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Chloryl Tetraperchloratoaurate
Chloryl tetraperchloratoaurate is an inorganic chemical compound with the formula consisting of the chloryl cation and a tetraperchloratoaurate(III) anion. It is an orange solid that readily hydrolyzes in air. Production and reactions Chloryl tetraperchloratoaurate is produced by the oxidation of gold metal, gold(III) chloride, or chloroauric acid by dichlorine hexoxide Dichlorine hexoxide is the chemical compound with the molecular formula or , which is correct for its gaseous state. However, in liquid or solid form, this chlorine oxide ionizes into the dark red ionic compound chloryl perchlorate or dioxochlor ...: : A production of gold(III) perchlorate is attempted by heating this compound, but it instead forms an oxy-perchlorato derivative. References {{perchlorates Gold(III) compounds Perchlorates chloryl compounds ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Monoclinic Crystal System
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°. Bravais lattices Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic. For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;See , row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. The length a of the primitive cell below equals \frac \sqrt of the conventional cell above. Crystal classes The table below organizes the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chloryl
In chemistry, chloryl refers to a triatomic cation with chemical formula . This species has the same general structure as chlorite () but it is electronically different, with chlorine having a +5 oxidation state (rather than the +3 of chlorite). This makes it a rare example of a positively charged oxychloride. Chloryl compounds, such as and lO2RuF6], are all highly reactive and react violently with water and most organic compounds. Structure The cation is isoelectronic with , and has a bent structure with a bond angle close to 120°. The Cl–O bond is of bond order 1.5, with its Lewis structure consisting of a double bond and a dative bond which does not utilize d-orbitals. The red color of is caused by electron transitions into an antibonding orbital. The analogous transition in is not in the visible spectrum, so is colorless. The strength of interaction with the counterion affects the energy of this antibonding orbital; thus, in colorless chloryl compounds, strong inte ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gold
Gold is a chemical element; it has chemical symbol Au (from Latin ) and atomic number 79. In its pure form, it is a brightness, bright, slightly orange-yellow, dense, soft, malleable, and ductile metal. Chemically, gold is a transition metal, a group 11 element, and one of the noble metals. It is one of the least reactivity (chemistry), reactive chemical elements, being the second-lowest in the reactivity series. It is solid under standard temperature and pressure, standard conditions. Gold often occurs in free elemental (native state (metallurgy), native state), as gold nugget, nuggets or grains, in rock (geology), rocks, vein (geology), veins, and alluvial deposits. It occurs in a solid solution series with the native element silver (as in electrum), naturally alloyed with other metals like copper and palladium, and mineral inclusions such as within pyrite. Less commonly, it occurs in minerals as gold compounds, often with tellurium (gold tellurides). Gold is resistant to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gold(III) Chloride
Gold(III) chloride, traditionally called auric chloride, is an inorganic compound of gold and chlorine with the molecular formula . The "III" in the name indicates that the gold has an oxidation state of +3, typical for many gold compounds. It has two forms, the monohydrate (AuCl3·H2O) and the anhydrous form, which are both hygroscopic and light-sensitive solids. This compound is a dimer of . This compound has a few uses, such as an oxidizing agent and for catalyzing various organic reactions. Structure exists as a chloride-bridged dimer both as a solid and vapour, at least at low temperatures. Gold(III) bromide behaves analogously. The structure is similar to that of iodine(III) chloride. Each gold center is square planar in gold(III) chloride, which is typical of a metal complex with a d8 electron count. The bonding in is considered somewhat covalent. Properties Gold(III) chloride is a diamagnetic light-sensitive red crystalline solid that forms the orange mon ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chloroauric Acid
