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Gold Phosphide
Gold phosphides are inorganic compounds of gold and phosphorus. The only known gold phosphide is a metastable gold(I) polyphosphide with the formula . Older texts sometimes refer to a binary auric phosphide ; this hypothetical compound has not been verified by modern methods such as X-ray crystallography. Preparation Monoclinic is produced by direct reaction between metallic gold and red phosphorus at high temperatures over multiple days. The reaction produced only , with no other compounds observed across a wide variety of Au:P atom ratios. Gold(III) phosphide was purportedly prepared by the direct reaction of spongy gold and phosphorus or by passing phosphine into a solution of auric chloride in ether or alcohol: : Properties is claimed to decompose in air or with . It has a monoclinic crystal structure. Related A mixed anion phosphide iodide, , is known to possess a trigonal In crystallography, the hexagonal crystal family is one of the six crystal family, crystal ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inorganic Compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bondsthat is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep Mantle (geology), mantle remain active areas of investigation. All allotropes (structurally different pure forms of an element) and some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, graphene, etc.), carbon monoxide , carbon dioxide , carbides, and salt (chemistry), salts of inorganic anions such as carbonates, cyanides, cyanates, thiocyanates, isothiocyanates, etc. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it cannot occur within life, living things. History ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Auric Chloride
Gold(III) chloride, traditionally called auric chloride, is an inorganic compound of gold and chlorine with the molecular formula . The "III" in the name indicates that the gold has an oxidation state of +3, typical for many gold compounds. It has two forms, the monohydrate (AuCl3·H2O) and the anhydrous form, which are both hygroscopic and light-sensitive solids. This compound is a Dimer (chemistry), dimer of . This compound has a few uses, such as an oxidizing agent and for Catalysis, catalyzing various Organic chemistry, organic reactions. Structure exists as a bridging ligand, chloride-bridged Wiktionary:dimer, dimer both as a solid and vapour, at least at low temperatures. Gold(III) bromide behaves analogously. The structure is similar to that of iodine(III) chloride. Each gold center is square planar in gold(III) chloride, which is typical of a metal complex with a d electron count, d8 electron count. The bonding in is considered somewhat covalent bond, covalent. Prop ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phosphides
In chemistry, a phosphide is a compound containing the ion or its equivalent. Many different phosphides are known, with widely differing structures. Most commonly encountered on the binary phosphides, i.e. those materials consisting only of phosphorus and a less electronegative element. Numerous are polyphosphides, which are solids consisting of anionic chains or clusters of phosphorus. Phosphides are known with the majority of less electronegative elements with the exception of Hg, Pb, Sb, Bi, Te, and Po.Von Schnering, H.G. and Hönle , W. (1994) "Phosphides - Solid-state Chemistry" in ''Encyclopedia of Inorganic Chemistry''. R. Bruce King (ed.). John Wiley & Sons Finally, some phosphides are molecular. Binary phosphides Binary phosphides include phosphorus and one other element. An example of a group 1 phosphide is sodium phosphide (). Other notable examples include aluminium phosphide () and calcium phosphide (), which are used as pesticides, exploiting their tend ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gold Compounds
Gold compounds are compounds by the element gold (Au). Although gold is the most noble of the noble metals, it still forms many diverse compounds. The oxidation state of gold in its compounds ranges from −1 to +5, but Au(I) and Au(III) dominate its chemistry. Au(I), referred to as the aurous ion, is the most common oxidation state with soft ligands such as thioethers, thiolates, and organophosphines. Au(I) compounds are typically linear. A good example is , which is the soluble form of gold encountered in mining. The binary gold halides, such as gold(I) chloride, AuCl, form zigzag polymeric chains, again featuring linear coordination at Au. Most drugs based on gold are Au(I) derivatives. Au(III) (referred to as the auric) is a common oxidation state, and is illustrated by gold(III) chloride, . The gold atom centers in Au(III) complexes, like other d8 compounds, are typically square planar, with chemical bonds that have both covalent and ionic character. Gold(I,III) chloride is a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Trigonal
In crystallography, the hexagonal crystal family is one of the six crystal family, crystal families, which includes two crystal systems (hexagonal and trigonal) and two lattice systems (hexagonal and rhombohedral). While commonly confused, the trigonal crystal system and the rhombohedral lattice system are not equivalent (see section hexagonal crystal family#Crystal systems, crystal systems below). In particular, there are crystals that have trigonal symmetry but belong to the hexagonal lattice (such as α-quartz). The hexagonal crystal family consists of the 12 point groups such that at least one of their space groups has the hexagonal lattice as underlying lattice, and is the union of the hexagonal crystal system and the trigonal crystal system. There are 52 space groups associated with it, which are exactly those whose Bravais lattice is either hexagonal or rhombohedral. __TOC__ Lattice systems The hexagonal crystal family consists of two lattice systems: hexagonal and rhom ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phosphide Iodide
