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Barium Metaphosphate
Barium metaphosphate is an inorganic substance with the molecular formula Ba(PO3)2. It is a colourless solid that is insoluble in water, though is soluble in acidic solutions through "slow dissolution". X-ray crystallography shows that this material is composed of Ba2+ cations attached to a polyphosphate ((PO3−)n) anion. A number of hydrated forms are known which are actually cyclic metaphosphates, Ba2(P4O12)·3.5H2O, Ba3(P3O9)2·6H2O. Preparation Barium metaphosphate can be prepared by the reaction of barium carbonate with metaphosphoric acid: :BaCO3 + 2HPO3 → Ba(PO3)2 +CO2 +H2O or alternatively by the aqueous reaction of barium chloride and sodium metaphosphate: BaCl2(aq) + 2NaPO3(aq) → Ba(PO3)2 + 2NaCl Applications The combination of soda and barium polyphosphate forms a low-melting glass with a high coefficient of thermal expansion. The melting point of the glass increases with barium content. This glass makes seals with low melting metals like aluminium (melting p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
X-ray Crystallography
X-ray crystallography is the experimental science of determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to Diffraction, diffract in specific directions. By measuring the angles and intensities of the X-ray diffraction, a crystallography, crystallographer can produce a three-dimensional picture of the density of electrons within the crystal and the positions of the atoms, as well as their chemical bonds, crystallographic disorder, and other information. X-ray crystallography has been fundamental in the development of many scientific fields. In its first decades of use, this method determined the size of atoms, the lengths and types of chemical bonds, and the atomic-scale differences between various materials, especially minerals and alloys. The method has also revealed the structure and function of many biological molecules, including vitamins, drugs, proteins and nucleic acids such as DNA. X-ray crystall ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polyphosphate
A polyphosphate is a Salt (chemistry), salt or ester of polymeric oxyanions formed from tetrahedral PO4 (phosphate) structural units linked together by sharing oxygen atoms. Polyphosphates can adopt linear or a cyclic (also called, ring) structures. In biology, the polyphosphate esters adenosine diphosphate, ADP and adenosine triphosphate, ATP are involved in energy storage. A variety of polyphosphates find application in mineral sequestration in municipal waters, generally being present at 1 to 5 ppm. guanosine triphosphate, GTP, cytidine triphosphate, CTP, and uridine triphosphate, UTP are also nucleotides important in the protein synthesis, lipid synthesis, and carbohydrate metabolism, respectively. Polyphosphates are also used as food additives, marked E452. Structure Image:Triphosphorsäure.svg, Structure of triphosphoric acid Image:Polyphosphoric acid.svg, Polyphosphoric acid Image:Trimetaphosphat.svg, Cyclic trimetaphosphate Image:Adenosindiphosphat protoni ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Barium Carbonate
Barium carbonate is the inorganic compound with the formula BaCO3. Like most alkaline earth metal carbonates, it is a white salt that is poorly soluble in water. It occurs as the mineral known as witherite. In a commercial sense, it is one of the most important barium compounds. Preparation Barium carbonate is made commercially from barium sulfide by treatment with sodium carbonate at 60 to 70 °C ( soda ash method) or, more commonly carbon dioxide at 40 to 90 °C: In the soda ash process, an aqueous solution of barium sulfide is treated with sodium carbonate: : Reactions Barium carbonate reacts with acids such as hydrochloric acid to form soluble barium salts, such as barium chloride: : Pyrolysis of barium carbonate gives barium oxide. Uses It is mainly used to remove sulfate impurities from feedstock of the chlor-alkali process. Otherwise it is a common precursor to barium-containing compounds such as ferrites. Other uses Barium carbonate is widely used in t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Barium Chloride
Barium chloride is an inorganic compound with the formula . It is one of the most common water-soluble salts of barium. Like most other water-soluble barium salts, it is a white powder, highly toxic, and imparts a yellow-green coloration to a flame. It is also hygroscopic, converting to the dihydrate , which are colourless crystals with a bitter salty taste. It has limited use in the laboratory and industry. Preparation On an industrial scale, barium chloride is prepared via a two step process from barite (barium sulfate). The first step requires high temperatures. : The second step requires reaction between barium sulfide and hydrogen chloride: : or between barium sulfide and calcium chloride: : In place of HCl, chlorine can be used. Barium chloride is extracted out from the mixture with water. From water solutions of barium chloride, its dihydrate () can be crystallized as colorless crystals. Barium chloride can in principle be prepared by the reaction between barium hydrox ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Glass
