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Azodicarbonamide
Azodicarbonamide, ADCA, ACA, ADA, or azo(''bis'')formamide, is a chemical compound with the molecular formula . It is a yellow to orange-red, odorless, crystalline powder. It is sometimes called "the yoga mat chemical" because of widespread use in foamed plastics. It was first described by John Bryden in 1959. Synthesis It is prepared in two steps via treatment of urea with hydrazine to form biurea, as described in this idealized equation: : Oxidation of biurea with gaseous chlorine yields azodicarbonamide: : Applications Blowing agent The principal use of azodicarbonamide is in the production of foamed plastics as a blowing agent. The thermal decomposition of azodicarbonamide produces nitrogen, carbon monoxide, carbon dioxide, and ammonia gases, which are trapped in the polymer as bubbles to form a foamed article. Azodicarbonamide is used in plastics, synthetic leather, and other industries and can be pure or modified. Modification affects the reaction temperatures. Pure azo ...
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Biurea
Biurea is a chemical compound with the molecular formula C2H6N4O2. It is produced in food products containing azodicarbonamide, a common ingredient in bread flour, when they are cooked. Upon exposure, biurea is rapidly eliminated from the body through excretion. Biurea is produced from urea and hydrazine by transamidation. Its major use is as a chemical intermediate in the production of azodicarbonamide, a common blowing agent. References {{reflist External links Biurea
National Library of Medicine, NLM Hazardous Substances Data Bank Semicarbazides Ureas ...
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Subway (restaurant)
Subway IP LLC, trading as Subway, is an American multinational fast food restaurant franchise that specializes in submarine sandwiches (subs) and wraps. It was founded by Fred DeLuca and financed by Peter Buck in 1965 as Pete's Super Submarine Sandwiches in Bridgeport, Connecticut. After several name changes, it was renamed Subway in 1972, and a franchise operation began in 1974 with a second restaurant in Wallingford, Connecticut. It was the fastest-growing franchise in the world in 2015 and, as of September 2023, has over 37,000 locations in more than 102 countries and territories. More than half its locations (21,796 or 61.1%) are in the United States. It is the largest single-brand restaurant chain and the largest restaurant operator in the world. Its international headquarters are in Shelton, Connecticut. History Foundation and early years In 1965, Fred DeLuca borrowed $1,000 from his friend Peter Buck to start "Pete's Drive-In: Super Submarine Sandwiches" at 385 ...
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Dough Conditioner
A dough conditioner, flour treatment agent, improving agent or bread improver is any ingredient or chemical added to bread dough to strengthen its texture or otherwise improve it in some way. Dough conditioners may include enzymes, yeast nutrients, mineral salts, oxidants and reductants, bleaching agents and emulsifiers. They are food additives combined with flour to improve baking functionality. Flour treatment agents are used to increase the speed of dough rising and to improve the strength and workability of the dough. Examples Examples of dough conditioners include ascorbic acid, distilled monoglycerides, citrate ester of monoglycerides, diglycerides, ammonium chloride, enzymes, diacetyl tartaric acid ester of monoglycerides or DATEM, potassium bromate, potassium iodate, calcium salts such as calcium iodate, L-cystine, L-cysteine HCl, glycerol monostearate, azodicarbonamide, sodium stearoyl lactylate, sucrose palmitate or other sucrose esters, polyoxyethylene sor ...
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Semicarbazide
Semicarbazide is the chemical compound with the formula OC(NH2)(N2H3). It is a water-soluble white solid. It is a derivative of urea. Synthesis The compound prepared by treating urea with hydrazine:Jean-Pierre Schirmann, Paul Bourdauducq "Hydrazine" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2002. . :OC(NH2)2 + N2H4 → OC(NH2)(N2H3) + NH3 A further reaction can occur to give carbohydrazide: :OC(NH2)(N2H3) + N2H4 → OC(N2H3)2 + NH3 Derivatives Semicarbazide is frequently reacted with aldehydes and ketones to produce semicarbazones via a condensation reaction. This is an example of imine formation resulting from the reaction of a primary amine with a carbonyl group. The reaction is useful because semicarbazones, like oximes and 2,4-DNPs, typically have high melting points and crystallize, facilitating purification or identification of reaction products. Properties Semicarbazide products (semicarbazones and thiosemicarbazones) ...
