Hollandite Supergroup
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Hollandite Supergroup
Hollandite (chemical formula: Ba(Mn4+6Mn3+2)O16) is a manganese oxide mineral. Its structure consists of double chains of MnO6 octahedra delimiting 2 × 2 tunnels. The electrostatic charge created by the Mn3+ for Mn4+ substitution is balanced by cations in the tunnels. Their nature determines the mineral species: Ba for hollandite, K for cryptomelane, Pb for coronadite, Sr for strontiomelane, Tl for thalliomelane, and Na for manjiroite. Pure species are rare and most 2 × 2 tectomanganates contain mixtures of several types of tunnel cations. A mineral, with the chemical composition BaMn4+6Fe3+2O16, that was first found in the Kajlidongri mine in the Jhabua district of Madhya Pradesh, India, had the name ''hollandite'' until it was reclassified as ''ferrihollandite'' by the International Mineralogical Association in 2012. Ferrihollandite is the barium-iron (III) endmember of the coronadite group. File:Hollandite_star_in_quartz.jpg, Hollandite star in rare quartz inclusion File ...
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Oxide Minerals
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. Minerals with complex anion groups such as the Silicate mineral, silicates, Sulfate mineral, sulfates, carbonate mineral, carbonates and Phosphate mineral, phosphates are classed separately. Simple oxides *XO form **Periclase group ***Periclase ***Manganosite **Zincite group ***Zincite ***Bromellite ***Tenorite ***Litharge * form **Cuprite **Ice * form **Hematite group ***Corundum ***Hematite ***Ilmenite * form **Rutile group ***Rutile ***Pyrolusite ***Cassiterite **Baddeleyite **Uraninite **Thorianite * form **Spinel group ***Spinel ***Gahnite ***Magnetite ***Franklinite ***Chromite **Chrysoberyl **Columbite *Hydroxide subgroup: **Brucite **Manganite **Romanèchite **Goethite group: ***Diaspore ***Goethite Nickel–Strunz class 4: oxides Internationa ...
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Monoclinic
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three Vector (geometric), vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism (geometry), prism. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°. Bravais lattices Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic. For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;See , row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. The length a of the primitive cell below equals \frac \sqrt of the conventional cell above. Crystal class ...
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Space Group
In mathematics, physics and chemistry, a space group is the symmetry group of a repeating pattern in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of the pattern that leave it unchanged. In three dimensions, space groups are classified into 219 distinct types, or 230 types if chiral copies are considered distinct. Space groups are discrete cocompact groups of isometries of an oriented Euclidean space in any number of dimensions. In dimensions other than 3, they are sometimes called Bieberbach groups. In crystallography, space groups are also called the crystallographic or Fedorov groups, and represent a description of the symmetry of the crystal. A definitive source regarding 3-dimensional space groups is the ''International Tables for Crystallography'' . History Space groups in 2 dimensions are the 17 wallpaper groups which have been known for several centuries, though the proof that the list ...
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Oxide Mineral
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. Minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. Simple oxides *XO form **Periclase group *** Periclase *** Manganosite **Zincite group *** Zincite *** Bromellite *** Tenorite *** Litharge * form ** Cuprite **Ice * form **Hematite group ***Corundum ***Hematite *** Ilmenite * form **Rutile group ***Rutile *** Pyrolusite *** Cassiterite ** Baddeleyite ** Uraninite ** Thorianite * form **Spinel group ***Spinel ***Gahnite ***Magnetite *** Franklinite ***Chromite ** Chrysoberyl ** Columbite *Hydroxide subgroup: **Brucite ** Manganite ** Romanèchite **Goethite group: *** Diaspore ***Goethite Nickel–Strunz class 4: oxides IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 20 ...
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Cryptomelane
Cryptomelane (K(Mn4+,Mn2+)8O16) is the potassium endmember of the hollandite group, a family of tectomanganates with a 2 × 2 tunnel structure. In 1942 the name ''cryptomelane'' was proposed as part of an effort to sort out the manganese oxide minerals referred to as ''psilomelane''. Cryptomelane was identified and defined based on X-ray diffraction studies of samples from Tombstone, Arizona; Deming, New Mexico; Mena, Arkansas; and Philipsburg, Montana. Cryptomelane was approved in 1982 by the International Mineralogical Association (IMA). The type locality is the Tombstone District, Cochise County, Arizona, US. The name comes from the Greek for hidden and black, in reference to the confusion and difficulty in recognition of the various black manganese oxide minerals referred to as ''psilomelane'', the collective term for hard manganese oxides. It is of rather common occurrence in oxidized manganese deposits where it occurs as replacements and open space fillings in veins and ...
