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Tetraperchloratoaluminate
Tetraperchloratoaluminates are salts of the tetraperchloratoaluminate anion, l(ClO4)4sup>−. The anion contains aluminium tetrahedrally surrounded by four perchlorate groups. The perchlorate is covalently bonded to the aluminium, but perchlorate is much more well known as an ion. The covalent bond to aluminium distorts the perchlorate and renders it unstable. Related chemicals are the haloperchloroatoaluminates, where there is one perchloro group attached to aluminium, and three halogens such as chlorine (chloroperchloroatoaluminates) or bromine (bromoperchloroatoaluminates). Formation Nitronium tetraperchloratoaluminate is made from exact amounts of nitronium perchlorate and anhydrous aluminium chloride combined in liquid sulfur dioxide. Ammonium tetraperchloratoaluminate can be formed by three moles of nitronium perchlorate, one mole of anhydrous aluminium chloride, and one mole of ammonium perchlorate Ammonium perchlorate ("AP") is an inorganic compound with the formula . ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perchlorates
A perchlorate is a chemical compound containing the perchlorate ion, , the conjugate base of perchloric acid (ionic perchlorate). As counterions, there can be metal cations, quaternary ammonium cations or other ions, for example, nitronium cation (). The term ''perchlorate'' can also describe perchlorate esters or covalent perchlorates. These are organic compounds that are alkyl or aryl esters of perchloric acid. They are characterized by a covalent bond between an oxygen atom of the ClO4 moiety and an organyl group. In most ionic perchlorates, the cation is non-coordinating. The majority of ionic perchlorates are commercially produced salts commonly used as oxidizers for pyrotechnic devices and for their ability to control static electricity in food packaging. Additionally, they have been used in rocket propellants, fertilizers, and as bleaching agents in the paper and textile industries. Perchlorate contamination of food and water endangers human health, primarily affectin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perchlorate
A perchlorate is a chemical compound containing the perchlorate ion, , the conjugate base of perchloric acid (ionic perchlorate). As counterions, there can be metal cations, quaternary ammonium cations or other ions, for example, nitronium cation (). The term ''perchlorate'' can also describe perchlorate esters or covalent perchlorates. These are organic compounds that are alkyl or aryl esters of perchloric acid. They are characterized by a covalent bond between an oxygen atom of the ClO4 moiety and an organyl group. In most ionic perchlorates, the cation is non-coordinating. The majority of ionic perchlorates are commercially produced salts commonly used as oxidizers for pyrotechnic devices and for their ability to control static electricity in food packaging. Additionally, they have been used in rocket propellants, fertilizers, and as bleaching agents in the paper and textile industries. Perchlorate contamination of food and water endangers human health, primarily af ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aluminium
Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has a great affinity towards oxygen, passivation (chemistry), forming a protective layer of aluminium oxide, oxide on the surface when exposed to air. It visually resembles silver, both in its color and in its great ability to reflect light. It is soft, magnetism, nonmagnetic, and ductility, ductile. It has one stable isotope, 27Al, which is highly abundant, making aluminium the abundance of the chemical elements, 12th-most abundant element in the universe. The radioactive decay, radioactivity of aluminium-26, 26Al leads to it being used in radiometric dating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitronium Perchlorate
Nitronium perchlorate, NO2ClO4, also known as nitryl perchlorate and nitroxyl perchlorate, is an inorganic chemical, the Salt (chemistry), salt of the perchlorate anion and the nitronium ion, nitronium cation. It forms colorless monoclinic crystals. It is hygroscopic, and is a strong oxidizing and nitrating agent. It may become hypergolic in contact with organic materials. Nitronium perchlorate was investigated as an oxidizer in solid rocket propellants. Thomas N. Scortia filed for patent on such propellant in 1963, however, its reactivity and incompatibility with many materials hindered such use. Coating of nitronium perchlorate particles with ammonium nitrate, prepared in situ by passing of dry ammonia gas over the particles, was investigated, and a patent was awarded. The decomposition rate of nitronium perchlorate can be altered by doping with Polyvalency (chemistry), multivalent cations. Nitronium perchlorate and ammonium perchlorate do not produce smoke when stoichiometri ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aluminium Chloride