Phosphide iodides or iodide phosphides are compounds containing anions composed of iodide (I−) and phosphide (P3−). They can be considered as mixed anion compounds Mixed-anion compounds, heteroanionic materials or mixed-anion materials are chemical compounds containing cations and more than one kind of anion. The compounds contain a single phase, rather than just a mixture. Use in materials science By having .... They are in the category of pnictidehalides. Related compounds include the phosphide chlorides, arsenide iodides antimonide iodides and phosphide bromides. Phosphorus can form clusters or chains in these compounds, so that some are 1-dimensional or fibrous. Phosphide iodides are often metallic, black or dark red in colour. List References {{iodides Phosphides Iodides Mixed anion compounds ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Monoclinic
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three Vector (geometric), vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism (geometry), prism. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°. Bravais lattices Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic. For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;See , row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. The length a of the primitive cell below equals \frac \sqrt of the conventional cell above. Crystal class ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Macmillan & Company
Macmillan Publishers (occasionally known as the Macmillan Group; formally Macmillan Publishers Ltd in the United Kingdom and Macmillan Publishing Group, LLC in the United States) is a British publishing company traditionally considered to be one of the "Big Five" English language publishers (along with Penguin Random House, Hachette, HarperCollins and Simon & Schuster). Founded in London in 1843 by Scottish brothers Daniel and Alexander MacMillan, the firm soon established itself as a leading publisher in Britain. It published two of the best-known works of Victorian-era children's literature, Lewis Carroll's ''Alice's Adventures in Wonderland'' (1865) and Rudyard Kipling's ''The Jungle Book'' (1894). Former Prime Minister of the United Kingdom, Harold Macmillan, grandson of co-founder Daniel, was chairman of the company from 1964 until his death in December 1986. Since 1999, Macmillan has been a wholly owned subsidiary of Holtzbrinck Publishing Group with offices in 41 coun ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quarterly Journal Of The Chemical Society Of London
The ''Journal of the Chemical Society'' was a scientific journal established by the Chemical Society in 1849 as the ''Quarterly Journal of the Chemical Society''. The first editor was Edmund Ronalds. The journal underwent several renamings, splits, and mergers throughout its history. In 1980, the Chemical Society merged with several other organizations into the Royal Society of Chemistry. The journal's continuity is found in ''Chemical Communications'', ''Dalton Transactions'', '' Faraday Transactions'', and ''Perkin Transactions'', all of which are published by the Royal Society of Chemistry. History ;'' Proceedings of the Chemical Society'' * ''Memoirs of the Chemical Society of London'' (1841) * ''Proceedings of the Chemical Society of London'' (1842–1843) * ''Memoirs and Proceedings of the Chemical Society'' (1843–1848) * ''Proceedings of the Chemical Society, London'' (1885–1914) * Published as a supplement to ''Journal of the Chemical Society'' from 1914 to 1956 * ''Pro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
John Churchill (publisher)
John Spriggs Morss Churchill (1801–1875) was an English medical publisher. Life The third son of the Rev. James Churchill (1770–1820), a dissenting minister, by his wife Mary née Morss (1775–1820), a daughter of George Morss, he was born at Ongar in Essex, 4 August 1801. He was educated at Henley grammar school, under the Rev. Dr. George Scobell. In 1816 Churchill was bound an apprentice for seven years to Elizabeth Cox & Son, medical booksellers, of 39 High Street, Southwark. Having served his time he became a freeman of the Stationers' Company, and then for about eighteen months was employed in the house of Longman & Co. With the fortune of his wife, whom he married in 1832, Churchill started in business on his own account, purchasing the old-established retail connection of Callow & Wilson, 16 Princes Street, Leicester Square. Churchill attended book sales and the sales of medical libraries all over the country, and issued an annual catalogue. The business increased ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phosphine
Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula , classed as a pnictogen hydride. Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane (). With traces of present, is spontaneously flammable in air ( pyrophoric), burning with a luminous flame. Phosphine is a highly toxic respiratory poison, and is immediately dangerous to life or health at 50 ppm. Phosphine has a trigonal pyramidal structure. Phosphines are compounds that include and the organophosphines, which are derived from by substituting one or more hydrogen atoms with organic groups. They have the general formula . Phosphanes are saturated phosphorus hydrides of the form , such as triphosphane. Phosphine () is the smallest of the phosphines and the smallest of the phosphanes. History Philippe Gengembre (1764–1838), a student of Lavoisi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gold
Gold is a chemical element; it has chemical symbol Au (from Latin ) and atomic number 79. In its pure form, it is a brightness, bright, slightly orange-yellow, dense, soft, malleable, and ductile metal. Chemically, gold is a transition metal, a group 11 element, and one of the noble metals. It is one of the least reactivity (chemistry), reactive chemical elements, being the second-lowest in the reactivity series. It is solid under standard temperature and pressure, standard conditions. Gold often occurs in free elemental (native state (metallurgy), native state), as gold nugget, nuggets or grains, in rock (geology), rocks, vein (geology), veins, and alluvial deposits. It occurs in a solid solution series with the native element silver (as in electrum), naturally alloyed with other metals like copper and palladium, and mineral inclusions such as within pyrite. Less commonly, it occurs in minerals as gold compounds, often with tellurium (gold tellurides). Gold is resistant to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
