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Beryllium Hydroxide
Beryllium hydroxide, Be(OH)2, is an amphoteric hydroxide, dissolving in both acids and alkalis. Industrially, it is produced as a by-product in the extraction of beryllium metal from the ores beryl and bertrandite. The natural pure beryllium hydroxide is rare (in form of the mineral behoite, orthorhombic) or very rare (clinobehoite, monoclinic).Mindat, http://www.mindat.org/min-1066.html When alkali is added to beryllium salt solutions the α-form (a gel) is formed. If this left to stand or boiled, the rhombic β-form precipitates.Mary Eagleson, 1994, Concise encyclopedia chemistry, Walter de Gruyter, This has the same structure as zinc hydroxide, Zn(OH)2, with tetrahedral beryllium centers. Reactions Beryllium hydroxide is difficult to dissolve in water. With alkalis it dissolves to form the tetrahydroxoberyllate (also known as tetrahydroxidoberyllate) anion, e(OH)4sup>2−.Egon Wiberg, Arnold Frederick Holleman (2001) ''Inorganic Chemistry'', Elsevier With sodium hydroxide so ...
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Aluminium Oxide
Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula . It is the most commonly occurring of several Aluminium oxide (compounds), aluminium oxides, and specifically identified as aluminium oxide. It is commonly called alumina and may also be called aloxide, aloxite, ALOX or alundum in various forms and applications and alumina is refined from bauxite. It occurs naturally in its crystalline Polymorphism (materials science), polymorphic phase (matter), phase α-Al2O3 as the mineral corundum, varieties of which form the precious gemstones ruby and sapphire,which have an alumina content approaching 100%. Al2O3 is used as feedstock to produce aluminium metal, as an abrasive owing to its hardness, and as a refractory material owing to its high melting point. Natural occurrence Corundum is the most common naturally occurring crystallinity, crystalline form of aluminium oxide. ruby, Rubies and sapphires are gem-quality forms o ...
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Magnesium Hydroxide
Magnesium hydroxide is an inorganic compound with the chemical formula Mg(OH)2. It occurs in nature as the mineral brucite. It is a white solid with low solubility in water (). Magnesium hydroxide is a common component of antacids, such as milk of magnesia. Preparation Treating the solution of different soluble magnesium salts with alkaline water induces the Precipitation (chemistry), precipitation of the solid hydroxide Mg(OH)2: :Mg2+ + 2 OH− → Mg(OH)2 As is the second most abundant cation present in seawater after , it can be economically extracted directly from seawater by alkalinisation as described here above. On an industrial scale, Mg(OH)2 is produced by treating seawater with calcium hydroxide, lime (Ca(OH)2). A volume of of seawater gives about of Mg(OH)2. Ca(OH)2 ) is far more soluble than Mg(OH)2 ) and dramatically increases the pH value of seawater from 8.2 to 12.5. The less soluble precipitates because of the common ion effect due to the added by the di ...
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Amphoterism
In chemistry, an amphoteric compound () is a molecule or ion that can react both as an acid and as a base. What exactly this can mean depends on which definitions of acids and bases are being used. Etymology and terminology Amphoteric is derived from the Greek word () meaning "both". Related words in acid-base chemistry are amphichromatic and amphichroic, both describing substances such as acid-base indicators which give one colour on reaction with an acid and another colour on reaction with a base. Amphiprotism Amphiprotism is exhibited by compounds with both Brønsted acidic and basic properties. A prime example is H2O. Amphiprotic molecules can either donate or accept a proton (). Amino acids (and proteins) are amphiprotic molecules because of their amine () and carboxylic acid () groups. Ampholytes Ampholytes are zwitterions ‒ molecules or ions that contain both acidic and basic functional groups. Amino acids have both a basic group and an acidic group . Of ...
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Hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalently bound group  of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry. Many inorganic substances which bear the word ''hydroxide'' in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups. Hydroxide ion The hydroxide ion is naturally produced ...
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Acid
An acid is a molecule or ion capable of either donating a proton (i.e. Hydron, hydrogen cation, H+), known as a Brønsted–Lowry acid–base theory, Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis acid. The first category of acids are the proton donors, or Brønsted–Lowry acid–base theory, Brønsted–Lowry acids. In the special case of aqueous solutions, proton donors form the hydronium ion H3O+ and are known as Acid–base reaction#Arrhenius theory, Arrhenius acids. Johannes Nicolaus Brønsted, Brønsted and Martin Lowry, Lowry generalized the Arrhenius theory to include non-aqueous solvents. A Brønsted–Lowry or Arrhenius acid usually contains a hydrogen atom bonded to a chemical structure that is still energetically favorable after loss of H+. Aqueous Arrhenius acids have characteristic properties that provide a practical description of an acid. Acids form aqueous solutions with a sour taste, can turn blue litmus red, and ...
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Alkali
In chemistry, an alkali (; from the Arabic word , ) is a basic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The adjective alkaline, and less often, alkalescent, is commonly used in English as a synonym for basic, especially for bases soluble in water. This broad use of the term is likely to have come about because alkalis were the first bases known to obey the Arrhenius definition of a base, and they are still among the most common bases. Etymology The word ''alkali'' is derived from Arabic ''al qalīy'' (or ''alkali''), meaning (see calcination), referring to the original source of alkaline substances. A water-extract of burned plant ashes, called potash and composed mostly of potassium carbonate, was mildly basic. After heating this substance with calcium hydroxide (''slaked lime''), a far more strongly basic substance known as ''caustic potash ...
