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Tetracarbon Dioxide
Tetracarbon dioxide is an oxide of carbon, a chemical compound of carbon and oxygen, with chemical formula C4O2 or O=C=C=C=C=O. It can be regarded as butatriene dione, the double ketone of butatriene — more precisely 1,2,3-butatriene-1,4-dione.J.I.G. Codagan, John Buckingham, Finlay J. MacDonald, P. H. Rhodes (1996), ''Dictionary of Organic Compounds''. CRC Press, , . 9000 pages. Butatriene dione is the fourth member of the family of linear carbon dioxides O(=C)''n''=O, that includes carbon dioxide CO2 or O=C=O, ethylene dione C2O2 or O=C=C=O, carbon suboxide C3O2 or O=C=C=C=O, pentacarbon dioxide C5O2 or O=C=C=C=C=C=O, and so on. The compound was obtained in 1990 by Maier and others, by flash vacuum pyrolysis of cyclic azaketones in a frozen argon matrix. It was also obtained in the same year by Sülzle and Schwartz through impact ionization of ((CH3-)2(C4O2)(=O)2=)2 in the gas phase. Although theoretical studies indicated that the even-numbered members of the O(=C)''n'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxocarbon
In chemistry, an oxocarbon or oxide of carbon is a chemical compound consisting only of carbon and oxygen. The simplest and most common oxocarbons are carbon monoxide (CO) and carbon dioxide (). Many other stable (practically if not thermodynamically) or metastable oxides of carbon are known, but they are rarely encountered, such as carbon suboxide ( or ) and mellitic anhydride (). Many other oxides are known today, most of them synthesized since the 1960s. Some of these new oxides are stable at room temperature. Some are metastable or stable only at very low temperatures, but decompose to simpler oxocarbons when warmed. Many are inherently unstable and can be observed only momentarily as intermediates in chemical reactions or are so reactive that they exist only in gas phase or have only been detected by matrix isolation. Graphene oxide and other stable polymeric carbon oxides with unbounded molecular structures exist. Overview Carbon dioxide (CO2) occurs widely in nature, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Matrix Isolation
Matrix isolation is an experimental technique used in chemistry and physics. It generally involves a material being trapped within an unreactive matrix. A ''host'' matrix is a continuous solid phase in which ''guest'' particles (atoms, molecules, ions, etc.) are embedded. The guest is said to be ''isolated'' within the ''host'' matrix. Initially the term matrix-isolation was used to describe the placing of a chemical species in any unreactive material, often polymers or resins, but more recently has referred specifically to gases in low-temperature solids. A typical matrix isolation experiment involves a guest sample being diluted in the gas phase with the host material, usually a noble gas or nitrogen. This mixture is then deposited on a window that is cooled to below the melting point of the host gas. The sample may then be studied using various spectroscopic procedures. Experimental setup The transparent window, on to which the sample is deposited, is usually cooled using a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ketenes
In organic chemistry, a ketene is an organic compound of the form , where R and R' are two arbitrary monovalent chemical groups (or two separate substitution sites in the same molecule). The name may also refer to the specific compound ethenone , the simplest ketene. Although they are highly useful, most ketenes are unstable. When used as reagents in a chemical procedure, they are typically generated when needed, and consumed as soon as (or while) they are produced. History Ketenes were first studied as a class by Hermann Staudinger before 1905. Ketenes were systematically investigated by Hermann Staudinger in 1905 in the form of diphenylketene (conversion of \alpha-chlorodiphenyl acetyl chloride with zinc). Staudinger was inspired by the first examples of reactive organic intermediates and stable radicals discovered by Moses Gomberg in 1900 (compounds with triphenylmethyl group). Properties Ketenes are highly electrophilic at the carbon atom bonded with the heteroato ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxocarbons
In chemistry, an oxocarbon or oxide of carbon is a chemical compound consisting only of carbon and oxygen. The simplest and most common oxocarbons are carbon monoxide (CO) and carbon dioxide (). Many other stable (practically if not thermodynamically) or metastable oxides of carbon are known, but they are rarely encountered, such as carbon suboxide ( or ) and mellitic anhydride (). Many other oxides are known today, most of them synthesized since the 1960s. Some of these new oxides are stable at room temperature. Some are metastable or stable only at very low temperatures, but decompose to simpler oxocarbons when warmed. Many are inherently unstable and can be observed only momentarily as intermediates in chemical reactions or are so reactive that they exist only in gas phase or have only been detected by matrix isolation. Graphene oxide and other stable polymeric carbon oxides with unbounded molecular structures exist. Overview Carbon dioxide (CO2) occurs widely in nature, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spin Triplet
