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Uranium Trioxide
Uranium trioxide (UO3), also called uranyl oxide, uranium(VI) oxide, and uranic oxide, is the hexavalent oxide of uranium. The solid may be obtained by heating uranyl nitrate to 400 °C. Its most commonly encountered polymorph is amorphous UO3. Production and use There are three methods to generate uranium trioxide. As noted below, two are used industrially in the reprocessing of nuclear fuel and uranium enrichment. # U3O8 can be oxidized at 500 °C with oxygen. Note that above 750 °C even in 5 atm O2 UO3 decomposes into U3O8. # Uranyl nitrate, UO2(NO3)2·6H2O can be heated to yield UO3. This occurs during the reprocessing of nuclear fuel. Fuel rods are dissolved in HNO3 to separate uranyl nitrate from plutonium and the fission products (the PUREX method). The pure uranyl nitrate is converted to solid UO3 by heating at 400 °C. After reduction with hydrogen (with other inert gas present) to uranium dioxide, the uranium can be used in new MOX fuel rod ...
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Uranium Dioxide
Uranium dioxide or uranium(IV) oxide (), also known as urania or uranous oxide, is an oxide of uranium, and is a black, radioactive, crystalline powder that naturally occurs in the mineral uraninite. It is used in nuclear fuel rods in nuclear reactors. A mixture of uranium and plutonium dioxides is used as MOX fuel. It has been used as an orange, yellow, green, and black color in ceramic glazes and glass. Production Uranium dioxide is produced by reducing uranium trioxide with hydrogen. This reaction often creates triuranium octoxide as an intermediate. :UO3 + H2 → UO2 + H2O at 700 °C (973 K) This reaction plays an important part in the creation of nuclear fuel through nuclear reprocessing and uranium enrichment. Chemistry Structure The solid is isostructural with (has the same structure as) fluorite ( calcium fluoride), where each U is surrounded by eight O nearest neighbors in a cubic arrangement. In addition, the dioxides of cerium, thorium, and the tran ...
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Sodium Diuranate
Sodium diuranate, also known as the yellow oxide of uranium, is an inorganic chemical compound with the chemical formula . It is a sodium salt of a diuranate anion. It forms a hexahydrate . Sodium diuranate is commonly referred to by the initials SDU. Along with ammonium diuranate it was a component in early yellowcakes. The ratio of the two compounds is determined by process conditions; however, yellowcake is now largely a mix of uranium oxides. Preparation In the classical procedure for extracting uranium, pitchblende is broken up and mixed with sulfuric and nitric acids. The uranium dissolves to form uranyl sulfate and sodium carbonate is added to precipitate impurities. If the uranium in the ore is in the tetravalent oxidation state, an oxidiser is added to oxidise it to the hexavalent oxidation state, and sodium hydroxide is then added to make the uranium precipitate as sodium diuranate. The alkaline process of milling uranium ores involves precipitating sodium uran ...
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White Blood Cell
White blood cells (scientific name leukocytes), also called immune cells or immunocytes, are cells of the immune system that are involved in protecting the body against both infectious disease and foreign entities. White blood cells are generally larger than red blood cells. They include three main subtypes: granulocytes, lymphocytes and monocytes. All white blood cells are produced and derived from multipotent cells in the bone marrow known as hematopoietic stem cells. Leukocytes are found throughout the body, including the blood and lymphatic system. All white blood cells have nuclei, which distinguishes them from the other blood cells, the anucleated red blood cells (RBCs) and platelets. The different white blood cells are usually classified by cell lineage ( myeloid cells or lymphoid cells). White blood cells are part of the body's immune system. They help the body fight infection and other diseases. Types of white blood cells are granulocytes (neutrophils, eosino ...
