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Cornwallite
Cornwallite is an uncommon copper arsenate mineral with formula Cu5(AsO4)2(OH)4. It forms a series with the phosphate pseudomalachite and is a dimorph of the triclinic cornubite. It is a green monoclinic mineral which forms as radial to fibrous encrustations. Discovery and occurrence It was first described in 1846, for an occurrence in Wheal Gorland, St Day United Mines of the St Day District, Cornwall, England. It occurs as secondary mineral in the oxidized zone of copper sulfide deposits. Associated minerals include olivenite, cornubite, arthurite, clinoclase, chalcophyllite, strashimirite, lavendulan, tyrolite, spangolite, austinite, conichalcite, brochantite, azurite and malachite Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fracture .... See also * Kernowite, another min ...
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Arsenate Mineral
Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO4)3− anion group and, more rarely, other arsenates with anions like AsO3(OH)2− (also written HAsO42−) (example: pharmacolite Ca(AsO3OH).2H2O) or (very rarely) sO2(OH)2sup>− (example: andyrobertsite). Arsenite minerals are much less common. Both the Dana and the Strunz mineral classifications place the arsenates in with the phosphate minerals. Example arsenate minerals include: *Annabergite Ni3(AsO4)2·8H2O * Austinite CaZn(AsO4)(OH) * Clinoclase Cu3(AsO4)(OH)3 * Conichalcite CaCu(AsO4)(OH) *Cornubite Cu5(AsO4)2(OH)4 * Cornwallite Cu2+5(AsO4)2(OH)2 * Erythrite Co3(AsO4)2·8H2O * Mimetite Pb5(AsO4)3Cl * Olivenite Cu2(AsO4)OH Nickel–Strunz Classification -08- Phosphates IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify the Classification of Nickel–Strunz (mindat.org, 10 ed, pending publication). *Abbreviations: **"*" - discred ...
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Kernowite
Kernowite is a mineral which was first described in 2020. It is named for Cornwall, which in the Cornish language is ''Kernow''. Description Kernowite is a complex arsenate mineral with the composition . It was first described in 2020, and is closely related to liroconite, containing iron in the place of aluminium, making it green rather than blue. Its name is derived from ''Kernow'', the name of Cornwall in the Cornish language, after being discovered in a rock mined .1800 in the Wheal Gorland mine, St Day, Cornwall. See also *Cornwallite Cornwallite is an uncommon copper arsenate mineral with formula Cu5(AsO4)2(OH)4. It forms a series with the phosphate pseudomalachite and is a dimorph of the triclinic cornubite. It is a green monoclinic mineral which forms as radial to fibrous e ... – a mineral also named after Cornwall References Further reading * {{Cite journal, journal=Mineralogical Magazine, publisher=Cambridge University Press, title=Newsletter 58, doi=10 ...
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Cornubite
Cornubite is a rare secondary copper arsenate mineral with formula: Cu5(AsO4)2(OH)4. It was first described for its discovery in 1958 in Wheal Carpenter, Gwinear, Cornwall, England, UK.Claringbull, Hey and Davis, ''American Mineralogist'' (1959) 44: 1321 The name is from Cornubia, the medieval Latin name for Cornwall. It is a dimorph of Cornwallite, and the arsenic analogue of pseudomalachite. Physical properties Cleavage is distinct in two directions, both perpendicular to the enlarged faces of the tabular crystals, intersecting at about 70°. Cornubite is fairly soft, with hardness 4, the same as fluorite, and specific gravity 4.64, which is similar to another copper arsenate, clinoclase, at 4.38, but much denser than quartz, at 2.66. Optical properties All triclinic minerals are biaxial; cornubite is biaxial (-). Its refractive indices are quite high, close to 1.9, similar to zircon and garnet. It is green, as are many copper minerals, usually translucen ...
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Arthurite
Arthurite is a mineral composed of divalent copper and iron ions in combination with trivalent arsenate, phosphate and sulfate ions with hydrogen and oxygen.Frost R. L., Duong L., Martens W. (2003) Molecular assembly in secondary minerals - Raman spectroscopy of the arthurite group species arthurite and whitmoreite. Neues Jahrbuch für Mineralogie, Monatshefte, 2003, 223-240. Initially discovered by Sir Arthur Russell in 1954 at Hingston Down Consols mine in Calstock, Cornwall, England,Davis, R. J. & Hey, M. H. (1964) Arthurite, a new copper-iron arsenate from Cornwall. '' Mineralogical Magazine'', 33, 937-941. arthurite is formed as a resultant mineral in the oxidation region of some copper deposits by the variation of enargite or arsenopyrite. The chemical formula of Arthurite is Cu Fe23+( As O4, P O4, S O4)2( O, O H)2•4 H2 O.Palmer, S.J., Frost R.L. (2011) The structure of the mineral arthurite CuFe23+(AsO4,PO4,SO4)2(O,OH)2·4H2O – A Raman spectroscopic study. Jo ...
