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Segregation (materials Science)
In Materials Science, materials science, segregation is the enrichment of atoms, ions, or molecules at a microscopic region in a materials system. While the terms segregation and adsorption are essentially synonymous, in practice, segregation is often used to describe the partitioning of molecular constituents to defects from ''solid'' solutions, whereas adsorption is generally used to describe such partitioning from liquids and gases to surfaces. The molecular-level segregation discussed in this article is distinct from other types of materials phenomena that are often called segregation, such as particle segregation in granular materials, and phase separation or precipitation, wherein molecules are segregated in to macroscopic regions of different compositions. Segregation has many practical consequences, ranging from the formation of soap bubbles, to microstructural engineering in materials science, to the stabilization of colloidal suspensions. Segregation can occur in various ...
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Materials Science
Materials science is an interdisciplinary field of researching and discovering materials. Materials engineering is an engineering field of finding uses for materials in other fields and industries. The intellectual origins of materials science stem from the Age of Enlightenment, when researchers began to use analytical thinking from chemistry, physics, and engineering to understand ancient, phenomenological observations in metallurgy and mineralogy. Materials science still incorporates elements of physics, chemistry, and engineering. As such, the field was long considered by academic institutions as a sub-field of these related fields. Beginning in the 1940s, materials science began to be more widely recognized as a specific and distinct field of science and engineering, and major technical universities around the world created dedicated schools for its study. Materials scientists emphasize understanding how the history of a material (''processing'') influences its struc ...
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Shear Modulus
In materials science, shear modulus or modulus of rigidity, denoted by ''G'', or sometimes ''S'' or ''μ'', is a measure of the Elasticity (physics), elastic shear stiffness of a material and is defined as the ratio of shear stress to the shear strain: :G \ \stackrel\ \frac = \frac = \frac where :\tau_ = F/A \, = shear stress :F is the force which acts :A is the area on which the force acts :\gamma_ = shear strain. In engineering :=\Delta x/l = \tan \theta , elsewhere := \theta :\Delta x is the transverse displacement :l is the initial length of the area. The derived SI unit of shear modulus is the Pascal (unit), pascal (Pa), although it is usually expressed in Pascal (unit), gigapascals (GPa) or in thousand pounds per square inch (ksi). Its dimensional analysis, dimensional form is M1L−1T−2, replacing ''force'' by ''mass'' times ''acceleration''. Explanation The shear modulus is one of several quantities for measuring the stiffness of materials. All of them arise in ...
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Freundlich Equation
The Freundlich equation or Freundlich adsorption isotherm, an adsorption isotherm, is an empirical relationship between the quantity of a gas adsorbed into a solid surface and the gas pressure. The same relationship is also applicable for the concentration of a solute adsorbed onto the surface of a solid and the concentration of the solute in the liquid phase. In 1909, Herbert Freundlich gave an expression representing the isothermal variation of adsorption of a quantity of gas adsorbed by unit mass of solid adsorbent with gas pressure. This equation is known as Freundlich adsorption isotherm or Freundlich adsorption equation. As this relationship is entirely empirical, in the case where adsorption behavior can be properly fit by isotherms with a theoretical basis, it is usually appropriate to use such isotherms instead (see for example the Langmuir and BET adsorption theories). The Freundlich equation is also derived (non-empirically) by attributing the change in the equilibrium ...
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Absorption (chemistry)
Absorption is a physical or chemical phenomenon or a process in which atoms, molecules or ions enter the liquid or solid bulk phase of a material. This is a different process from adsorption, since molecules undergoing absorption are taken up by the volume, not by the surface (as in the case for adsorption). A more common definition is that "Absorption is a chemical or physical phenomenon in which the molecules, atoms and ions of the substance getting absorbed enter into the bulk phase (gas, liquid or solid) of the material in which it is taken up." A more general term is '' sorption'', which covers absorption, adsorption, and ion exchange. Absorption is a condition in which something takes in another substance. In many processes important in technology, the chemical absorption is used in place of the physical process, e.g., absorption of carbon dioxide by sodium hydroxide – such acid-base processes do not follow the Nernst partition law (see: solubility). For some examp ...
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Adsorption
Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a fluid (the ''absorbate'') is dissolved by or permeates a liquid or solid (the ''absorbent''). While adsorption does often precede absorption, which involves the transfer of the absorbate into the volume of the absorbent material, alternatively, adsorption is distinctly a surface phenomenon, wherein the adsorbate does not penetrate through the material surface and into the bulk of the adsorbent. The term '' sorption'' encompasses both adsorption and absorption, and ''desorption'' is the reverse of sorption. Like surface tension, adsorption is a consequence of surface energy. In a bulk material, all the bonding requirements (be they ionic, covalent or metallic) of the constituent atoms of the material are fulfilled by other atoms in ...
