the next discovered actinide, californium
Californium is a synthetic chemical element; it has symbol Cf and atomic number 98. It was first synthesized in 1950 at Lawrence Berkeley National Laboratory (then the University of California Radiation Laboratory) by bombarding curium with al ...
, was not related to its lanthanide analogue dysprosium
Dysprosium is a chemical element; it has symbol Dy and atomic number 66. It is a rare-earth element in the lanthanide series with a metallic silver luster. Dysprosium is never found in nature as a free element, though, like other lanthanides, it ...
, but after the discovery place.
The most difficult steps in synthesising berkelium were its separation from the final products and the production of sufficient quantities of americium for the target material. First, americium ( 241Am) nitrate
Nitrate is a polyatomic ion with the chemical formula . salt (chemistry), Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. Almost all inorganic nitrates are solubility, soluble in wa ...
solution was coated on a platinum
Platinum is a chemical element; it has Symbol (chemistry), symbol Pt and atomic number 78. It is a density, dense, malleable, ductility, ductile, highly unreactive, precious metal, precious, silverish-white transition metal. Its name origina ...
foil, the solution was evaporated and the residue converted by annealing to americium dioxide (). This target was irradiated with 35 MeV alpha particle
Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay but may also be produce ...
s for 6 hours in the 60-inch cyclotron at the Lawrence Radiation Laboratory, University of California, Berkeley. The (α,2n) reaction induced by the irradiation yielded the 243Bk isotope and two free neutron
The neutron is a subatomic particle, symbol or , that has no electric charge, and a mass slightly greater than that of a proton. The Discovery of the neutron, neutron was discovered by James Chadwick in 1932, leading to the discovery of nucle ...
s:
: + → + 2
After the irradiation, the coating was dissolved with nitric acid
Nitric acid is an inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into nitrogen oxide, oxides of nitrogen. Most com ...
and then precipitated as the hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It ...
using concentrated aqueous ammonia solution. The product was centrifugated and re-dissolved in nitric acid. To separate berkelium from the unreacted americium, this solution was added to a mixture of aqueous ammonia
Ammonia is an inorganic chemical compound of nitrogen and hydrogen with the chemical formula, formula . A Binary compounds of hydrogen, stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinctive pu ...
and ammonium sulfate and heated in the presence of atmospheric oxygen to convert all the dissolved americium into the oxidation state
In chemistry, the oxidation state, or oxidation number, is the hypothetical Electrical charge, charge of an atom if all of its Chemical bond, bonds to other atoms are fully Ionic bond, ionic. It describes the degree of oxidation (loss of electrons ...
+6. Unoxidized residual americium was precipitated by the addition of hydrofluoric acid
Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. A common concentration is 49% (48–52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling p ...
as americium(III) fluoride
Fluoride (). According to this source, is a possible pronunciation in British English. is an Inorganic chemistry, inorganic, Monatomic ion, monatomic Ion#Anions and cations, anion of fluorine, with the chemical formula (also written ), whose ...
(). This step yielded a mixture of the accompanying product curium and the expected element 97 in form of trifluorides. The mixture was converted to the corresponding hydroxides by treating it with potassium hydroxide
Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash.
Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which utili ...
, and after centrifugation, was dissolved in perchloric acid.
Further separation was carried out in the presence of a citric acid
Citric acid is an organic compound with the formula . It is a Transparency and translucency, colorless Weak acid, weak organic acid. It occurs naturally in Citrus, citrus fruits. In biochemistry, it is an intermediate in the citric acid cycle, ...
/ammonium
Ammonium is a modified form of ammonia that has an extra hydrogen atom. It is a positively charged (cationic) polyatomic ion, molecular ion with the chemical formula or . It is formed by the protonation, addition of a proton (a hydrogen nucleu ...
buffer solution
A buffer solution is a solution where the pH does not change significantly on dilution or if an acid or base is added at constant temperature. Its pH changes very little when a small amount of strong acid or base is added to it. Buffer solution ...
in a weakly acidic medium , using ion exchange
Ion exchange is a reversible interchange of one species of ion present in an insoluble solid with another of like charge present in a solution surrounding the solid. Ion exchange is used in softening or demineralizing of water, purification of ch ...
at elevated temperature. The chromatographic separation behavior was unknown for element 97 at the time but was anticipated by analogy with terbium. The first results were disappointing because no alpha-particle emission signature could be detected from the elution product. With further analysis, searching for characteristic X-rays and conversion electron signals, a berkelium isotope was eventually detected. Its mass number
The mass number (symbol ''A'', from the German word: ''Atomgewicht'', "atomic weight"), also called atomic mass number or nucleon number, is the total number of protons and neutrons (together known as nucleons) in an atomic nucleus. It is appro ...
was uncertain between 243 and 244 in the initial report, but was later established as 243.