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Malachite
Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures and deep, underground spaces, where the water table and hydrothermal fluids provide the means for chemical precipitation. Individual crystals are rare, but occur as slender to acicular prisms. Pseudomorphs after more tabular or blocky azurite crystals also occur. Etymology and history The stone's name derives (via la, molochītis, frm, melochite, and Middle English ''melochites'') from Greek Μολοχίτης λίθος ''molochites lithos'', "mallow-green stone", from μολόχη ''molochē'', variant of μαλάχη ''malāchē'', "mallow". The mineral was given this name due to its resemblance to the leaves of the mallow plant. Malachite was mined from deposits near the Isthmus of Suez and the Sinai as early as 4000 BCE. ...
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Azurite
Azurite is a soft, deep-blue copper mineral produced by weathering of copper ore deposits. During the early 19th century, it was also known as chessylite, after the type locality at Chessy-les-Mines near Lyon, France. The mineral, a basic carbonate with the chemical formula Cu3(CO3)2(OH)2, has been known since ancient times, and was mentioned in Pliny the Elder's '' Natural History'' under the Greek name (κυανός: "deep blue," root of English ''cyan'') and the Latin name ''caeruleum''. Since antiquity, azurite's exceptionally deep and clear blue has been associated with low-humidity desert and winter skies. The modern English name of the mineral reflects this association, since both ''azurite'' and ''azure'' are derived via Arabic from the Persian (لاژورد), an area known for its deposits of another deep-blue stone, lapis lazuli ("stone of azure"). Mineralogy Azurite has the formula Cu3(CO3)2(OH)2, with the copper(II) cations linked to two different anions, ca ...
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Brochantite
Brochantite is a sulfate mineral, one of a number of cupric sulfates. Its chemical formula is Cu4SO4(OH)6. Formed in arid climates or in rapidly oxidizing copper sulfide deposits, it was named by Armand Lévy for his fellow Frenchman, geologist and mineralogist A. J. M. Brochant de Villiers. Crystals of brochantite can range from emerald green to black-green to blue-green, and can be acicular or prismatic. Brochantite is often associated with minerals such as malachite, azurite, and chrysocolla, and may form pseudomorphs with these minerals. The mineral is found in a number of locations around the world, notably the southwestern United States (especially Arizona), Serifos in Greece and Chile. Brochantite is a common corrosion product on bronze sculptures located in urban areas, where atmospheric sulfur dioxide (a common pollutant) is present. Brochantitie forms mainly in exposed areas where weathering prevents accumulation copper ions and enhancement in the acidity of w ...
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Conichalcite
Conichalcite, Ca Cu( As O4)(O H), is a relatively common arsenate mineral related to duftite ( PbCu(AsO4)(OH)). It is green, often botryoidal, and occurs in the oxidation zone of some metal deposits. It occurs with limonite, malachite, beudantite, adamite, cuproadamite, olivenite and smithsonite. Formation Conichalcite forms in the oxidation zones of copper orebodies. Here groundwater enriched with oxygen reacts with copper sulfide and copper oxide to produce an array of minerals such as malachite Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fracture ..., azurite and linarite. Conichalcite is often found encrusted on to limonitic rocks that have yellow to red colors. Conichalcite will also form a solid solution series with the mineral calciovolborthite. When these two miner ...
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Austinite
Austinite is a member of the adelite-descloizite group, adelite subgroup, the zinc (Zn) end member of the copper-Zn series with conichalcite. It is the zinc analogue of cobaltaustinite and nickelaustinite. At one time “brickerite” was thought to be a different species, but it is now considered to be identical to austinite. Austinite is named in honour of Austin Flint Rogers (1877–1957), American mineralogist from Stanford University, California, US. Structure The structure is composed of chains of edge-sharing polyhedra ZnO6, and very distorted Ca(O,OH)8 polyhedra linked through AsO4 into a three-dimensional network.Gaines ''et al.'' (1997) Dana’s New Mineralogy Eighth Edition, Wiley Any crystal which has a mirror plane as one of its symmetry elements has the property that its mirror image (with any plane as the mirror plane) can always be superimposed on the original crystal by translation or rotation or both. If there are no mirror planes as symmetry elements then ...
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Tyrolite
Tyrolite is a hydrated calcium copper arsenate carbonate mineral with formula: Ca Cu5( As O4)2 CO3(O H)4·6 H2O. Tyrolite forms glassy blue to green orthorhombic In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a r ... radial crystals and botryoidal masses. It has a Mohs hardness of 1.5 to 2 and a specific gravity of 3.1 to 3.2. It is translucent with refractive indices of nα=1.694 nβ=1.726 and nγ=1.730. It is a secondary mineral formed by the weathering of associated copper and arsenic minerals. It was first described in 1845 for an occurrence in Schwaz, Tyrol, Austria. References WebmineralMindat with location data


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