In quantum mechanics, a triplet is a quantum state of a system with a spin of quantum number =1, such that there are three allowed values of the spin component, = −1, 0, and +1. Spin, in the context of quantum mechanics, is not a mechanical rotation but a more abstract concept that characterizes a particle's intrinsic angular momentum. It is particularly important for systems at atomic length scales, such as individual atoms, protons, or electrons. Almost all molecules encountered in daily life exist in a singlet state, but molecular oxygen is an exception. At room temperature, O2 exists in a triplet state, which can only undergo a chemical reaction by making the forbidden transition into a singlet state. This makes it kinetically nonreactive despite being thermodynamically one of the strongest oxidants. Photochemical or thermal activation can bring it into the singlet state, which makes it kinetically as well as thermodynamically a very strong oxidant. __TOC__ Two spin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbon Monoxide
Carbon monoxide ( chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simplest molecule of the oxocarbon family. In coordination complexes the carbon monoxide ligand is called carbonyl. It is a key ingredient in many processes in industrial chemistry. The most common source of carbon monoxide is the partial combustion of carbon-containing compounds, when insufficient oxygen or heat is present to produce carbon dioxide. There are also numerous environmental and biological sources that generate and emit a significant amount of carbon monoxide. It is important in the production of many compounds, including drugs, fragrances, and fuels. Upon emission into the atmosphere, carbon monoxide affects several processes that contribute to climate change. Carbon monoxide has important biological roles across phylog ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tricarbon Monoxide
Tricarbon monoxide C3O is a reactive radical (chemistry), radical oxocarbon molecule found in space, and which can be made as a transient substance in the laboratory. It can be trapped in an inert gas matrix or made as a short lived gas. C3O can be classified as a ketene or an oxocumulene a kind of heterocumulene. Natural occurrence C3O has been detected by its microwave spectrum in the dark cold Taurus Molecular Cloud One and also in the protostar Elias 18. The route to produce this is speculated to be: :HC + CO2 → HC3O+ + CO :HC3O+ → C3O + H+ or :C2 + CO → C3O which is more favourable at lower temperatures. The related C3S is more abundant in dark molecular clouds, even though oxygen is 20 times more common than sulfur. The difference is due to the higher rate of formation and that C3S is less polar. Production C3O can be produced by heating Meldrum's acid. This also produces acetone, carbon monoxide and carbon dioxide. R. L. DeKock and W. Waltner were the first to id ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ionization
Ionization, or Ionisation is the process by which an atom or a molecule acquires a negative or positive Electric charge, charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged atom or molecule is called an ion. Ionization can result from the loss of an electron after collisions with subatomic particles, collisions with other atoms, molecules and ions, or through the interaction with electromagnetic radiation. Heterolytic bond cleavage and heterolytic substitution reactions can result in the formation of ion pairs. Ionization can occur through radioactive decay by the internal conversion process, in which an excited nucleus transfers its energy to one of the inner-shell electrons causing it to be ejected. Uses Everyday examples of gas ionization are such as within a fluorescent lamp or other electrical discharge lamps. It is also used in radiation detectors such as the Geiger-Müller counter or the ionization cham ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Helmut Schwartz
Helmut is a German name. Variants include Hellmut, Helmuth, and Hellmuth. From old German, the first element deriving from either ''heil'' ("healthy") or ''hiltja'' ("battle"), and the second from ''muot'' ("spirit, mind, mood"). Helmut may refer to: People A–L * Helmut Angula (born 1945), Namibian politician * Helmut Ashley (1919–2021), Austrian director and cinematographer * Helmut Bakaitis (born 1944), Australian director and actor *Helmut Berger (born 1944), Austrian actor * Helmut Dantine (1917–1982), Austrian actor *Helmut Deutsch (born 1945), Austrian classical pianist *Helmut Ditsch (born 1962), Argentine painter *Hellmut Diwald (1924–1993), German historian *Helmut Donner (born 1941), Austrian high jumper * Helmut Fischer (1926–1997), German actor *Hellmut von Gerlach (1866–1935), German journalist * Helmut Goebbels (1935–1945), only son of Joseph Goebbels * Helmut Griem (1932–2004), German actor *Helmut Gröttrup (1916–1981), German rocket scientist ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Detlev Sülzle
Detlev is a German given name. It is a spelling variant of Detlef. People with this name Notable people with this name include: * Detlev Blanke (born 1941), interlinguistics lecturer at Humboldt University of Berlin *Detlev Bronk (1897–1975), President of Johns Hopkins University in Baltimore, Maryland *Detlev Buchholz, theoretical physicist at Göttingen University * Detlev Buck (born 1962), German film director and actor * Otto Detlev Creutzfeldt (born 1927), German physiologist and neurologist *Detlev Dammeier (born 1968), German football coach and a former player * Wilhelm Heinrich Detlev Körner (1878–1938), illustrator of the American West * Detlev Lauscher (1952–2010), German footballer who played as a striker * Detlev von Liliencron (1844–1909), German lyric poet and novelist from Kiel * Detlev Mehlis (born 1949), Senior Public Prosecutor in the Office of the Attorney General in Berlin *Detlev F. Neufert Detlev F. Neufert is a German author, filmmaker, photograp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
