Bismuth Ferrite
   HOME





Bismuth Ferrite
Bismuth ferrite (BiFeO3, also commonly referred to as BFO in materials science) is an inorganic chemical compound with perovskite structure and one of the most promising multiferroic materials. The room-temperature phase of BiFeO3 is classed as rhombohedral belonging to the space group R3c. It is synthesized in bulk and thin film form and both its antiferromagnetic (G type ordering) Néel temperature (approximately 653 K) and ferroelectric Curie temperature are well above room temperature (approximately 1100K). Ferroelectric polarization occurs along the pseudocubic direction (\langle 111\rangle_c) with a magnitude of 90–95 μC/cm2. Sample Preparation Bismuth ferrite is not a naturally occurring mineral and several synthesis routes to obtain the compound have been developed. Solid state synthesis In the solid state reaction method bismuth oxide (Bi2O3) and iron oxide (Fe2O3) in a 1:1 mole ratio are mixed with a mortar or by ball milling and then fired at elevated temp ...
[...More Info...]      
[...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   [Amazon]


picture info

Bismuth
Bismuth is a chemical element; it has symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs naturally, and its sulfide and oxide forms are important commercial ores. The free element is 86% as dense as lead. It is a brittle metal with a silvery-white color when freshly produced. Surface oxidation generally gives samples of the metal a somewhat rosy cast. Further oxidation under heat can give bismuth a vividly iridescent appearance due to thin-film interference. Bismuth is both the most diamagnetic element and one of the least thermally conductive metals known. Bismuth was formerly understood to be the element with the highest atomic mass whose nuclei do not spontaneously decay. However, in 2003 it was found to be very slightly radioactive. The metal's only primordial isotope, bismuth-209, undergoes alpha decay with a half-l ...
[...More Info...]      
[...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   [Amazon]


Materials Today
''Materials Today'' is a monthly peer-reviewed scientific journal, website, and journal family. The parent journal was established in 1998 and covers all aspects of materials science. It is published by Elsevier and the editors-in-chief are Jun Lou (Rice University) and Gleb Yushin (Georgia Institute of Technology). The journal principally publishes invited review articles, but other formats are also included, such as primary research articles, news items, commentaries, and opinion pieces on subjects of interest to the field. The website publishes news, educational webinars, podcasts, and blogs, as well as a jobs and events board. According to the ''Journal Citation Reports'', the journal has a 2020 impact factor The impact factor (IF) or journal impact factor (JIF) of an academic journal is a type of journal ranking. Journals with higher impact factor values are considered more prestigious or important within their field. The Impact Factor of a journa ... of 31.041. The jour ...
[...More Info...]      
[...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   [Amazon]


Mullite
Mullite or porcelainite is a rare silicate mineral formed during contact metamorphism of clay minerals. It can form two stoichiometric forms: 3 Al2 O32 SiO2 or 2Al2O3 SiO2. Unusually, mullite has no charge-balancing cations present. As a result, there are three different aluminium sites: two distorted tetrahedral and one octahedral. Mullite was first described in 1924 for an occurrence on the Isle of Mull, Scotland. It occurs as argillaceous inclusions in volcanic rocks in the Isle of Mull, inclusions in sillimanite within a tonalite at Val Sissone, Italy and with emerylike rocks in Argyllshire, Scotland. Porcellanite Mullite (porcelainite) can be found as a constituent mineral in a type of thermally-metamorphosed rock called porcellanite. Use in porcelain Mullite is present in the form of needles in porcelain. It is produced during various melting and firing processes, and is used as a refractory material,H. Schneider & S. Komarneni (2005) Mullite. Wiley, VCH, 5 ...
[...More Info...]      
[...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   [Amazon]


picture info

Selenite (mineral)
Selenite, satin spar, desert rose, and gypsum flower are crystal habit varieties of the mineral gypsum. All varieties of gypsum, including selenite and alabaster, are composed of calcium sulfate dihydrate (meaning that it has two molecules of water), with the chemical formula CaSO4·2H2O. Selenite contains no selenium; the similar names both derive from Greek ( 'Moon'). Some of the largest crystals ever found are of selenite, the largest specimen found in the Naica Mine's Cave of the Crystals being 12 meters long and weighing 12 tons. History and etymology "Selenite" is mostly synonymous with gypsum, but from the 15th century, it has named the transparent variety that occurs in crystals or crystalline masses. The name derives through Middle English from Latin , ultimately from Greek (, ). It got this name because people historically believed the mineral waxed and waned with the cycles of the Moon.
[...More Info...]      
[...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   [Amazon]


picture info

Volatility (chemistry)
In chemistry, volatility is a material quality which describes how readily a substance vaporizes. At a given temperature and pressure, a substance with high volatility is more likely to exist as a vapour, while a substance with low volatility is more likely to be a liquid or solid. Volatility can also describe the tendency of a vapor to condense into a liquid or solid; less volatile substances will more readily condense from a vapor than highly volatile ones. Differences in volatility can be observed by comparing how fast substances within a group evaporate (or sublimate in the case of solids) when exposed to the atmosphere. A highly volatile substance such as rubbing alcohol (isopropyl alcohol) will quickly evaporate, while a substance with low volatility such as vegetable oil will remain condensed. In general, solids are much less volatile than liquids, but there are some exceptions. Solids that sublimate (change directly from solid to vapor) such as dry ice (solid carbon di ...
[...More Info...]      
[...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   [Amazon]