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Royal Society
The Royal Society, formally The Royal Society of London for Improving Natural Knowledge, is a learned society and the United Kingdom's national academy of sciences. The society fulfils a number of roles: promoting science and its benefits, recognising excellence in science, supporting outstanding science, providing scientific advice for policy, education and public engagement and fostering international and global co-operation. Founded on 28 November 1660, it was granted a royal charter by Charles II of England, King Charles II and is the oldest continuously existing scientific academy in the world. The society is governed by its Council, which is chaired by the society's president, according to a set of statutes and standing orders. The members of Council and the president are elected from and by its Fellows, the basic members of the society, who are themselves elected by existing Fellows. , there are about 1,700 fellows, allowed to use the postnominal title FRS (Fellow ...
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Metastudtite
Studtite, chemical formula UO2)O2(H2O)2�2(H2O) or UO4·4(H2O), is a secondary uranium mineral containing peroxide formed by the alpha-radiolysis of water during formation. It occurs as pale yellow to white needle-like crystals often in acicular, white sprays. Studtite was originally described by Vaes in 1947Annales de la Société Géologique de Belgique - 1947 - pp B212 to B226- J.F. Vaes - Six nouveaux minéraux d'urane provenant de Shinkolobwe (Katanga) - from specimens from Shinkolobwe, Katanga Copper Crescent, Katanga (Shaba), Democratic Republic of Congo, and has since been reported from several other localities. The mineral was named for Franz Edward Studt, an English prospector and geologist who was working for the Belgians. When exposed to air studtite converts over a short time to the metastudtite UO4·2(H2O) form. Despite their apparent chemical simplicity, these two uranyl species are the only reported peroxide minerals. They may also be readily formed on the surf ...
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Studtite
Studtite, chemical formula UO2)O2(H2O)2�2(H2O) or UO4·4(H2O), is a secondary uranium mineral containing peroxide formed by the alpha- radiolysis of water during formation. It occurs as pale yellow to white needle-like crystals often in acicular, white sprays. Studtite was originally described by Vaes in 1947Annales de la Société Géologique de Belgique - 1947 - pp B212 to B226- J.F. Vaes - Six nouveaux minéraux d'urane provenant de Shinkolobwe (Katanga) - from specimens from Shinkolobwe, Katanga Copper Crescent, Katanga (Shaba), Democratic Republic of Congo, and has since been reported from several other localities. The mineral was named for Franz Edward Studt, an English prospector and geologist who was working for the Belgians. When exposed to air studtite converts over a short time to the metastudtite UO4·2(H2O) form. Despite their apparent chemical simplicity, these two uranyl species are the only reported peroxide minerals. They may also be readily formed on the ...
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Schoepite
Schoepite, empirical formula (UO2)8O2(OH)12·12(H2O) is a rare alteration product of uraninite in hydrothermal uranium deposits. It may also form directly from ianthinite. The mineral presents as a transparent to translucent yellow, lemon yellow, brownish yellow, or amber orthorhombic tabular crystals. Although over 20 other crystal forms have been noted; rarely in microcrystalline aggregates. When exposed to air schoepite converts over a short time to the metaschoepite form (UO3·H2O, ) within a few months of being exposed to ambient air. The hardness is 2.5, density is 4.8 g/cm3, and it streaks yellow. It was first described from specimens from Shinkolobwe mine in Belgian Congo in 1923, several additional localities are known. Schoepite was named to honor Alfred Schoep (1881–1966), Professor of Mineralogy at the University of Ghent, Belgium Belgium, officially the Kingdom of Belgium, is a country in Northwestern Europe. Situated in a coastal lowland region ...
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Coffinite
Coffinite is a uranium-bearing silicate mineral with formula: U(SiO4)1−x(OH)4x. It occurs as black incrustations, dark to pale-brown in thin section. It has a grayish-black streak. It has a brittle to conchoidal fracture. The hardness of coffinite is between 5 and 6. It was first described in 1954 for an occurrence at the La Sal No. 2 Mine, Beaver Mesa, Mesa County, Colorado, US, and named for American geologist Reuben Clare Coffin (1886–1972). It has widespread global occurrence in Colorado Plateau-type uranium ore deposits of uranium and vanadium. It replaces organic matter in sandstone and in hydrothermal vein type deposits. It occurs in association with uraninite, thorite, pyrite, marcasite, roscoelite, clay minerals and amorphous organic matter. Composition Coffinite's chemical formula is U(SiO4)1−x(OH)4x. X-ray powder patterns from samples of coffinite allowed geologists to classify it as a new mineral in 1955. A comparison to the x-ray powder pattern of zircon ( ...