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Beryllium
Beryllium is a chemical element; it has Symbol (chemistry), symbol Be and atomic number 4. It is a steel-gray, hard, strong, lightweight and brittle alkaline earth metal. It is a divalent element that occurs naturally only in combination with other elements to form minerals. Gemstones high in beryllium include beryl (Aquamarine (gemstone), aquamarine, emerald, red beryl) and chrysoberyl. It is a Abundance of the chemical elements#Universe, relatively rare element in the universe, usually occurring as a product of the spallation of larger atomic nuclei that have collided with cosmic rays. Within the cores of stars, beryllium is depleted as it is fused into heavier elements. Beryllium constitutes about 0.0004 percent by mass of Earth's crust. The world's annual beryllium production of 220 tons is usually manufactured by extraction from the mineral beryl, a difficult process because beryllium bonds strongly to oxygen. In structural applications, the combination of high flexural ri ...
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Beryl
Beryl ( ) is a mineral composed of beryllium aluminium Silicate minerals#Cyclosilicates, silicate with the chemical formula Be3Al2(SiO3)6. Well-known varieties of beryl include emerald and Aquamarine (gem), aquamarine. Naturally occurring Hexagonal crystal system, hexagonal crystals of beryl can be up to several meters in size, but double terminated crystal, terminated crystals are relatively rare. Pure beryl is colorless, but it is frequently tinted by impurities; possible colors are green, blue, yellow, pink, and red (the rarest). It is an ore source of beryllium. Etymology The word ''beryl'' – – is borrowed, via and , from Ancient Greek βήρυλλος ''bḗryllos'', which referred to various blue-green stones, from Prakrit ''veruḷiya'', ''veḷuriya'' 'beryl' which is ultimately of Dravidian languages, Dravidian origin, maybe from the name of Belur, Karnataka, Belur or ''Velur'', a town in Karnataka, southern India. The term was later adopted for the mineral ber ...
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Bertrandite
Bertrandite is a beryllium sorosilicate hydroxide mineral with composition: Be4Si2O7(OH)2. Bertrandite is a colorless to pale yellow orthorhombic mineral with a hardness of 6–7. It is commonly found in beryllium rich pegmatites and is in part an alteration of beryl. Bertrandite often occurs as a pseudomorphic replacement of beryl. Associated minerals include beryl, phenakite, herderite, tourmaline, muscovite, fluorite and quartz. It, with beryl, are ores of beryllium. It was discovered near Nantes, France in 1883 and named after French mineralogist, Emile Bertrand (1844–1909). One of the world's largest deposits of bertrandite is Spor Mountain, Thomas Range, Utah which is currently the source of most of the world's beryllium production. See also *List of minerals *List of minerals named after people This is a list of minerals named after people. The chemical composition of the mineral follows the name. A * Abelsonite: – American physicist Philip Hauge Abe ...
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Zinc Hydroxide
Zinc hydroxide Zn( OH)2 is an inorganic chemical compound. It also occurs naturally as 3 rare minerals: wülfingite (orthorhombic), ashoverite and sweetite (both tetragonal). Like the hydroxides of other metals, such as lead, aluminium, beryllium, tin and chromium, Zinc hydroxide (and Zinc oxide), is amphoteric. Thus it will dissolve readily in a dilute solution of a strong acid, such as HCl, and also in a solution of an alkali such as sodium hydroxide. Preparation It can be prepared by first dissolving zinc oxide in concentrated aqueous solution of sodium hydroxide. The resulting solution is strongly diluted. :Zn2+ + 2 OH− → Zn(OH)2. The initial colorless solution contains the zincate ion: :Zn(OH)2 + 2 OH− → Zn(OH)42−. Zinc hydroxide will dissolve because the ion is normally surrounded by water ligands; when excess sodium hydroxide is added to the solution the hydroxide ions will reduce the complex to a −2 charge and make it soluble. When excess ammonia i ...
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Sodium Hydroxide
Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula . It is a white solid ionic compound consisting of sodium cations and hydroxide anions . Sodium hydroxide is a highly corrosive base (chemistry), base and alkali that decomposes lipids and proteins at ambient temperatures and at high concentrations may cause severe chemical burns. It is highly soluble in water, and readily absorbs moisture and carbon dioxide from the air. It forms a series of hydrates . The monohydrate crystallizes from water solutions between 12.3 and 61.8 °C. The commercially available "sodium hydroxide" is often this monohydrate, and published data may refer to it instead of the anhydrous compound. As one of the simplest hydroxides, sodium hydroxide is frequently used alongside neutral water and acidic hydrochloric acid to demonstrate the pH scale to chemistry students. Sodium hydroxide is used in many industries: in the making of wood pulp and paper, tex ...
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Sulfuric Acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, and hydrogen, with the molecular formula . It is a colorless, odorless, and Viscosity, viscous liquid that is Miscibility, miscible with water. Pure sulfuric acid does not occur naturally due to its Dehydration reaction, strong affinity to water vapor; it is Hygroscopy, hygroscopic and readily absorbs water vapor from the Atmosphere of Earth, air. Concentrated sulfuric acid is a strong oxidant with powerful dehydrating properties, making it highly corrosive towards other materials, from rocks to metals. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid but, to the contrary, dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is releas ...
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