Brochantite
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Brochantite is a
sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
, one of a number of cupric sulfates. Its chemical formula is Cu4SO4(OH)6. Formed in arid climates or in rapidly oxidizing copper sulfide deposits, it was named by Armand Lévy for his fellow
Frenchman French people () are a nation primarily located in Western Europe that share a common French culture, history, and language, identified with the country of France. The French people, especially the native speakers of langues d'oïl from nort ...
,
geologist A geologist is a scientist who studies the structure, composition, and History of Earth, history of Earth. Geologists incorporate techniques from physics, chemistry, biology, mathematics, and geography to perform research in the Field research, ...
and
mineralogist Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical mineralogy, optical) properties of minerals and mineralized artifact (archaeology), artifacts. Specific s ...
A. J. M. Brochant de Villiers.
Crystals A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macrosc ...
of brochantite can range from
emerald Emerald is a gemstone and a variety of the mineral beryl (Be3Al2(SiO3)6) colored green by trace amounts of chromium or sometimes vanadium.Hurlbut, Cornelius S. Jr., and Kammerling, Robert C. (1991). ''Gemology'', John Wiley & Sons, New York ...
green to black-green to blue-green, and can be acicular or prismatic. Brochantite is often associated with minerals such as
malachite Malachite () is a copper Carbonate mineral, carbonate hydroxide mineral, with the chemical formula, formula Basic copper carbonate, Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often for ...
,
azurite Azurite or '' Azure spar'Krivovichev V. G.'' Mineralogical glossary. Scientific editor A. G. Bulakh. — St.Petersburg: St.Petersburg Univ. Publ. House. 2009. — 556 p. — ISBN 978-5-288-04863-0. ''(in Russian)'' is a soft, deep-blue copp ...
, and
chrysocolla Chrysocolla ( ) is a hydrous copper phyllosilicate mineral and mineraloid with the formula (''x'' < 1) or . The structure of the mineral has been questioned, as a 2006 spectrographic study suggest ma ...
, and may form pseudomorphs with these minerals. The mineral is found in a number of locations around the world, notably the southwestern
United States The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...
(especially
Arizona Arizona is a U.S. state, state in the Southwestern United States, Southwestern region of the United States, sharing the Four Corners region of the western United States with Colorado, New Mexico, and Utah. It also borders Nevada to the nort ...
),
Serifos Serifos () is a Greek island in the Aegean Sea, located in the western Cyclades, south of Kythnos and northwest of Sifnos. It is part of the Milos regional unit. The area is and the population was 1,241 at the 2021 census. It is located about ...
in
Greece Greece, officially the Hellenic Republic, is a country in Southeast Europe. Located on the southern tip of the Balkan peninsula, it shares land borders with Albania to the northwest, North Macedonia and Bulgaria to the north, and Turkey to th ...
and
Chile Chile, officially the Republic of Chile, is a country in western South America. It is the southernmost country in the world and the closest to Antarctica, stretching along a narrow strip of land between the Andes, Andes Mountains and the Paci ...
. Brochantite is a common corrosion product on bronze sculptures located in urban areas, where atmospheric sulfur dioxide (a common pollutant) is present. Brochantite forms mainly in exposed areas where weathering prevents accumulation copper ions and enhancement in the acidity of water films.Leygraf C, Graedel TE. Atmospheric corrosion. New York: Wiley-Interscience; 2000. In sheltered areas, the main corrosion product is
antlerite Antlerite is a greenish hydrous copper sulfate mineral, with the formula Cu3(SO4)(OH)4. It occurs in tabular, Acicular (crystal habit), acicular, or fibrous crystals with a vitreous lustre, vitreous luster. Originally believed to be a rare minera ...
.


Gallery

File:Brochantite-md75b.jpg, These long slender crystals, from
Bisbee, Arizona Bisbee is a city in and the county seat of Cochise County, Arizona, Cochise County in southeastern Arizona, United States. It is southeast of Tucson, Arizona, Tucson and north of the Mexican border. According to the 2020 United States census, ...
, have the highly desirable emerald green color and good luster that is sought after in brochantite by collectors. Detail of thumbnail specimen, size 2.3 × 2 × .8 cm. File:Brochantite-Chrysocolla-k329b.jpg, Brochantite on
chrysocolla Chrysocolla ( ) is a hydrous copper phyllosilicate mineral and mineraloid with the formula (''x'' < 1) or . The structure of the mineral has been questioned, as a 2006 spectrographic study suggest ma ...
. Locality: Rokana Mine, Kitwe,
Copperbelt Province Copperbelt Province is a province in Zambia which covers the mineral-rich Copperbelt, and farming and bush areas to the south. It was the backbone of the Northern Rhodesian economy during British colonial rule and fuelled the hopes of the imme ...
,
Zambia Zambia, officially the Republic of Zambia, is a landlocked country at the crossroads of Central Africa, Central, Southern Africa, Southern and East Africa. It is typically referred to being in South-Central Africa or Southern Africa. It is bor ...
. Detail of larger specimen, field of view about 3 × 5 cm. File:Brochantite-Linarite-20434.jpg, Brochantite on
linarite Linarite is a somewhat rare, crystalline mineral that is known among mineral collectors for its unusually intense, pure blue color. It is formed by the oxidation of galena and chalcopyrite and other copper sulfides. It is a combined copper lead s ...
. Locality: Mujuram,
Morocco Morocco, officially the Kingdom of Morocco, is a country in the Maghreb region of North Africa. It has coastlines on the Mediterranean Sea to the north and the Atlantic Ocean to the west, and has land borders with Algeria to Algeria–Morocc ...
. Size 8 × 8 cm.


References


External links

{{EB1911 poster, Brochantite Copper(II) minerals Sulfate minerals Monoclinic minerals Minerals in space group 14