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Blind River, Ontario
Blind River is a town situated on the North Channel (Ontario), North Channel of Lake Huron in the Algoma District, Ontario, Canada. The town, named after the nearby Blind River (Ontario), Blind River, celebrated its centennial in 2006. History France, French explorers discovered the North Channel and made it a renowned voyageurs, voyageur route. Fur traders, lumberjack, loggers and mining, miners followed to seek natural resources. A fur trading post was established by the North West Company in 1789 at the mouth of the Mississagi River. When the fur trade slowed about 1820, the Hudson's Bay Company purchased the North West Company. A number of Animal trapping, trappers settled along the rivers flowing into Lake Huron. One of the rivers, just east of the Mississagi mouth, was called Penewobecong, which translates to "smooth rock or sloping". The voyageurs named the river the Blind River because the mouth was not easily visible along the canoe route. The name Blind River was adopt ...
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Cameco Corporation
Cameco Corporation (formerly Canadian Mining and Energy Corporation) is the world's largest publicly traded uranium company, based in Saskatoon, Saskatchewan, Canada. In 2015, it was the world's second largest uranium producer, accounting for 18% of world production. History The Canadian Mining and Energy Corporation was formed in 1988 by the merger and privatization of two Crown corporations: the federally owned Eldorado Nuclear Limited (known previously as Eldorado Mining and Refining Limited) and Saskatchewan-based Saskatchewan Mining Development Corporation (SMDC). The name was later shortened to "Cameco Corporation". The new company was initially owned 62% by the provincial government and 38% by the federal government. The initial public offering (IPO) for 20% of the company was conducted in July, 1991. Government ownership of the company decreased over the next eleven years, with full privatization occurring in February, 2002. In 1996, Cameco acquired Power Resources ...
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Mining
Mining is the Resource extraction, extraction of valuable geological materials and minerals from the surface of the Earth. Mining is required to obtain most materials that cannot be grown through agriculture, agricultural processes, or feasibly created Chemical synthesis, artificially in a laboratory or factory. Ores recovered by mining include Metal#Extraction, metals, coal, oil shale, gemstones, limestone, chalk mining, chalk, dimension stone, rock salt, potash, gravel, and clay. The ore must be a rock or mineral that contains valuable constituent, can be extracted or mined and sold for profit. Mining in a wider sense includes extraction of any non-renewable resource such as petroleum, natural gas, or even fossil water, water. Modern mining processes involve prospecting for ore bodies, analysis of the profit potential of a proposed mine, extraction of the desired materials, and final mine reclamation, reclamation or restoration of the land after the mine is closed. Mining ma ...
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Uranium Hexafluoride
Uranium hexafluoride, sometimes called hex, is the inorganic compound with the formula . Uranium hexafluoride is a volatile, white solid that is used in enriching uranium for nuclear reactors and nuclear weapons. Preparation Uranium dioxide is converted with hydrofluoric acid (HF) to uranium tetrafluoride: : The resulting is subsequently oxidized with fluorine to give the hexafluoride: : In samples contaminated with uranium trioxide, uranyl fluoride, an oxyfluoride compound is produced in the HF step: : which can be fluorinated to produce the same product, uranium hexafluoride. : The fluorination step in both reactions above are highly exothermic. Properties Physical properties At atmospheric pressure, sublimes at 56.5 °C. The solid-state structure was determined by neutron diffraction at 77 K and 293 K.J. C. Taylor, P. W. Wilson, J. W. Kelly: „The structures of fluorides. I. Deviations from ideal symmetry in the structure of crystalline UF6: a neutron diffract ...
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