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Coronadite
Coronadite is the lead endmember of the coronadite group, a family of tectomanganates with a 2 × 2 tunnel structure. The mineral was named after Francisco Vasquez de Coronado who was an explorer of southwest US. The name was made up by Waldemar Lindgren in 1905. It is chemically related to ferricoronadite, an analogue, as well as cryptomelane, hollandite Hollandite (chemical formula: Ba(Mn4+6Mn3+2)O16) is a manganese oxide mineral. Its structure consists of double chains of MnO6 octahedra delimiting 2 × 2 tunnels. The electrostatic charge created by the Mn3+ for Mn4+ substitution is balanced by ..., manjiroite and strontiomelane. File:Hollandite.jpg, Polyhedral representation of the 2 × 2 tunnel structure of coronadite. The black atoms represent Pb. References {{Reflist Manganese minerals Lead minerals Minerals described in 1904 ...
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Madhya Pradesh
Madhya Pradesh (; ; ) is a state in central India. Its capital is Bhopal and the largest city is Indore, Indore. Other major cities includes Gwalior, Jabalpur, and Sagar, Madhya Pradesh, Sagar. Madhya Pradesh is the List of states and union territories of India by area, second largest Indian state by area and the List of states and union territories of India by population, fifth largest state by population with over 72 million residents. It borders the states of Rajasthan to the northwest, Uttar Pradesh to the northeast, Chhattisgarh to the east, Maharashtra to the south, Gujarat to the west. The area covered by the present-day Madhya Pradesh includes the area of the ancient Avanti (India), Avanti Mahajanapada, whose capital Ujjain (also known as Avantika) arose as a major city during the second wave of Indian urbanisation in the sixth century BCE. Subsequently, the region was ruled by the major dynasties of India. The Maratha Confederacy, Maratha Empire dominated the maj ...
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International Mineralogical Association
Founded in 1958, the International Mineralogical Association (IMA) is an international group of 40 national societies. The goal is to promote the science of mineralogy and to standardize the nomenclature of the 5000 plus known mineral species. The IMA is affiliated with the International Union of Geological Sciences (IUGS). The Association supports the activities of Commissions and Working Groups involved on certain aspects of mineralogical practice and facilitates interactions among mineralogists by sponsoring and organising meetings. In particular, the IMA holds its general meeting every four years. The last meeting was scheduled in 2022 in Lyon, France. Presidents The presidents of the IMA have been: * since 2024: Eiji Ohtani ** Tohoku University * 2022–2024: Hans-Peter Schertl ** Bochum University * 2020–2022: Anhuai Lu ** Peking University *2018–2020: Patrick Cordier ** Université de Lille *2016–2018: Peter C. Burns ** University of Notre Dame *2014–2016 ...
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Manganese Dioxide
Manganese dioxide is the inorganic compound with the formula . This blackish or brown solid occurs naturally as the mineral pyrolusite, which is the main ore of manganese and a component of manganese nodules. The principal use for is for dry-cell batteries, such as the alkaline battery and the zinc–carbon battery, although it is also used for other battery chemistries such as aqueous zinc-ion batteries.. is also used as a pigment and as a precursor to other manganese compounds, such as . It is used as a reagent in organic synthesis, for example, for the oxidation of allylic alcohols. has an α- polymorph that can incorporate a variety of atoms (as well as water molecules) in the "tunnels" or "channels" between the manganese oxide octahedra. There is considerable interest in as a possible cathode for lithium-ion batteries. Structure Several polymorphs of are claimed, as well as a hydrated form. Like many other dioxides, crystallizes in the rutile crystal structure (t ...
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Barium Minerals
Barium is a chemical element; it has symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. The most common minerals of barium are barite (barium sulfate, BaSO4) and witherite ( barium carbonate, BaCO3). The name ''barium'' originates from the alchemical derivative "baryta", from Greek (), meaning 'heavy'. ''Baric'' is the adjectival form of barium. Barium was identified as a new element in 1772, but not reduced to a metal until 1808 with the advent of electrolysis. Barium has few industrial applications. Historically, it was used as a getter for vacuum tubes and in oxide form as the emissive coating on indirectly heated cathodes. It is a component of YBCO (high-temperature superconductors) and electroceramics, and is added to steel and cast iron to reduce the size of carbon grains within the microstructure. Barium compounds a ...
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