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Mercury Zinc Telluride
Mercury zinc telluride (HgZnTe, MZT) is a telluride of mercury and zinc, an alloy of mercury telluride and zinc telluride. It is a narrow-gap semiconductor material. Mercury zinc telluride is used in infrared detectors and arrays for infrared imaging and infrared astronomy Infrared astronomy is a sub-discipline of astronomy which specializes in the astronomical observation, observation and analysis of astronomical objects using infrared (IR) radiation. The wavelength of infrared light ranges from 0.75 to 300 microm .... Mercury zinc telluride has better chemical, thermal, and mechanical stability than mercury cadmium telluride. The bandgap of MZT is more sensitive to composition fluctuations than that of MCT, which may be an issue for reproducible device fabrication. MZT is less amenable than MCT to fabrication of complex heterostructures by molecular beam epitaxy. See also * Cadmium zinc telluride * Mercury cadmium telluride External links National Pollutant Invent ...
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Tellurium
Tellurium is a chemical element; it has symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally found in its native form as elemental crystals. Tellurium is far more common in the Universe as a whole than on Earth. Its extreme rarity in the Earth's crust, comparable to that of platinum, is due partly to its formation of a volatile hydride that caused tellurium to be lost to space as a gas during the hot nebular formation of Earth. Tellurium-bearing compounds were first discovered in 1782 in a gold mine in Kleinschlatten, Transylvania (now Zlatna, Romania) by Austrian mineralogist Franz-Joseph Müller von Reichenstein, although it was Martin Heinrich Klaproth who named the new element in 1798 after the Latin 'earth'. Gold telluride minerals are the most notable natural gold compounds. However, they are not a commercially signif ...
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Mercury Cadmium Telluride
Hg1−''x''Cd''x''Te or mercury cadmium telluride (also cadmium mercury telluride, MCT, MerCad Telluride, MerCadTel, MerCaT or CMT) is a chemical compound of cadmium telluride (CdTe) and mercury telluride (HgTe) with a tunable bandgap spanning the shortwave infrared to the very long wave infrared regions. The amount of cadmium (Cd) in the alloy can be chosen so as to tune the optical absorption of the material to the desired infrared wavelength. CdTe is a semiconductor with a bandgap of approximately at room temperature. HgTe is a semimetal, which means that its bandgap energy is zero. Mixing these two substances allows one to obtain any bandgap between 0 and 1.5 eV. Properties Physical Hg1−''x''Cd''x''Te has a zincblende structure with two interpenetrating face-centered cubic lattices offset by (1/4,1/4,1/4)''a''o in the primitive cell. The cations Cd and Hg are statistically mixed on the yellow sublattice while the Te anions form the grey sublattice in the imag ...
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Tellurides
The telluride ion is the anion Te2− and its derivatives. It is analogous to the other chalcogenide anions, the lighter O2−, S2−, and Se2−, and the heavier Po2−. In principle, Te2− is formed by the two-e− reduction of tellurium. The redox potential is −1.14 V. :Te(s) + 2 e− ↔ Te2− Although solutions of the telluride dianion have not been reported, soluble salts of bitelluride (TeH−) are known. Organic tellurides ''Tellurides'' also describe a class of organotellurium compounds formally derived from Te2−. An illustrative member is dimethyl telluride, which results from the methylation of telluride salts: :2 CH3I + Na2Te → (CH3)2Te + 2 NaI Dimethyl telluride is formed by the body when tellurium is ingested. Such compounds are often called telluroethers because they are structurally related to ethers with tellurium replacing oxygen, although the length of the C–Te bond is much longer than a C–O bond. C–Te–C angles tend to be closer ...