Synthesis and extraction
Preparation of isotopes
Berkelium is produced by bombarding lighter actinides uranium
Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...
(238U) or plutonium
Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four ...
(239Pu) with neutron
The neutron is a subatomic particle, symbol or , that has no electric charge, and a mass slightly greater than that of a proton. The Discovery of the neutron, neutron was discovered by James Chadwick in 1932, leading to the discovery of nucle ...
s in a nuclear reactor
A nuclear reactor is a device used to initiate and control a Nuclear fission, fission nuclear chain reaction. They are used for Nuclear power, commercial electricity, nuclear marine propulsion, marine propulsion, Weapons-grade plutonium, weapons ...
. In a more common case of uranium fuel, plutonium is produced first by neutron capture
Neutron capture is a nuclear reaction in which an atomic nucleus and one or more neutrons collide and merge to form a heavier nucleus. Since neutrons have no electric charge, they can enter a nucleus more easily than positively charged protons, wh ...
(the so-called (n,γ) reaction or neutron fusion) followed by beta-decay:
:^_U -> ce^_U -> beta^-23.5 \ \ce] ^_Np -> beta^-2.3565 \ \ce] ^_Pu (The times are half-lives.)
Plutonium-239 is further irradiated by a source that has a high neutron flux, several times higher than a conventional nuclear reactor, such as the 85-megawatt High Flux Isotope Reactor (HFIR) at the Oak Ridge National Laboratory
Oak Ridge National Laboratory (ORNL) is a federally funded research and development centers, federally funded research and development center in Oak Ridge, Tennessee, United States. Founded in 1943, the laboratory is sponsored by the United Sta ...
in Tennessee, US. The higher flux promotes fusion reactions involving not one but several neutrons, converting 239Pu to 244Cm and then to 249Cm:
:
Curium-249 has a short half-life of 64 minutes, and thus its further conversion to 250Cm has a low probability. Instead, it transforms by beta-decay into 249Bk:
:^_Cm ->[][64.15 \ \ce] ^_Bk -> beta^-330 \ \ce] ^_Cf
The thus-produced 249Bk has a long half-life of 330 days and thus can capture another neutron. However, the product, 250Bk, again has a relatively short half-life of 3.212 hours and thus does not yield any heavier berkelium isotopes. It instead decays to the californium isotope 250Cf:
:^_Bk -> ce^_Bk -> beta^-3.212 \ \ce] ^_Cf
Although 247Bk is the most stable isotope of berkelium, its production in nuclear reactors is very difficult because its potential progenitor 247Cm has never been observed to undergo beta decay. Thus, 249Bk is the most accessible isotope of berkelium, which still is available only in small quantities (only 0.66 grams have been produced in the US over the period 1967–1983) at a high price of the order 185 United States dollar, USD per microgram.[Hammond C. R. "The elements" in ] It is the only berkelium isotope available in bulk quantities, and thus the only berkelium isotope whose properties can be extensively studied.
The isotope 248Bk was first obtained in 1956 by bombarding a mixture of curium isotopes with 25 MeV α-particles. Although its direct detection was hindered by strong signal interference with 245Bk, the existence of a new isotope was proven by the growth of the decay product 248Cf which had been previously characterized. The half-life of 248Bk was estimated as hours, though later 1965 work gave a half-life in excess of 300 years (which may be due to an isomeric state). Berkelium-247 was produced during the same year by irradiating 244Cm with alpha-particles:
:
Berkelium-242 was synthesized in 1979 by bombarding 235U with 11B, 238U with 10B, 232Th with 14N or 232Th with 15N. It converts by electron capture
Electron capture (K-electron capture, also K-capture, or L-electron capture, L-capture) is a process in which the proton-rich nucleus of an electrically neutral atom absorbs an inner atomic electron, usually from the K or L electron shells. Th ...
to 242Cm with a half-life of minutes. A search for an initially suspected isotope 241Bk was then unsuccessful; 241Bk has since been synthesized.