picture info

Stoichiometric
Stoichiometry () is the relationships between the masses of reactants and products before, during, and following chemical reactions. Stoichiometry is based on the law of conservation of mass; the total mass of reactants must equal the total mass of products, so the relationship between reactants and products must form a ratio of positive integers. This means that if the amounts of the separate reactants are known, then the amount of the product can be calculated. Conversely, if one reactant has a known quantity and the quantity of the products can be empirically determined, then the amount of the other reactants can also be calculated. This is illustrated in the image here, where the unbalanced equation is: : : However, the current equation is imbalanced. The reactants have 4 hydrogen and 2 oxygen atoms, while the product has 2 hydrogen and 3 oxygen. To balance the hydrogen, a coefficient of 2 is added to the product H2O, and to fix the imbalance of oxygen, it is also added ...
[...More Info...]      
[...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   [Amazon]


picture info

Ball Milling
A ball mill is a type of grinder filled with grinding balls, used to grind or blend materials for use in mineral dressing processes, paints, pyrotechnics, ceramics, and selective laser sintering. It works on the principle of impact and attrition: size reduction is done by impact as the balls drop from near the top of the shell. A ball mill consists of a hollow cylindrical shell rotating about its axis. The axis of the shell may be either horizontal or at a small angle to the horizontal. It is partially filled with balls. The grinding media are the balls, which may be made of steel ( chrome steel), stainless steel, ceramic, or rubber. The inner surface of the cylindrical shell is usually lined with an abrasion-resistant material such as manganese steel or rubber lining. Less wear takes place in rubber lined mills. The length of the mill is approximately equal to its diameter. The general idea behind the ball mill is an ancient one, but it was not until the Industrial Revo ...
[...More Info...]      
[...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   [Amazon]


picture info

Mortar (bowl)
A mortar and pestle is a set of two simple tools used to prepare ingredients or substances by crushing and grinding them into a fine paste or powder in the kitchen, laboratory, and pharmacy. The ''mortar'' () is characteristically a bowl, typically made of hardwood, metal, ceramic, or hard stone such as granite. The ''pestle'' (, also ) is a blunt, club-shaped object. The substance to be ground, which may be wet or dry, is placed in the mortar where the pestle is pounded, pressed, or rotated into the substance until the desired texture is achieved. Mortars and pestles have been used in cooking since the Stone Age; today they are typically associated with the pharmacy profession due to their historical use in preparing medicines. They are used in chemistry settings for pulverizing small amounts of chemicals; in arts and cosmetics for pulverizing pigments, binders, and other substances; in ceramics for making grog; in masonry and other types of construction requiring pulverized ...
[...More Info...]      
[...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   [Amazon]


picture info

Mole (unit)
The mole (symbol mol) is a unit of measurement, the base unit in the International System of Units (SI) for ''amount of substance'', an SI base quantity proportional to the number of elementary entities of a substance. One mole is an aggregate of exactly elementary entities (approximately 602 sextillion or 602 billion times a trillion), which can be atoms, molecules, ions, ion pairs, or other particles. The number of particles in a mole is the Avogadro number (symbol ) and the numerical value of the '' Avogadro constant'' (symbol ) expressed in mol−1. The relationship between the mole, Avogadro number, and Avogadro constant can be expressed in the following equation:1\text = \frac = \frac The current SI value of the mole is based on the historical definition of the mole as the amount of substance that corresponds to the number of atoms in 12  grams of 12C, which made the molar mass of a compound in grams per mole, numerically equal to the average molecular mass or ...
[...More Info...]      
[...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   [Amazon]


picture info

Iron
Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's outer and inner core. It is the fourth most abundant element in the Earth's crust, being mainly deposited by meteorites in its metallic state. Extracting usable metal from iron ores requires kilns or furnaces capable of reaching , about 500 °C (900 °F) higher than that required to smelt copper. Humans started to master that process in Eurasia during the 2nd millennium BC and the use of iron tools and weapons began to displace copper alloys – in some regions, only around 1200 BC. That event is considered the transition from the Bronze Age to the Iron Age. In the modern world, iron alloys, such as steel, stainless steel, cast iron and special steels, are by far the most common industrial metals, due to their mechan ...
[...More Info...]      
[...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   [Amazon]


Oxide
An oxide () is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of −2) of oxygen, an O2− ion with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials considered pure elements often develop an oxide coating. For example, aluminium foil develops a thin skin of (called a passivation layer) that protects the foil from further oxidation.Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford:Butterworth-Heinemann. . Stoichiometry Oxides are extraordinarily diverse in terms of stoichiometries (the measurable relationship between reactants and chemical equations of an equation or reaction) and in terms of the structures of each stoichiometry. Most elements form oxides of more than one stoichiometry. A well known example is carbon monoxide and carbon dioxide.Greenwood, N. N.; & Earnsh ...
[...More Info...]      
[...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   [Amazon]


picture info

Bismuth
Bismuth is a chemical element; it has symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs naturally, and its sulfide and oxide forms are important commercial ores. The free element is 86% as dense as lead. It is a brittle metal with a silvery-white color when freshly produced. Surface oxidation generally gives samples of the metal a somewhat rosy cast. Further oxidation under heat can give bismuth a vividly iridescent appearance due to thin-film interference. Bismuth is both the most diamagnetic element and one of the least thermally conductive metals known. Bismuth was formerly understood to be the element with the highest atomic mass whose nuclei do not spontaneously decay. However, in 2003 it was found to be very slightly radioactive. The metal's only primordial isotope, bismuth-209, undergoes alpha decay with a half-l ...
[...More Info...]      
[...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   [Amazon]