Alluaivite is a rare mineral of the

eudialyte group Eudialyte group is a group of complex trigonal zircono- and, more rarely, titanosilicate minerals with general formula (1)N(2)N(3)N(4)N(5)sub>3 (1a)M(1b)sub>3M(2)3M(4)Z3 i24O72'4X2, where N(1) and N(2) and N(3) and N(5) = Na+ and more rarely H3 ...

,http://www.mindat.org/show.php?id=141&ld=2 Mindat with complex formula written as .Khomyakov A. P., Netschelyustov G. N. and Rastsvetaeva R. K. 1990: Alluaivite Na₁₉(Ca,Mn)₆(Ti,Nb)₃Si₂₆O₇₄Cl^.2H₂O – A new titanosilicate mineral of eudialyte-like structure. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva, 119(3), 117–120, in Jambor J. L. and Puziewicz J. 1991: New mineral names. American Mineralogist, 76, 1728–1735

/ref> It is unique among the eudialyte group as the only titanosilicate (other representatives of the group are usually zirconosilicates). The two dual-nature minerals of the group, being both titano- and zirconosilicates, are labyrinthite and dualite. They both contain alluaivite module in their structures.Khomyakov, A.P., Nechelyustov, G.N., and Rastsvetaeva, R.K., 2006. Labyrinthite (Na,K,Sr)₃₅Ca₁₂Fe₃Zr₆TiSi₅₁O₁₄₄(O,OH,H₂O)₉Cl₃, a new mineral with a modular eudialyte-like structure from Khibiny Alkaline Massif, Kola Peninsula, Russia. Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva 135(2), 38–49Khomyakov, A.P., Nechelyustov, G.N., and Rastsvetaeva, R.K., 2009: Dualite, Na₃₀(Ca,Na,Ce,Sr)₁₂(Na,Mn,Fe,Ti)₆Zr₃Ti₃MnSi₅₁O₁₄₄(OH,H₂O,Cl)₉, a new zircono-titanosilicate with a modular eudialyte-like structure from the Lovozero alkaline Pluton, Kola Peninsula, Russia. Geology of Ore Deposits 50(7), 574–582 Alluaivite is named after Mt. Alluaiv in Lovozero Tundry

massif A massif () is a principal mountain mass, such as a compact portion of a mountain range, containing one or more summits (e.g. France's Massif Central). In mountaineering literature, ''massif'' is frequently used to denote the main mass of an ...

Kola Peninsula The Kola Peninsula (; ) is a peninsula in the extreme northwest of Russia, and one of the largest peninsulas of Europe. Constituting the bulk of the territory of Murmansk Oblast, it lies almost completely inside the Arctic Circle and is border ...

Russia Russia, or the Russian Federation, is a country spanning Eastern Europe and North Asia. It is the list of countries and dependencies by area, largest country in the world, and extends across Time in Russia, eleven time zones, sharing Borders ...

, where it is found in ultra-

agpaitic An agpaitic rock is a peralkaline igneous rock, typically nepheline syenite or phonolite. Characteristic minerals in these rocks include complex silicates containing zirconium, titanium, sodium, calcium, the rare-earth elements, and fluorine. Agp ...

, hyperalkaline

pegmatites A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...

.http://www.handbookofmineralogy.org/pdfs/Alluaivite.PDF Handbook of Mineralogy

Notes on chemistry

Alluaivite contains relatively high amounts of admixing

strontium Strontium is a chemical element; it has symbol Sr and atomic number 38. An alkaline earth metal, it is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to ...

cerium Cerium is a chemical element; it has Chemical symbol, symbol Ce and atomic number 58. It is a hardness, soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it ...

potassium Potassium is a chemical element; it has Symbol (chemistry), symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to ...

, and

barium Barium is a chemical element; it has symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...

, with lesser amounts of substituting

lanthanum Lanthanum is a chemical element; it has symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements bet ...

and

zirconium Zirconium is a chemical element; it has Symbol (chemistry), symbol Zr and atomic number 40. First identified in 1789, isolated in impure form in 1824, and manufactured at scale by 1925, pure zirconium is a lustrous transition metal with a greyis ...

Occurrence and association

Alluaivite was found in ultra-agpaitic (highly alkaline)

pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic c ...

s on Mt. Alluaiv,

Lovozero massif The Lovozero Massif (, ''Lovozyorskiye Tundry'', named after the lake in that area – Lake Lovozero; the region is also known as , ''Lovozyorye'') is a mountain range located in the center of the Kola Peninsula in Russia, between Lovozero and ...

, Kola Peninsula, Russia – hence its name. Associating minerals are

aegirine Aegirine is a member of the clinopyroxene group of inosilicate minerals. It is the sodium endmember of the aegirine– augite series. It has the chemical formula NaFeSi2O6, in which the iron is present as the ion Fe3+. In the aegirine–augite se ...

arfvedsonite Arfvedsonite () or ''soda hornblende'' (partiellement obsolète) is a sodium amphibole mineral with composition: aNa2] Fe2+)4Fe3+(OH)2, Si8O22]. It crystallizes in the monoclinic prismatic crystal system and typically occurs as greenish black t ...

eudialyte Eudialyte, whose name derives from the Greek phrase , , meaning "well decomposable", is a somewhat rare, nine-member-ring cyclosilicate mineral, which forms in alkaline igneous rocks, such as nepheline syenites. Its name alludes to its ready so ...

nepheline Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatit ...

, potassic

feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...

, and

sodalite Sodalite ( ) is a tectosilicate mineral with the formula , with royal blue varieties widely used as an ornamental gemstone. Although massive sodalite samples are opaque, crystals are usually transparent to translucent. Sodalite is a member of th ...

References

Cyclosilicates Sodium minerals Calcium minerals Titanium minerals Trigonal minerals Minerals in space group 166 {{silicate-mineral-stub