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Alessandro Giuseppe Antonio Anastasio Volta (, ; ; 18 February 1745 – 5 March 1827) was an Italian
chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a graduated scientist trained in the study of chemistry, or an officially enrolled student in the field. Chemists study the composition of ...
and
physicist A physicist is a scientist who specializes in the field of physics, which encompasses the interactions of matter and energy at all length and time scales in the physical universe. Physicists generally are interested in the root or ultimate cau ...
who was a pioneer of
electricity Electricity is the set of physical phenomena associated with the presence and motion of matter possessing an electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by Maxwel ...
and power, and is credited as the inventor of the
electric battery An electric battery is a source of electric power consisting of one or more electrochemical cells with external connections for powering electrical devices. When a battery is supplying power, its positive Terminal (electronics), terminal is the ...
and the discoverer of
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes ...
. He invented the voltaic pile in 1799, and reported the results of his experiments in a two-part letter to the president of the
Royal Society The Royal Society, formally The Royal Society of London for Improving Natural Knowledge, is a learned society and the United Kingdom's national academy of sciences. The society fulfils a number of roles: promoting science and its benefits, re ...
, which was published in 1800. With this invention, Volta proved that electricity could be generated chemically and debunked the prevalent theory that electricity was generated solely by living beings. Volta's invention sparked a great amount of scientific excitement and led others to conduct similar experiments, which eventually led to the development of the field of
electrochemistry Electrochemistry is the branch of physical chemistry concerned with the relationship between Electric potential, electrical potential difference and identifiable chemical change. These reactions involve Electron, electrons moving via an electronic ...
. Volta drew admiration from
Napoleon Bonaparte Napoleon Bonaparte (born Napoleone di Buonaparte; 15 August 1769 – 5 May 1821), later known by his regnal name Napoleon I, was a French general and statesman who rose to prominence during the French Revolution and led Military career ...
for his invention, and was invited to the Institute of France to demonstrate his invention to the members of the institute. Throughout his life, Volta enjoyed a certain amount of closeness with the emperor who conferred upon him numerous honours. Volta held the chair of experimental physics at the
University of Pavia The University of Pavia (, UNIPV or ''Università di Pavia''; ) is a university located in Pavia, Lombardy, Italy. There was evidence of teaching as early as 1361, making it one of the List of oldest universities in continuous operation, oldest un ...
for nearly 40 years and was widely idolised by his students. Despite his professional success, Volta was inclined towards domestic life and this was more apparent in his later years when he tended to live secluded from public life and more for the sake of his family. He died in 1827 from a series of illnesses which began in 1823. The SI unit of
electric potential Electric potential (also called the ''electric field potential'', potential drop, the electrostatic potential) is defined as electric potential energy per unit of electric charge. More precisely, electric potential is the amount of work (physic ...
is named the
volt The volt (symbol: V) is the unit of electric potential, Voltage#Galvani potential vs. electrochemical potential, electric potential difference (voltage), and electromotive force in the International System of Units, International System of Uni ...
in his honour.


Early life and marriage

Volta was born in Como, a town in northern
Italy Italy, officially the Italian Republic, is a country in Southern Europe, Southern and Western Europe, Western Europe. It consists of Italian Peninsula, a peninsula that extends into the Mediterranean Sea, with the Alps on its northern land b ...
, on 18 February 1745. His father, Filippo Volta, was of noble lineage. His mother, Donna Maddalena, came from the family of the Inzaghis. In 1794, Volta married an aristocratic lady also from Como, Teresa Peregrini, with whom he raised three sons: Zanino, Flaminio, and Luigi.


