Aenigmatite
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Aenigmatite, also known as cossyrite after Cossyra, the ancient name of
Pantelleria Pantelleria (; ), known in ancient times as Cossyra or Cossura, is an Italian island and comune in the Strait of Sicily in the Mediterranean Sea, southwest of Sicily and east of the Tunisian coast. On clear days Tunisia is visible from the ...
, is a
sodium Sodium is a chemical element; it has Symbol (chemistry), symbol Na (from Neo-Latin ) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 element, group 1 of the peri ...
,
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
,
titanium Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
inosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, the crystalline forms of silica (silicon dio ...
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
. The chemical formula is Na2Fe2+5TiSi6O20 and its structure consists of single tetrahedral chains with a repeat unit of four and complex side branches. It forms brown to black triclinic lamellar crystals. It has
Mohs hardness The Mohs scale ( ) of mineral hardness is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fair ...
of 5.5 to 6 and
specific gravity Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nea ...
of 3.74 to 3.85. Aenigmatite forms a solid-solution series with wilkinsonite, Na2Fe2+4Fe3+2Si6O20. Aenigmatite is primarily found in peralkaline
volcanic rock Volcanic rocks (often shortened to volcanics in scientific contexts) are rocks formed from lava erupted from a volcano. Like all rock types, the concept of volcanic rock is artificial, and in nature volcanic rocks grade into hypabyssal and me ...
s,
pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic c ...
s, and
granite Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...
s as well as silica-poor
intrusive rock Intrusive rock is formed when magma penetrates existing rock, crystallizes, and solidifies underground to form ''Igneous intrusion, intrusions'', such as batholiths, dike (geology), dikes, Sill (geology), sills, laccoliths, and volcanic necks.I ...
s. It was first described by August Breithaupt in 1865 for an occurrence in the Ilimaussaq intrusive complex of southwest
Greenland Greenland is an autonomous territory in the Danish Realm, Kingdom of Denmark. It is by far the largest geographically of three constituent parts of the kingdom; the other two are metropolitan Denmark and the Faroe Islands. Citizens of Greenlan ...
. Its name comes from αίνιγμα, the
Greek Greek may refer to: Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group *Greek language, a branch of the Indo-European language family **Proto-Greek language, the assumed last common ancestor of all kno ...
word for "riddle". It was also reported from the Kaidun meteorite, possibly a Mars meteorite, which landed in March 1980 in
South Yemen South Yemen, officially the People's Democratic Republic of Yemen, abbreviated to Democratic Yemen, was a country in South Arabia that existed in what is now southeast Yemen from 1967 until Yemeni unification, its unification with the Yemen A ...
. Other notable studied occurrences include: * Narsaarsuk and elsewhere in Greenland. * The Khibiny and Lovozero alkaline massifs on
Kola Peninsula The Kola Peninsula (; ) is a peninsula in the extreme northwest of Russia, and one of the largest peninsulas of Europe. Constituting the bulk of the territory of Murmansk Oblast, it lies almost completely inside the Arctic Circle and is border ...
,
Russia Russia, or the Russian Federation, is a country spanning Eastern Europe and North Asia. It is the list of countries and dependencies by area, largest country in the world, and extends across Time in Russia, eleven time zones, sharing Borders ...
. * The Yenisei Range,
Krasnoyarsk Krai Krasnoyarsk Krai (, ) is a federal subjects of Russia, federal subject (a krai) of Russia located in Siberia. Its administrative center is the types of inhabited localities in Russia, city of Krasnoyarsk, the second-largest city in Siberia after ...
,
Russia Russia, or the Russian Federation, is a country spanning Eastern Europe and North Asia. It is the list of countries and dependencies by area, largest country in the world, and extends across Time in Russia, eleven time zones, sharing Borders ...
. * The volcanic island of
Pantelleria Pantelleria (; ), known in ancient times as Cossyra or Cossura, is an Italian island and comune in the Strait of Sicily in the Mediterranean Sea, southwest of Sicily and east of the Tunisian coast. On clear days Tunisia is visible from the ...
,
Italy Italy, officially the Italian Republic, is a country in Southern Europe, Southern and Western Europe, Western Europe. It consists of Italian Peninsula, a peninsula that extends into the Mediterranean Sea, with the Alps on its northern land b ...
. * In the United States, from Granite Mountain, near
Little Rock Little Rock is the List of capitals in the United States, capital and List of municipalities in Arkansas, most populous city of the U.S. state of Arkansas. The city's population was 202,591 as of the 2020 census. The six-county Central Arkan ...
, Pulaski County, Arkansas, and Santa Rosa,
Sonoma County, California Sonoma County ( ) is a county located in the U.S. state of California. As of the 2020 United States census, its population was 488,863. Its seat of government and largest city is Santa Rosa. Sonoma County comprises the Santa Rosa-Petaluma ...
. * In Australia, from Warrumbungle volcano, Nandewar volcano, and the Mount Warning complex, New South Wales; and the Peak Range Province, Queensland. * In Canada, from Mount Edziza, the Ilgachuz and Rainbow Range shield complexes. * From Logan Point quarry,
Dunedin Volcano The Dunedin Volcano is an extensively eroded multi-vent shield volcano that was active between 16 and 10 million years ago. It originally extended from the modern city of Dunedin, New Zealand to Aramoana about 25 km away. Extensive erosion ...
, New Zealand.


See also

*
List of minerals This is a list of minerals which have Wikipedia articles. Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various ''species''. Within a mineral speci ...


References

{{Titanium minerals Sodium minerals Iron(II) minerals Titanium minerals Inosilicates Triclinic minerals Minerals in space group 2