:
Separation
The fact that berkelium readily assumes oxidation state
In chemistry, the oxidation state, or oxidation number, is the hypothetical Electrical charge, charge of an atom if all of its Chemical bond, bonds to other atoms are fully Ionic bond, ionic. It describes the degree of oxidation (loss of electrons ...
+4 in solids, and is relatively stable in this state in liquids, greatly assists separation of berkelium from many other actinides. These are produced in relatively large amounts during the nuclear synthesis and often favor the +3 state. This fact was not yet known in the initial experiments, which used a more complex separation procedure. Various inorganic oxidation agents can be applied to the solution to convert it to the +4 state, such as bromates (), bismuthates (), chromates ( and ), silver(I) thiolate (), lead(IV) oxide (), ozone
Ozone () (or trioxygen) is an Inorganic compound, inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , break ...
(), or photochemical oxidation procedures. More recently, it has been discovered that some organic and bio-inspired molecules, such as the chelator 3,4,3-LI(1,2-HOPO), can also oxidize Bk(III) and stabilize Bk(IV) under mild conditions. is then extracted with ion exchange
Ion exchange is a reversible interchange of one species of ion present in an insoluble solid with another of like charge present in a solution surrounding the solid. Ion exchange is used in softening or demineralizing of water, purification of ch ...
, extraction chromatography
In chemical analysis, chromatography is a laboratory technique for the Separation process, separation of a mixture into its components. The mixture is dissolved in a fluid solvent (gas or liquid) called the ''mobile phase'', which carries it ...
or liquid-liquid extraction using HDEHP (bis-(2-ethylhexyl) phosphoric acid), amine
In chemistry, amines (, ) are organic compounds that contain carbon-nitrogen bonds. Amines are formed when one or more hydrogen atoms in ammonia are replaced by alkyl or aryl groups. The nitrogen atom in an amine possesses a lone pair of elec ...
s, tributyl phosphate or various other reagents. These procedures separate berkelium from most trivalent actinides and lanthanides, except for the lanthanide cerium
Cerium is a chemical element; it has Chemical symbol, symbol Ce and atomic number 58. It is a hardness, soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it ...
(lanthanides are absent in the irradiation target but are created in various nuclear fission
Nuclear fission is a reaction in which the nucleus of an atom splits into two or more smaller nuclei. The fission process often produces gamma photons, and releases a very large amount of energy even by the energetic standards of radioactiv ...
decay chains).
A more detailed procedure adopted at the Oak Ridge National Laboratory
Oak Ridge National Laboratory (ORNL) is a federally funded research and development centers, federally funded research and development center in Oak Ridge, Tennessee, United States. Founded in 1943, the laboratory is sponsored by the United Sta ...
was as follows: the initial mixture of actinides is processed with ion exchange using lithium chloride
Lithium chloride is a chemical compound with the formula Li Cl. The salt is a typical ionic compound (with certain covalent characteristics), although the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlorid ...
reagent
In chemistry, a reagent ( ) or analytical reagent is a substance or compound added to a system to cause a chemical reaction, or test if one occurs. The terms ''reactant'' and ''reagent'' are often used interchangeably, but reactant specifies a ...
, then precipitated as hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It ...
s, filtered and dissolved in nitric acid. It is then treated with high-pressure elution from cation exchange resins, and the berkelium phase is oxidized and extracted using one of the procedures described above. Reduction of the thus-obtained to the +3 oxidation state yields a solution, which is nearly free from other actinides (but contains cerium). Berkelium and cerium are then separated with another round of ion-exchange treatment.