Aluminium chloride, also known as aluminium trichloride, is an inorganic compound with the formula . It forms a hexahydrate with the formula , containing six water molecules of hydration. Both the anhydrous form and the hexahydrate are colourless crystals, but samples are often contaminated with iron(III) chloride, giving them a yellow colour. The anhydrous form is commercially important. It has a low melting and boiling point. It is mainly produced and consumed in the production of aluminium, but large amounts are also used in other areas of the chemical industry. The compound is often cited as a Lewis acid. It is an inorganic compound that reversibly changes from a polymer to a monomer at mild temperature. Structure Anhydrous adopts three structures, depending on the temperature and the state (solid, liquid, gas). Solid has a sheet-like layered structure with cubic close-packed chloride ions. In this framework, the Al centres exhibit octahedral coordination geom ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfur Dioxide
Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a colorless gas with a pungent smell that is responsible for the odor of burnt matches. It is released naturally by volcanic activity and is produced as a by-product of metals refining and the burning of Sour gas, sulfur-Sour crude oil, bearing fossil fuels. Sulfur dioxide is somewhat toxic to humans, although only when inhaled in relatively large quantities for a period of several minutes or more. It was known to medieval alchemy, alchemists as "volatile spirit of sulfur". Structure and bonding SO2 is a bent molecule with ''C''2v Point groups in three dimensions, symmetry point group. A valence bond theory approach considering just ''s'' and ''p'' orbitals would describe the bonding in terms of resonance (chemistry), resonance between two resonance structures. The sulfur–oxygen bond has a bond order of 1.5. There is support f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammonium Perchlorate
Ammonium perchlorate ("AP") is an inorganic compound with the formula . It is a colorless or white solid that is soluble in water. It is a powerful oxidizer. Combined with a fuel, it can be used as a rocket propellant called ammonium perchlorate composite propellant. Its instability has involved it in accidents such as the PEPCON disaster. Production Ammonium perchlorate (AP) is produced by reaction between ammonia and perchloric acid. This process is the main outlet for the industrial production of perchloric acid. The salt also can be produced by salt metathesis reaction of ammonium salts with sodium perchlorate. This process exploits the relatively low solubility of NH4ClO4, which is about 10% of that for sodium perchlorate.Helmut Vogt, Jan Balej, John E. Bennett, Peter Wintzer, Saeed Akbar Sheikh, Patrizio Gallone "Chlorine Oxides and Chlorine Oxygen Acids" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH. AP crystallises as colorless rhombohedra. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hexaperchloratoaluminate
Hexaperchloratoaluminate is a polyatomic anion with the chemical formula . It is composed of six perchlorate groups ( or more precisely ) covalently bound to the central aluminium atom, resulting in the anion with net charge of –3. The six perchlorate groups are ligands of the central aluminium. This anion is a highly oxidizing and reactive complex, similar to other hexacoordinated aluminium complexes such as hexanitratoaluminate. The aluminium perchlorate salts formed with hexaperchloratoaluminate are of particular interest due to their potential uses as energetic materials. The series of hexaperchloratoaluminate salts includes lithium hexaperchloratoaluminate, ammonium hexaperchloratoaluminate, tetramethylammonium hexaperchloratoaluminate, and trinitronium hexaperchloratoaluminate. Each of these compounds possess unique properties and may have potential applications in areas such as rocket propellants, pyrotechnics, and other explosive-based technologies. Preparation Hexape ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aluminium Complexes
Aluminium (or aluminum in North American English) is a chemical element; it has symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has a great affinity towards oxygen, forming a protective layer of oxide on the surface when exposed to air. It visually resembles silver, both in its color and in its great ability to reflect light. It is soft, nonmagnetic, and ductile. It has one stable isotope, 27Al, which is highly abundant, making aluminium the 12th-most abundant element in the universe. The radioactivity of 26Al leads to it being used in radiometric dating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ is small and highly charged; as such, it has more polarizing power, and bonds formed by aluminium have a more covalent character. The strong af ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