Glass is an amorphous (non-crystalline solid, non-crystalline) solid. Because it is often transparency and translucency, transparent and chemically inert, glass has found widespread practical, technological, and decorative use in window panes, tableware, and optics. Some common objects made of glass are named after the material, e.g., a Tumbler (glass), "glass" for drinking, "glasses" for vision correction, and a "magnifying glass". Glass is most often formed by rapid cooling (quenching) of the Melting, molten form. Some glasses such as volcanic glass are naturally occurring, and obsidian has been used to make arrowheads and knives since the Stone Age. Archaeological evidence suggests glassmaking dates back to at least 3600 BC in Mesopotamia, Ancient Egypt, Egypt, or Syria. The earliest known glass objects were beads, perhaps created accidentally during metalworking or the production of faience, which is a form of pottery using lead glazes. Due to its ease of formability int ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Coefficient Of Thermal Expansion
Thermal expansion is the tendency of matter to increase in length, area, or volume, changing its size and density, in response to an increase in temperature (usually excluding phase transitions). Substances usually contract with decreasing temperature (thermal contraction), with rare exceptions within limited temperature ranges ('' negative thermal expansion''). Temperature is a monotonic function of the average molecular kinetic energy of a substance. As energy in particles increases, they start moving faster and faster, weakening the intermolecular forces between them and therefore expanding the substance. When a substance is heated, molecules begin to vibrate and move more, usually creating more distance between themselves. The relative expansion (also called strain) divided by the change in temperature is called the material's coefficient of linear thermal expansion and generally varies with temperature. Prediction If an equation of state is available, it can be used t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Borosilicate
Borosilicate glass is a type of glass with silicon dioxide, silica and boron trioxide as the main glass-forming constituents. Borosilicate glasses are known for having very low coefficient of thermal expansion, coefficients of thermal expansion (≈3 × 10−6 K−1 at 20 °C), making them more resistant to thermal shock than any other common glass. Such glass is subjected to less thermal stress and can withstand temperature differentials without Thermal fracturing in glass, fracturing of about . It is commonly used for the construction of reagent bottles and Laboratory flask, flasks, as well as lighting, electronics, and cookware. For many other applications, soda-lime glass is more common. Borosilicate glass is sold under various trade names, including Borosil, Duran (glass), Duran, Pyrex, Glassco, Supertek, Suprax, Simax, Bellco, Marinex (Brazil), BSA 60, BSC 51 (by NIPRO), Heatex, Endural, Schott_AG, Schott, Refmex GL Glass, Refmex, Kimax, Gemstone Well, United ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diammonium Phosphate
Diammonium phosphate (DAP; IUPAC name diammonium hydrogen phosphate; chemical formula (NH4)2(HPO4)) is one of a series of water- soluble ammonium phosphate salts that can be produced when ammonia reacts with phosphoric acid. Solid diammonium phosphate shows a dissociation pressure of ammonia as given by the following expression and equation: : At 100 °C, the dissociation pressure of diammonium phosphate is approximately 5 mmHg. According to the diammonium phosphate MSDS from CF Industries, Inc., decomposition starts as low as 70 °C: "Hazardous Decomposition Products: Gradually loses ammonia when exposed to air at room temperature. Decomposes to ammonia and monoammonium phosphate at around 70 °C (158 °F). At 155 °C (311 °F), DAP emits phosphorus oxides, nitrogen oxides and ammonia." Uses DAP is used as a fertilizer. When applied as plant fertilizer, it temporarily increases the soil pH, but over a long term the treated ground becomes more acidic than before, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Carbonate
Sodium carbonate (also known as washing soda, soda ash, sal soda, and soda crystals) is the inorganic compound with the formula and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood (once used to produce potash), sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the chloralkali process. Hydrates Sodium carbonate is obtained as three hydrates and as the anhydrous salt: * sodium carbonate decahydrate ( natron), Na2CO3·10H2O, which readily effloresces to form the monohydrate. * sodium carbonate heptahydrate (not known in mineral form), Na2CO3·7H2O. * sodium carbonate monohydrate ( thermonatr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Barium Compounds
Barium is a chemical element; it has symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. The most common minerals of barium are barite (barium sulfate, BaSO4) and witherite (barium carbonate, BaCO3). The name ''barium'' originates from the alchemical derivative "baryta", from Greek (), meaning 'heavy'. ''Baric'' is the adjectival form of barium. Barium was identified as a new element in 1772, but not reduced to a metal until 1808 with the advent of electrolysis. Barium has few industrial applications. Historically, it was used as a getter for vacuum tubes and in oxide form as the emissive coating on indirectly heated cathodes. It is a component of YBCO (high-temperature superconductors) and electroceramics, and is added to steel and cast iron to reduce the size of carbon grains within the microstructure. Barium compounds are a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