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Limiting Factor
A limiting factor is a variable of a system that causes a noticeable change in output or another measure of a type of system. The limiting factor is in a pyramid shape of organisms going up from the producers to consumers and so on. A factor not limiting over a certain domain of starting conditions may yet be limiting over another domain of starting conditions, including that of the factor. Overview The identification of a factor as limiting is possible only in distinction to one or more other factors that are non-limiting. Disciplines differ in their use of the term as to whether they allow the simultaneous existence of more than one limiting factor (which may then be called "co-limiting"), but they all require the existence of at least one non-limiting factor when the terms are used. There are several different possible scenarios of limitation when more than one factor is present. The first scenario, called ''single limitation'' occurs when only one factor, the one with maximu ...
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Melting Point
The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state of matter, state from solid to liquid. At the melting point the solid and liquid phase (matter), phase exist in Thermodynamic equilibrium, equilibrium. The melting point of a substance depends on pressure and is usually specified at a Standard temperature and pressure, standard pressure such as 1 Atmosphere (unit), atmosphere or 100 Pascal (unit), kPa. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point. Because of the ability of substances to Supercooling, supercool, the freezing point can easily appear to be below its actual value. When the "characteristic freezing point" of a substance is determined, in fact, the actual methodology is almost always "the principle of observing the disappearance rather than the formation of ice, that is, the #Melting point measurements, melting ...
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Coordination Number
In chemistry, crystallography, and materials science, the coordination number, also called ligancy, of a central atom in a molecule or crystal is the number of atoms, molecules or ions bonded to it. The ion/molecule/atom surrounding the central ion/molecule/atom is called a ligand. This number is determined somewhat differently for molecules than for crystals. For molecules and polyatomic ions the coordination number of an atom is determined by simply counting the other atoms to which it is bonded (by either single or multiple bonds). For example, [Cr(NH3)2Cl2Br2]− has Cr3+ as its central cation, which has a coordination number of 6 and is described as ''hexacoordinate''. The common coordination numbers are 4, 6 and 8. Molecules, polyatomic ions and coordination complexes In chemistry, coordination number, defined originally in 1893 by Alfred Werner, is the total number of neighbors of a central atom in a molecule or ion. The concept is most commonly applied to coordination ...
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Segregation In Materials 3
Segregation may refer to: Separation of people * Geographical segregation, rates of two or more populations which are not homogenous throughout a defined space * School segregation * Housing segregation * Racial segregation, separation of humans into racial groups in daily life ** Racial segregation in the United States * Religious segregation, the separation of people according to their religion * Residential segregation, the physical separation of two or more groups into different neighbourhoods * Sex segregation, the physical, legal, and cultural separation of people according to their biological sex * Occupational segregation, the distribution of people based upon demographic characteristics, most often gender, both across and within occupations and jobs * Age segregation, separation of people based on their age and may be observed in many aspects of some societies * Health segregation - see quarantine and isolation (health care) * Segregation of inmates in prisons - see pr ...
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Interaction Energy
In physics, interaction energy is the contribution to the total energy that is caused by an interaction between the objects being considered. The interaction energy usually depends on the relative position of the objects. For example, Q_1 Q_2 / (4 \pi \varepsilon_0 \Delta r) is the electrostatic interaction energy between two objects with charges Q_1, Q_2. Interaction energy A straightforward approach for evaluating the interaction energy is to calculate the difference between the objects' combined energy and all of their isolated energies. In the case of two objects, ''A'' and ''B'', the interaction energy can be written as: Theoretical and Computational Chemistry, 1999, Ideas of Quantum Chemistry, 2007 and Quantum Magnetic Resonance Imaging Diagnostics of Human Brain Disorders, 2010 \Delta E_\text = E(A,B) - \left( E(A) + E(B) \right), where E(A) and E(B) are the energies of the isolated objects (monomers), and E(A,B) the energy of their interacting assembly (dimer). For large ...
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Binary System
A binary system is a system of two astronomical bodies of the same kind that are comparable in size. Definitions vary, but typically require the center of mass to be located outside of either object. (See animated examples.) The most common kinds of binary system are binary stars and binary asteroids, but brown dwarfs, planets, neutron stars, black holes and galaxies can also form binaries. A ''multiple system'' is similar but consists of three or more objects, for example triple stars and triple asteroids (a more common term than 'trinary'). Classification In a binary system, the brighter or more massive object is referred to as primary, and the other the secondary. Binary stars are also classified based on orbit. Wide binaries are objects with orbits that keep them apart from one another. They evolve separately and have very little effect on each other. Close binaries are close to each other and are able to transfer mass from one another. They can also be classified ba ...
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Solid Solubility
In chemistry, solubility is the ability of a chemical substance, substance, the solute, to form a solution (chemistry), solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solubility of a substance in a specific solvent is generally measured as the concentration of the solute in a wikt:saturated#Chemistry, saturated solution, one in which no more solute can be dissolved. At this point, the two substances are said to be at the solubility equilibrium. For some solutes and solvents, there may be no such limit, in which case the two substances are said to be "miscibility, miscible in all proportions" (or just "miscible"). The solute can be a solid, a liquid, or a gas, while the solvent is usually solid or liquid. Both may be pure substances, or may themselves be solutions. Gases are always miscible in all proportions, except in very extreme situations,J. de Swaan Arons and G. A. ...
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