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Zinc Compounds
Zinc compounds are chemical compounds containing the element zinc which is a member of the group 12 element, group 12 of the periodic table. The oxidation state of zinc in most compounds is the group oxidation state of +2. Zinc may be classified as a post-transition main group element with zinc(II). Zinc compounds are noteworthy for their nondescript appearance and behavior: they are generally colorless (unlike compounds of other elements with oxidation number +2, which are colored), do not readily engage in redox reactions, and generally adopt symmetrical structures. General characteristics In its compounds, Zn2+ ions have an electronic configuration [Ar] 3d10. As such, Zn2+ tends to have a symmetrical coordination geometry in both its complexes and compounds. In both ZnO and ZnS, (zincblende) zinc is bound tetrahedrally bound to four ligands (oxide and sulfide, respectively). Many coordination complex, complexes, such as ZnCl42−, are tetrahedral. Tetrahedrally coordinated zin ...
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Mercury(II) Compounds
Mercury most commonly refers to: * Mercury (planet), the closest planet to the Sun * Mercury (element), a chemical element * Mercury (mythology), a Roman deity Mercury or The Mercury may also refer to: Companies * Mercury (toy manufacturer), a brand of diecast toy cars manufactured in Italy * Mercury Communications, a British telecommunications firm set up in the 1980s * Mercury Corporation, an American aircraft manufacturer * Mercury Cyclecar Company, a defunct American car company * Mercury Drug, a Philippine pharmacy chain * Mercury Energy, an electricity generation and retail company in New Zealand * Mercury Filmworks, a Canadian independent animation studio * Mercury General, a multiple-line American insurance organization * Mercury Interactive, a software testing tools vendor * Mercury Marine, a manufacturer of marine engines, particularly outboard motors * Mercury Systems, a defense-related information technology company * Mercury Technologies, a financial tec ...
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Mercury Cadmium Telluride
Hg1−''x''Cd''x''Te or mercury cadmium telluride (also cadmium mercury telluride, MCT, MerCad Telluride, MerCadTel, MerCaT or CMT) is a chemical compound of cadmium telluride (CdTe) and mercury telluride (HgTe) with a tunable bandgap spanning the shortwave infrared to the very long wave infrared regions. The amount of cadmium (Cd) in the alloy can be chosen so as to tune the optical absorption of the material to the desired infrared wavelength. CdTe is a semiconductor with a bandgap of approximately at room temperature. HgTe is a semimetal, which means that its bandgap energy is zero. Mixing these two substances allows one to obtain any bandgap between 0 and 1.5 eV. Properties Physical Hg1−''x''Cd''x''Te has a zincblende structure with two interpenetrating face-centered cubic lattices offset by (1/4,1/4,1/4)''a''o in the primitive cell. The cations Cd and Hg are statistically mixed on the yellow sublattice while the Te anions form the grey sublattice in the imag ...
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Cadmium Zinc Telluride
Cadmium zinc telluride, (CdZnTe) or CZT, is a compound of cadmium, zinc and tellurium or, more strictly speaking, an alloy of cadmium telluride and zinc telluride. A direct bandgap semiconductor, it is used in a variety of applications, including Semiconductor detector, semiconductor radiation detectors, photorefraction, photorefractive gratings, electro-optic modulators, solar cells, and Terahertz radiation, terahertz generation and detection. The band gap varies from approximately 1.4 to 2.2 electronvolt, eV, depending on composition. Characteristics Radiation detectors using CZT can operate in direct-conversion (or photoconductive) mode at room temperature, unlike some other materials (particularly germanium) which require cooling. Their relative advantages include high sensitivity for X-rays and gamma rays, due to the high atomic numbers of Cd and Te, and better energy resolution than Scintillator, scintillator detectors. CZT can be formed into different shapes for differ ...