Career

In 1774, he became a professor of physics at the Royal School in Como. A year later, he improved and popularised the
electrophorus In electromagnetism, an electrophorus or electrophore is a simple, manual, Capacitor, capacitive, electrostatic generator used to produce Electric charge, charge via the process of electrostatic induction. A first version of it was invented in 1 ...
, a device that produced
static electricity Static electricity is an imbalance of electric charges within or on the surface of a material. The charge remains until it can move away by an electric current or electrical discharge. The word "static" is used to differentiate it from electric ...
. His promotion of it was so extensive that he is often credited with its invention, even though a machine operating on the same principle was described in 1762 by the Swedish experimenter Johan Wilcke. In 1777, he travelled through Switzerland, where he befriended H. B. de Saussure. In the years between 1776 and 1778, Volta studied the
chemistry Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and chemical compound, compounds made of atoms, molecules a ...
of gases. He researched and discovered
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes ...
after reading a paper by
Benjamin Franklin Benjamin Franklin (April 17, 1790) was an American polymath: a writer, scientist, inventor, statesman, diplomat, printer, publisher and Political philosophy, political philosopher.#britannica, Encyclopædia Britannica, Wood, 2021 Among the m ...
of the United States on "flammable air". In November 1776, he found methane in the marshes of Angera on
Lake Maggiore Lake Maggiore (, ; ; ; ; literally 'greater lake') or Verbano (; ) is a large lake located on the south side of the Alps. It is the second largest lake in Italy and the largest in southern Switzerland. The lake and its shoreline are divided be ...
, and by 1778 he managed to isolate it. He devised experiments such as the ignition of methane by an electric spark in a closed vessel. Volta also studied what we now call electrical
capacitance Capacitance is the ability of an object to store electric charge. It is measured by the change in charge in response to a difference in electric potential, expressed as the ratio of those quantities. Commonly recognized are two closely related ...
, developing separate means to study both electrical potential difference (''V'') and charge (''Q''), and discovering that for a given object, they are proportional. This is called Volta's Law of Capacitance, and for this work, the unit of electrical potential has been named the volt. In 1779, he became a professor of experimental physics at the
University of Pavia The University of Pavia (, UNIPV or ''Università di Pavia''; ) is a university located in Pavia, Lombardy, Italy. There was evidence of teaching as early as 1361, making it one of the List of oldest universities in continuous operation, oldest un ...
, a chair that he occupied for almost 40 years. Volta's lectures were so crowded with students that the subsequent emperor Joseph II ordered the construction (based on a project by Leopold Pollack) of a new "physical theatre", today the "Aula Volta". Furthermore, the emperor granted Volta substantial funding to equip the physics cabinet with instruments, purchased by Volta in England and France. At the University History Museum of the University of Pavia there are 150 of them, used by Alessandro Volta.


Volta and Galvani

Luigi Galvani, an Italian physicist, discovered something he named "animal electricity" when two different metals were connected in series with a frog's leg and to one another. Volta realised that the frog's leg served as both a conductor of electricity (what we would now call an
electrolyte An electrolyte is a substance that conducts electricity through the movement of ions, but not through the movement of electrons. This includes most soluble Salt (chemistry), salts, acids, and Base (chemistry), bases, dissolved in a polar solven ...
) and as a detector of electricity. He also understood that the frog's legs were irrelevant to the
electric current An electric current is a flow of charged particles, such as electrons or ions, moving through an electrical conductor or space. It is defined as the net rate of flow of electric charge through a surface. The moving particles are called charge c ...
, which was caused by the two differing metals. He replaced the frog's leg with brine-soaked paper and detected the flow of electricity by other means familiar to him from his previous studies. In this way, he discovered the electrochemical series, and the law that the
electromotive force In electromagnetism and electronics, electromotive force (also electromotance, abbreviated emf, denoted \mathcal) is an energy transfer to an electric circuit per unit of electric charge, measured in volts. Devices called electrical ''transducer ...
(emf) of a galvanic cell, consisting of a pair of metal
electrode An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or a gas). In electrochemical cells, electrodes are essential parts that can consist of a varie ...
s separated by electrolyte, is the difference between their two electrode potentials (thus, two identical electrodes and a common electrolyte give zero net emf). This may be called Volta's Law of the electrochemical series. In 1800, as the result of a professional disagreement over the galvanic response advocated by Galvani, Volta invented the voltaic pile, an early
electric battery An electric battery is a source of electric power consisting of one or more electrochemical cells with external connections for powering electrical devices. When a battery is supplying power, its positive Terminal (electronics), terminal is the ...
, which produced a steady electric current. Volta had determined that the most effective pair of dissimilar metals to produce electricity was
zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
and
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
. Initially, he experimented with individual cells in series, each cell being a wine goblet filled with brine into which the two dissimilar electrodes were dipped. The voltaic pile replaced the goblets with cardboard soaked in brine.