Bulk metal preparation
In order to characterize chemical and physical properties of solid berkelium and its compounds, a program was initiated in 1952 at the Material Testing Reactor, Arco, Idaho, US. It resulted in preparation of an eight-gram plutonium-239 target and in the first production of macroscopic quantities (0.6 micrograms) of berkelium by Burris B. Cunningham and Stanley Gerald Thompson in 1958, after a continuous reactor irradiation of this target for six years. This irradiation method was and still is the only way of producing weighable amounts of the element, and most solid-state studies of berkelium have been conducted on microgram or submicrogram-sized samples.
The world's major irradiation sources are the 85-megawatt High Flux Isotope Reactor at the Oak Ridge National Laboratory
Oak Ridge National Laboratory (ORNL) is a federally funded research and development centers, federally funded research and development center in Oak Ridge, Tennessee, United States. Founded in 1943, the laboratory is sponsored by the United Sta ...
in Tennessee, USA, and the SM-2 loop reactor at the Research Institute of Atomic Reactors (NIIAR) in Dimitrovgrad, Russia
Dimitrovgrad (; ), formerly Melekkes, Melekes, and Melekess (; ; ) until 1972, is a city in Ulyanovsk Oblast, Russia. It is the administrative center of Melekessky District, although it is not within the district and is an independent city. Th ...
, which are both dedicated to the production of transcurium elements (atomic number greater than 96). These facilities have similar power and flux levels, and are expected to have comparable production capacities for transcurium elements, although the quantities produced at NIIAR are not publicly reported. In a "typical processing campaign" at Oak Ridge, tens of grams of curium are irradiated to produce decigram quantities of californium
Californium is a synthetic chemical element; it has symbol Cf and atomic number 98. It was first synthesized in 1950 at Lawrence Berkeley National Laboratory (then the University of California Radiation Laboratory) by bombarding curium with al ...
, milligram quantities of berkelium-249 and einsteinium, and picogram
To help compare different '' orders of magnitude'', the following lists describe various ''mass'' levels between 10−67 kg and 1052 kg. The least massive thing listed here is a graviton, and the most massive thing is the observable univer ...
quantities of fermium. In total, just over one gram of berkelium-249 has been produced at Oak Ridge since 1967.
The first berkelium metal sample weighing 1.7 micrograms was prepared in 1971 by the reduction of fluoride with lithium
Lithium (from , , ) is a chemical element; it has chemical symbol, symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard temperature and pressure, standard conditions, it is the least dense metal and the ...
vapor at 1000 °C; the fluoride was suspended on a tungsten wire above a tantalum
Tantalum is a chemical element; it has Symbol (chemistry), symbol Ta and atomic number 73. It is named after Tantalus, a figure in Greek mythology. Tantalum is a very hard, ductility, ductile, lustre (mineralogy), lustrous, blue-gray transition ...
crucible containing molten lithium. Later, metal samples weighing up to 0.5 milligrams were obtained with this method.
:
Similar results are obtained with fluoride. Berkelium metal can also be produced by the reduction of oxide with thorium
Thorium is a chemical element; it has symbol Th and atomic number 90. Thorium is a weakly radioactive light silver metal which tarnishes olive grey when it is exposed to air, forming thorium dioxide; it is moderately soft, malleable, and ha ...
or lanthanum.
Compounds
Oxides
Two oxides of berkelium are known, with the berkelium oxidation
Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
state of +3 () and +4 ( ). oxide is a brown solid, while oxide is a yellow-green solid with a melting point of 1920 °C and is formed from BkO2 by reduction with molecular hydrogen
Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
:
:
Upon heating to 1200 °C, the oxide undergoes a phase change; it undergoes another phase change at 1750 °C. Such three-phase behavior is typical for the actinide sesquioxides. oxide, BkO, has been reported as a brittle gray solid but its exact chemical composition remains uncertain.
Halides
In halides, berkelium assumes the oxidation states +3 and +4. The +3 state is the most stable, especially in solutions, while the tetravalent halides and are only known in the solid phase. The coordination of berkelium atom in its trivalent fluoride and chloride is tricapped trigonal prismatic, with the coordination number
In chemistry, crystallography, and materials science, the coordination number, also called ligancy, of a central atom in a molecule or crystal is the number of atoms, molecules or ions bonded to it. The ion/molecule/atom surrounding the central ion ...
of 9. In trivalent bromide, it is bicapped trigonal prismatic (coordination 8) or octahedral (coordination 6), and in the iodide it is octahedral.
fluoride () is a yellow-green ionic solid and is isotypic with uranium tetrafluoride or zirconium tetrafluoride. fluoride () is also a yellow-green solid, but it has two crystalline structures. The most stable phase at low temperatures is isotypic with yttrium(III) fluoride, while upon heating to between 350 and 600 °C, it transforms to the structure found in lanthanum trifluoride.