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Molecular Beam Epitaxy
Molecular-beam epitaxy (MBE) is an epitaxy method for thin-film deposition of single crystals. MBE is widely used in the manufacture of semiconductor devices, including transistors. MBE is used to make diodes and MOSFETs (MOS field-effect transistors) at microwave frequencies, and to manufacture the lasers used to read optical discs (such as CDs and DVDs). History The original ideas of the MBE process were first established by K. G. Günther. Films that he deposited were not epitaxial, but were deposited on glass substrates. With the development of vacuum technology, the MBE process was demonstrated by John Davey and Titus Pankey who succeeded in growing GaAs epitaxial films on single crystal GaAs substrates using Günther's method. Major subsequent development of MBE films was enabled by J.R. Arthur's investigations of kinetic behavior of growth mechanisms and Alfred Y. Cho's in situ observation of MBE process using reflection high-energy electron diffraction (RHEED) in the ...
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Infrared Astronomy
Infrared astronomy is a sub-discipline of astronomy which specializes in the astronomical observation, observation and analysis of astronomical objects using infrared (IR) radiation. The wavelength of infrared light ranges from 0.75 to 300 micrometers, and falls in between Visible light, visible radiation, which ranges from 380 to 750 nanometers, and terahertz radiation, submillimeter waves. Infrared astronomy began in the 1830s, a few decades after the discovery of infrared light by William Herschel in 1800. Early progress was limited, and it was not until the early 20th century that conclusive detections of astronomical objects other than the Sun and Moon were made in infrared light. After a number of discoveries were made in the 1950s and 1960s in radio astronomy, astronomers realized the information available outside the visible wavelength range, and modern infrared astronomy was established. Infrared and optical astronomy are often practiced using the same telescopes, as the ...
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Mercury (element)
Mercury is a chemical element; it has Symbol (chemistry), symbol Hg and atomic number 80. It is commonly known as quicksilver. A Heavy metal element, heavy, silvery d-block element, mercury is the only metallic element that is known to be liquid at standard temperature and pressure; the only other element that is liquid under these conditions is the halogen bromine, though metals such as caesium, gallium, and rubidium melt just above room temperature. Mercury occurs in deposits throughout the world mostly as cinnabar (mercuric sulfide). The red pigment vermilion is obtained by Mill (grinding), grinding natural cinnabar or synthetic mercuric sulfide. Exposure to mercury and mercury-containing organic compounds is toxic to the nervous system, immune system and kidneys of humans and other animals; mercury poisoning can result from exposure to water-soluble forms of mercury (such as mercuric chloride or methylmercury) either directly or through mechanisms of biomagnification. Mercu ...
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Infrared Imaging
Infrared thermography (IRT), thermal video or thermal imaging, is a process where a thermal camera captures and creates an image of an object by using infrared radiation emitted from the object in a process, which are examples of infrared imaging science. Thermographic cameras usually detect radiation in the long-infrared range of the electromagnetic spectrum (roughly 9,000–14,000 nanometers or 9–14 μm) and produce images of that radiation, called thermograms. Since infrared radiation is emitted by all objects with a temperature above absolute zero according to the black body Planck's law of black-body radiation, radiation law, thermography makes it possible to see one's environment with or without optical spectrum, visible illumination. The amount of radiation emitted by an object increases with temperature; therefore, thermography allows one to see variations in temperature. When viewed through a thermal imaging camera, warm objects stand out well against cooler backgr ...
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Infrared Detector
An infrared detector is a detector that reacts to infrared (IR) radiation. The two main types of detectors are thermal and photonic (photodetectors). The thermal effects of the incident IR radiation can be followed through many temperature dependent phenomena. Bolometers and microbolometers are based on changes in resistance. Thermocouples and thermopiles use the thermoelectric effect. Golay cells follow thermal expansion. In IR spectrometers the pyroelectric detectors are the most widespread. The response time and sensitivity of photonic detectors can be much higher, but usually these have to be cooled to cut thermal noise. The materials in these are semiconductors with narrow band gaps. Incident IR photons can cause electronic excitations. In photoconductive detectors, the resistivity of the detector element is monitored. Photovoltaic detectors contain a p-n junction on which photoelectric current appears upon illumination. An infrared detector is hybridized by connecting ...
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