Early battery

In announcing his invention of the voltaic pile, Volta paid tribute to the influences of William Nicholson, Tiberius Cavallo, and Abraham Bennet. The battery made by Volta is credited as one of the first electrochemical cells. It consists of two electrodes: one made of
zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
, the other of
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
. The
electrolyte An electrolyte is a substance that conducts electricity through the movement of ions, but not through the movement of electrons. This includes most soluble Salt (chemistry), salts, acids, and Base (chemistry), bases, dissolved in a polar solven ...
is either
sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ...
mixed with water or a form of saltwater brine. The electrolyte exists in the form and . Zinc metal, which is higher in the electrochemical series than both copper and hydrogen, is oxidized to zinc cations (Zn2+) and creates electrons that move to the copper electrode. The positively charged hydrogen ions (
proton A proton is a stable subatomic particle, symbol , Hydron (chemistry), H+, or 1H+ with a positive electric charge of +1 ''e'' (elementary charge). Its mass is slightly less than the mass of a neutron and approximately times the mass of an e ...
s) capture
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
s from the copper electrode, forming bubbles of hydrogen gas, H2. This makes the zinc rod the negative electrode and the copper rod the positive electrode. Thus, there are two terminals, and an electric current will flow if they are connected. The
chemical reaction A chemical reaction is a process that leads to the chemistry, chemical transformation of one set of chemical substances to another. When chemical reactions occur, the atoms are rearranged and the reaction is accompanied by an Gibbs free energy, ...
s in this voltaic cell are as follows: :Zinc: :: :Sulfuric acid: :: Copper metal does not react, but rather it functions as a catalyst for the hydrogen-gas formation and an electrode for the electric current. The sulfate anion () does not undergo any chemical reaction either, but migrates to the zinc anode to compensate for the charge of the zinc cations formed there. However, this cell also has some disadvantages. It is unsafe to handle, since sulfuric acid, even if diluted, can be hazardous. Also, the power of the cell diminishes over time because the hydrogen gas is not released. Instead, it accumulates on the surface of the copper electrode and forms a barrier between the metal and the electrolyte solution.


Last years and retirement

In 1809, Volta became an associated member of the Royal Institute of the Netherlands. In honour of his work, Volta was made a count by
Napoleon Bonaparte Napoleon Bonaparte (born Napoleone di Buonaparte; 15 August 1769 – 5 May 1821), later known by his regnal name Napoleon I, was a French general and statesman who rose to prominence during the French Revolution and led Military career ...
in 1810. Volta retired in 1819 to his estate in Camnago, a of Como, Italy, now named "Camnago Volta" in his honour. He died there on 5 March 1827, just after his 82nd birthday. Volta's remains were buried in Camnago Volta.