Visible amounts of chloride () were first isolated and characterized in 1962, and weighed only 3 billionths of a gram
The gram (originally gramme; SI unit symbol g) is a Physical unit, unit of mass in the International System of Units (SI) equal to one thousandth of a kilogram.
Originally defined in 1795 as "the absolute Mass versus weight, weight of a volume ...
. It can be prepared by introducing hydrogen chloride
The Chemical compound, compound hydrogen chloride has the chemical formula and as such is a hydrogen halide. At room temperature, it is a colorless gas, which forms white fumes of hydrochloric acid upon contact with atmospheric water vapor. Hyd ...
vapors into an evacuated quartz tube containing berkelium oxide at a temperature about 500 °C. This green solid has a melting point of 600 °C, and is isotypic with uranium(III) chloride. Upon heating to nearly melting point, converts into an orthorhombic phase.
Two forms of bromide are known: one with berkelium having coordination 6, and one with coordination 8. The latter is less stable and transforms to the former phase upon heating to about 350 °C. An important property of radioactive solids has been studied on these two crystal forms: the structure of fresh and aged 249BkBr3 samples was probed by X-ray diffraction
X-ray diffraction is a generic term for phenomena associated with changes in the direction of X-ray beams due to interactions with the electrons around atoms. It occurs due to elastic scattering, when there is no change in the energy of the waves. ...
over a period longer than 3 years, so that various fractions of berkelium-249 had beta decay
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which an atomic nucleus emits a beta particle (fast energetic electron or positron), transforming into an isobar of that nuclide. For example, beta decay of a neutron ...
ed to californium-249. No change in structure was observed upon the 249BkBr3—249CfBr3 transformation. However, other differences were noted for 249BkBr3 and 249CfBr3. For example, the latter could be reduced with hydrogen to 249CfBr2, but the former could not – this result was reproduced on individual 249BkBr3 and 249CfBr3 samples, as well on the samples containing both bromides. The intergrowth of californium in berkelium occurs at a rate of 0.22% per day and is an obstacle to studying berkelium properties. Beside a chemical contamination, 249Cf, being an alpha emitter, brings undesirable self-damage of the crystal lattice and the resulting self-heating. The chemical effect however can be avoided by performing measurements as a function of time and extrapolating the obtained results.
Other inorganic compounds
The pnictides of berkelium-249 of the type BkX are known for the elements nitrogen
Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
, phosphorus
Phosphorus is a chemical element; it has Chemical symbol, symbol P and atomic number 15. All elemental forms of phosphorus are highly Reactivity (chemistry), reactive and are therefore never found in nature. They can nevertheless be prepared ar ...
, arsenic
Arsenic is a chemical element; it has Symbol (chemistry), symbol As and atomic number 33. It is a metalloid and one of the pnictogens, and therefore shares many properties with its group 15 neighbors phosphorus and antimony. Arsenic is not ...
and antimony
Antimony is a chemical element; it has chemical symbol, symbol Sb () and atomic number 51. A lustrous grey metal or metalloid, it is found in nature mainly as the sulfide mineral stibnite (). Antimony compounds have been known since ancient t ...
. They crystallize in the rock-salt structure and are prepared by the reaction of either hydride () or metallic berkelium with these elements at elevated temperature (about 600 °C) under high vacuum.
sulfide, , is prepared by either treating berkelium oxide with a mixture of hydrogen sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable. Trace amounts in ambient atmosphere have a characteristic foul odor of rotten eggs. Swedish chemist ...
and carbon disulfide vapors at 1130 °C, or by directly reacting metallic berkelium with elemental sulfur. These procedures yield brownish-black crystals.
and hydroxides are both stable in 1 molar solutions of sodium hydroxide
Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula . It is a white solid ionic compound consisting of sodium cations and hydroxide anions .