Chloroauric acid is an inorganic compound with the chemical formula . It forms hydrates . Both the trihydrate and tetrahydrate are known. Both are orange-yellow solids consisting of the planar anion. Often chloroauric acid is handled as a solution, such as those obtained by dissolution of gold in aqua regia. These solutions can be converted to other gold complexes or reduced to metallic gold or gold nanoparticles. Properties The tetrahydrate crystallizes as and two water molecules. Structure The oxidation state of gold in and anion is +3. The salts of (tetrachloroauric(III) acid) are tetrachloroaurates(III), containing anions (tetrachloroaurate(III) anions), which have square planar molecular geometry. The Au–Cl distances are around 2.28 Å. Other d8 complexes adopt similar structures, e.g. tetrachloroplatinate(II) . Solute properties Solid chloroauric acid is a hydrophilic ( ionic) protic solute. It is soluble in water and other oxygen-containing solvents, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dichlorine Hexoxide
Dichlorine hexoxide is the chemical compound with the molecular formula or , which is correct for its gaseous state. However, in liquid or solid form, this chlorine oxide ionizes into the dark red ionic compound chloryl perchlorate or dioxochloronium(V) perchlorate , which may be thought of as the mixed anhydride of chloric and perchloric acids. This compound is a notable perchlorating agent. It is produced by reaction between chlorine dioxide and excess ozone: : Molecular structure It was originally reported to exist as the monomeric chlorine trioxide in gas phase, but was later shown to remain an oxygen-bridged dimer after evaporation and until thermal decomposition into chlorine perchlorate, , and oxygen. The compound was then rediscovered. It is a dark red fuming liquid at room temperature that crystallizes as a red ionic compound, chloryl perchlorate, . The red color shows the presence of chloryl ions. Thus, chlorine's formal oxidation state in this compound remain ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chlorine Dioxide
Chlorine dioxide is a chemical compound with the formula ClO2 that exists as yellowish-green gas above 11 °C, a reddish-brown liquid between 11 °C and −59 °C, and as bright orange crystals below −59 °C. It is usually handled as an aqueous solution. It is commonly used as a bleach. More recent developments have extended its applications in food processing and as a disinfectant. Structure and bonding The molecule ClO2 has an odd number of valence electrons, and therefore it is a Paramagnetism, paramagnetic radical (chemistry), radical. It is an unusual "example of an odd-electron molecule stable toward dimerization" (nitric oxide being another example). ClO2 crystallizes in the orthorhombic List of space groups, Pbca space group. History Chlorine dioxide was first prepared in 1811 by Sir Humphry Davy. In 1933, Lawrence O. Brockway, a graduate student of Linus Pauling, proposed a structure that involved a three-electron bond and two single bond ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gold(III) Compounds
Gold is a chemical element; it has chemical symbol Au (from Latin ) and atomic number 79. In its pure form, it is a bright, slightly orange-yellow, dense, soft, malleable, and ductile metal. Chemically, gold is a transition metal, a group 11 element, and one of the noble metals. It is one of the least reactive chemical elements, being the second-lowest in the reactivity series. It is solid under standard conditions. Gold often occurs in free elemental (native state), as nuggets or grains, in rocks, veins, and alluvial deposits. It occurs in a solid solution series with the native element silver (as in electrum), naturally alloyed with other metals like copper and palladium, and mineral inclusions such as within pyrite. Less commonly, it occurs in minerals as gold compounds, often with tellurium (gold tellurides). Gold is resistant to most acids, though it does dissolve in aqua regia (a mixture of nitric acid and hydrochloric acid), forming a soluble tetrachloroaurate ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perchlorates
A perchlorate is a chemical compound containing the perchlorate ion, , the conjugate base of perchloric acid (ionic perchlorate). As counterions, there can be metal cations, quaternary ammonium cations or other ions, for example, nitronium cation (). The term ''perchlorate'' can also describe perchlorate esters or covalent perchlorates. These are organic compounds that are alkyl or aryl esters of perchloric acid. They are characterized by a covalent bond between an oxygen atom of the ClO4 moiety and an organyl group. In most ionic perchlorates, the cation is non-coordinating. The majority of ionic perchlorates are commercially produced salts commonly used as oxidizers for pyrotechnic devices and for their ability to control static electricity in food packaging. Additionally, they have been used in rocket propellants, fertilizers, and as bleaching agents in the paper and textile industries. Perchlorate contamination of food and water endangers human health, primarily affectin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