Legacy

Volta's legacy is celebrated by the Tempio Voltiano memorial located in the public gardens by the lake. There is also a museum that was built in his honour, which exhibits some of the equipment that Volta used to conduct experiments. Nearby stands the Villa Olmo, which houses the Voltian Foundation, an organization promoting scientific activities. Volta carried out his experimental studies and produced his first inventions near Como. In the Old Campus of the
University of Pavia The University of Pavia (, UNIPV or ''Università di Pavia''; ) is a university located in Pavia, Lombardy, Italy. There was evidence of teaching as early as 1361, making it one of the List of oldest universities in continuous operation, oldest un ...
, there is the classroom (Aula Volta) commissioned by Emperor Joseph II to Leopoldo Pollack in 1787 for the lectures of Alessandro Volta, while in the University History Museum there are many scientific instruments that belonged to Volta. In 1927, an international physics conference, the Como Conference was held at Lake Como for the 100th anniversary of his death. His image was depicted on the Italian Lire 10,000 note (1990–1997) along with a sketch of his voltaic pile. In late 2017, Nvidia announced a new workstation-focused GPU microarchitecture called Volta. The
electric eel The electric eels are a genus, ''Electrophorus'', of neotropical freshwater fish from South America in the family Gymnotidae, of which they are the only members of the subfamily Electrophorinae. They are known for their electric fish, ability ...
species '' Electrophorus voltai'', described in 2019 as the strongest bioelectricity producer in nature, was named after Volta.


Religious beliefs

Volta was raised as a Catholic and for all of his life continued to maintain his belief. Because he was not ordained a clergyman as his family expected, he was sometimes accused of being irreligious and some people have speculated about his possible unbelief, stressing that "he did not join the Church", or that he virtually "ignored the church's call". Nevertheless, he cast out doubts in a declaration of faith in which he said:
I do not understand how anyone can doubt the sincerity and constancy of my attachment to the religion which I profess, the Roman, Catholic and Apostolic religion in which I was born and brought up, and of which I have always made confession, externally and internally. I have, indeed, and only too often, failed in the performance of those good works which are the mark of a Catholic Christian, and I have been guilty of many sins: but through the special mercy of God I have never, as far as I know, wavered in my faith... In this faith I recognise a pure gift of God, a supernatural grace; but I have not neglected those human means which confirm belief, and overthrow the doubts which at times arise. I studied attentively the grounds and basis of religion, the works of apologists and assailants, the reasons for and against, and I can say that the result of such study is to clothe religion with such a degree of probability, even for the merely natural reason, that every spirit unperverted by sin and passion, every naturally noble spirit must love and accept it. May this confession which has been asked from me and which I willingly give, written and subscribed by my own hand, with authority to show it to whomsoever you will, for I am not ashamed of the Gospel, may it produce some good fruit!


Publications

*


Lesser known collections

* ''Briefe über thierische elektricität'' (1900) (''Letters about thieric electricity'', Available through Worldcat.org libraries, Leipzig, W. Engelmann, publisher) * ''Untersuchungen über den Galvanismus'', 1796 bis 1800 (''Studies on Galvanism'', Available through Worldcat.org libraries) * ''Del modo di render sensibilissima la più debole elettricità sia naturale, sia artificiale'' (''Of the method of rendering very sensible the weakest natural or artificial electricity'' By Alexander Volta, Professor Of Experimental Philosophy In Como, &c. Read at the Royal Society, 14 March 1782, Held in WorldCat libraries)


See also

* Armstrong effect *
Electrophorus In electromagnetism, an electrophorus or electrophore is a simple, manual, Capacitor, capacitive, electrostatic generator used to produce Electric charge, charge via the process of electrostatic induction. A first version of it was invented in 1 ...
* History of the battery * History of the internal combustion engine * Lemon battery * Mercury beating heart * Thermoelectric effect * Volta (lunar crater) * Volta Prize


References


External links

*
Volta and the "Pile"




*


Life of Alessandro Volta: Biography; Inventions; Facts

Alessandro Volta , Biography, Facts, Battery, & Invention , Britannica
{{DEFAULTSORT:Volta, Alessandro 1745 births 1827 deaths People from Como 19th-century Italian physicists Battery inventors Enlightenment scientists Fellows of the Royal Society Independent scientists History of neuroscience 18th-century Italian inventors 18th-century Italian physicists Italian Roman Catholics Members of the Royal Netherlands Academy of Arts and Sciences People associated with electricity Recipients of the Copley Medal Italian scientific instrument makers Academic staff of the University of Pavia