Sodium hydroxide is a highly corrosive base (chemistry), ...
. phosphate
Phosphates are the naturally occurring form of the element phosphorus.
In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthop ...
() has been prepared as a solid, which shows strong fluorescence
Fluorescence is one of two kinds of photoluminescence, the emission of light by a substance that has absorbed light or other electromagnetic radiation. When exposed to ultraviolet radiation, many substances will glow (fluoresce) with colore ...
under excitation with a green light. Berkelium hydrides are produced by reacting metal with hydrogen gas at temperatures about 250 °C. They are non-stoichiometric with the nominal formula (0 < ''x'' < 1). Several other salts of berkelium are known, including an oxysulfide (), and hydrated nitrate
Nitrate is a polyatomic ion with the chemical formula . salt (chemistry), Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. Almost all inorganic nitrates are solubility, soluble in wa ...
(), chloride (), sulfate
The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...
() and oxalate (). Thermal decomposition at about 600 °C in an argon
Argon is a chemical element; it has symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abu ...
atmosphere (to avoid oxidation to ) of yields the crystals of oxysulfate (). This compound is thermally stable to at least 1000 °C in inert atmosphere.
Organoberkelium compounds
Berkelium forms a trigonal (η5–C5H5)3Bk metallocene complex with three cyclopentadienyl Cyclopentadienyl can refer to
* Cyclopentadienyl anion, or cyclopentadienide,
** Cyclopentadienyl ligand
* Cyclopentadienyl radical, •
* Cyclopentadienyl cation,
See also
* Pentadienyl
{{Chemistry index ...
rings, which can be synthesized by reacting chloride with the molten beryllocene () at about 70 °C. It has an amber color and a density of 2.47 g/cm3. The complex is stable to heating to at least 250 °C, and sublimates without melting at about 350 °C. The high radioactivity of berkelium gradually destroys the compound (within a period of weeks). One cyclopentadienyl ring in (η5–C5H5)3Bk can be substituted by chlorine to yield . The optical absorption spectra of this compound are very similar to those of (η5–C5H5)3Bk.
Berkelium also forms berkelocene, an actinocene complex, with substituted cyclooctatetraenides.
Applications
There is currently no use for any isotope of berkelium outside basic scientific research. Berkelium-249 is a common target nuclide to prepare still heavier transuranium elements and superheavy element
Superheavy elements, also known as transactinide elements, transactinides, or super-heavy elements, or superheavies for short, are the chemical elements with atomic number greater than 104. The superheavy elements are those beyond the actinides in ...
s,[Stwertka, Albert. ''A Guide to the Elements'', Oxford University Press, 1996, p. 211. ] such as lawrencium, rutherfordium
Rutherfordium is a synthetic element, synthetic chemical element; it has Chemical symbol, symbol Rf and atomic number 104. It is named after physicist Ernest Rutherford. As a synthetic element, it is not found in nature and can only be made in a p ...
and bohrium. It is also useful as a source of the isotope californium-249, which is used for studies on the chemistry of californium
Californium is a synthetic chemical element; it has symbol Cf and atomic number 98. It was first synthesized in 1950 at Lawrence Berkeley National Laboratory (then the University of California Radiation Laboratory) by bombarding curium with al ...
in preference to the more radioactive californium-252 that is produced in neutron bombardment facilities such as the HFIR.
A 22 milligram batch of berkelium-249 was prepared in a 250-day irradiation and then purified for 90 days at Oak Ridge in 2009. This target yielded the first 6 atoms of tennessine
Tennessine is a synthetic element; it has Chemical symbol, symbol Ts and atomic number 117. It has the second-highest atomic number and joint-highest atomic mass of all known elements and is the penultimate element of the Period 7 element, 7th ...
at the Joint Institute for Nuclear Research (JINR), Dubna
Dubna ( rus, Дубна́, p=dʊbˈna) is a town in Moscow Oblast, Russia. It has a status of '' naukograd'' (i.e. town of science), being home to the Joint Institute for Nuclear Research, an international nuclear physics research center and o ...
, Russia, after bombarding it with calcium ions in the U400 cyclotron for 150 days. This synthesis was a culmination of the Russia-US collaboration between JINR and Lawrence Livermore National Laboratory
Lawrence Livermore National Laboratory (LLNL) is a Federally funded research and development centers, federally funded research and development center in Livermore, California, United States. Originally established in 1952, the laboratory now i ...
on the synthesis of elements 113 to 118 which was initiated in 1989.
Nuclear fuel cycle
The nuclear fission
Nuclear fission is a reaction in which the nucleus of an atom splits into two or more smaller nuclei. The fission process often produces gamma photons, and releases a very large amount of energy even by the energetic standards of radioactiv ...
properties of berkelium are different from those of the neighboring actinides curium and californium, and they suggest berkelium to perform poorly as a fuel in a nuclear reactor. Specifically, berkelium-249 has a moderately large neutron capture cross section of 710 barns for thermal neutrons, 1200 barns resonance integral, but very low fission cross section for thermal neutrons. In a thermal reactor, much of it will therefore be converted to berkelium-250 which quickly decays to californium-250. In principle, berkelium-249 can sustain a nuclear chain reaction in a fast breeder reactor
A breeder reactor is a nuclear reactor that generates more fissile material than it consumes. These reactors can be Nuclear fuel, fueled with more-commonly available isotopes of uranium and Isotopes of thorium, thorium, such as uranium-238 and t ...
. Its critical mass is relatively high at 192 kg, which can be reduced with a water or steel reflector but would still exceed the world production of this isotope.[Institut de Radioprotection et de Sûreté Nucléaire]
"Evaluation of nuclear criticality safety. data and limits for actinides in transport"
, p. 16
Berkelium-247 can maintain a chain reaction both in a thermal-neutron and in a fast-neutron reactor, however, its production is rather complex and thus the availability is much lower than its critical mass, which is about 75.7 kg for a bare sphere, 41.2 kg with a water reflector and 35.2 kg with a steel reflector (30 cm thickness).
Health issues
Little is known about the effects of berkelium on human body, and analogies with other elements may not be drawn because of different radiation products (electron
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
s for berkelium and alpha particle
Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay but may also be produce ...
s, neutron
The neutron is a subatomic particle, symbol or , that has no electric charge, and a mass slightly greater than that of a proton. The Discovery of the neutron, neutron was discovered by James Chadwick in 1932, leading to the discovery of nucle ...
s, or both for most other actinides). The low energy of electrons emitted from berkelium-249 (less than 126 keV) hinders its detection, due to signal interference with other decay processes, but also makes this isotope relatively harmless to humans as compared to other actinides. However, berkelium-249 transforms with a half-life of only 330 days to the strong alpha-emitter californium-249, which is rather dangerous and has to be handled in a glovebox in a dedicated laboratory.
Most available berkelium toxicity data originate from research on animals. Upon ingestion by rats, only about 0.01% of berkelium ends in the blood stream. From there, about 65% goes to the bones, where it remains for about 50 years, 25% to the lungs (biological half-life about 20 years), 0.035% to the testicles or 0.01% to the ovaries where berkelium stays indefinitely. The balance of about 10% is excreted. In all these organs berkelium might promote cancer, and in the skeleton
A skeleton is the structural frame that supports the body of most animals. There are several types of skeletons, including the exoskeleton, which is a rigid outer shell that holds up an organism's shape; the endoskeleton, a rigid internal fra ...
, its radiation can damage red blood cells. The maximum permissible amount of berkelium-249 in the human skeleton is 0.4 nanogram
To help compare different ''Order of magnitude, orders of magnitude'', the following lists describe various ''mass'' levels between 10−67 kilogram, kg and 1052 kg. The least massive thing listed here is a graviton, and the most massive thi ...
s.[Pradyot Patnaik. ''Handbook of Inorganic Chemicals'' McGraw-Hill, 2002, ]
References
Bibliography
*
*
*
External links
Berkelium
at ''The Periodic Table of Videos
''Periodic Videos'' (also known as ''The Periodic Table of Videos'') is a video project and YouTube channel on chemistry. It consists of a series of videos about chemical elements and the periodic table, with additional videos on other topics i ...
'' (University of Nottingham)
{{good article
Chemical elements
Chemical elements with double hexagonal close-packed structure
Actinides
Synthetic elements