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Hydrazine
Hydrazine is an inorganic compound with the chemical formula . It is a simple pnictogen hydride, and is a colourless flammable liquid with an ammonia-like odour. Hydrazine is highly hazardous unless handled in solution as, for example, hydrazine hydrate (). Hydrazine is mainly used as a foaming agent in preparing Polymeric foam, polymer foams, but applications also include its uses as a precursor (chemistry), precursor to pharmaceuticals and agrochemicals, as well as a long-term storable propellant for in-outer space, space spacecraft propulsion. Additionally, hydrazine is used in various rocket propellant, rocket fuels and to prepare the gas precursors used in airbags. Hydrazine is used within both nuclear and conventional electrical power plant steam cycles as an oxygen scavenger to control concentrations of dissolved oxygen in an effort to reduce corrosion. , approximately 120,000 tons of hydrazine hydrate (corresponding to a 64% solution of hydrazine in water by weight) we ...
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Blowing Agent
A blowing agent is a substance which is capable of producing a cellular structure via a foaming process in a variety of materials that undergo hardening or phase transition, such as polymers, plastics, and metals. They are typically applied when the blown material is in a liquid stage. The cellular structure in a matrix reduces density, increasing thermal and acoustic insulation, while increasing relative stiffness of the original polymer. Blowing agents (also known as 'pneumatogens') or related mechanisms to create holes in a matrix producing cellular materials, have been classified as follows: *Physical blowing agents include CFCs (however, these are ozone depletants, banned by the Montreal Protocol of 1987), HCFCs (replaced CFCs, but are still ozone depletants, therefore being phased out), hydrocarbons (e.g. pentane, isopentane, cyclopentane), and liquid CO2. The bubble/foam-making process is irreversible and endothermic, i.e. it needs heat (e.g. from a melt process or ...
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Registration, Evaluation, Authorisation And Restriction Of Chemicals
Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) is a European Union regulation dating from 18 December 2006, amended on 16 December 2008 by Regulation (EC) No 1272/2008. REACH addresses the production and use of chemical substances, and their potential impacts on both human health and the environment. Its 849 pages took seven years to pass, and it has been described as the most complex legislation in the Union's history and the most important in 20 years. It is the strictest law to date regulating chemical substances and will affect industries throughout the world. REACH entered into force on 1 June 2007, with a phased implementation over the next decade. The regulation also established the European Chemicals Agency, which manages the technical, scientific and administrative aspects of REACH. Overview When REACH is fully in force, it will require all companies manufacturing or importing chemical substances into the European Union in quantities of o ...
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Health And Safety Executive
The Health and Safety Executive (HSE) is a British public body responsible for the encouragement, regulation and enforcement of workplace health, safety and welfare. It has additionally adopted a research role into occupational risks in Great Britain. It is a non-departmental public body with its headquarters in Bootle, England. In Northern Ireland, these duties lie with the Health and Safety Executive for Northern Ireland. The HSE was created by the Health and Safety at Work etc. Act 1974, and has since absorbed earlier regulatory bodies such as the Factory Inspectorate and the Railway Inspectorate though the Railway Inspectorate was transferred to the Office of Rail and Road in April 2006. The HSE is sponsored by the Department for Work and Pensions. As part of its work, HSE investigates industrial accidents, small and large, including major incidents such as the explosion and fire at Buncefield in 2005. Though it formerly reported to the Health and Safety Commission, on 1 ...
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Asthma
Asthma is a common long-term inflammatory disease of the airways of the lungs. It is characterized by variable and recurring symptoms, reversible airflow obstruction, and easily triggered bronchospasms. Symptoms include episodes of wheezing, coughing, chest tightness, and shortness of breath. A sudden worsening of asthma symptoms sometimes called an 'asthma attack' or an 'asthma exacerbation' can occur when allergens, pollen, dust, or other particles, are inhaled into the lungs, causing the bronchioles to constrict and produce mucus, which then restricts oxygen flow to the alveoli. These may occur a few times a day or a few times per week. Depending on the person, asthma symptoms may become worse at night or with exercise. Asthma is thought to be caused by a combination of genetic and environmental factors. Environmental factors include exposure to air pollution and allergens. Other potential triggers include medications such as aspirin and beta blockers. Diag ...
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WorkSafe Victoria
WorkSafe Victoria is the trading name of the Victorian WorkCover Authority, a statutory authority of the state government of Victoria, Australia. History After being renamed in 2014 as Victorian Work-cover Authority by Minister Gordon Rich-Phillips, it returned to the WorkSafe trading name after the election of the Labor Government in November 2014. It has had a number of previous names including ''VWA'', ''WorkCare'' and the ''Department of Labour''. The name ''WorkSafe'' became the trading name for the workplace health and safety and workers compensation divisions in mid-2008, as it reflected the objective of encouraging people to work safely and reduce workplace injuries. The organisation reports to a Minister and has a Board. The Chief Executive is Joe Calafiore. reviewof WorkSafe and the Geelong Geelong ( ) (Wathawurrung language, Wathawurrung: ''Djilang''/''Djalang'') is a port city in Victoria, Australia, located at the eastern end of Corio Bay (the smaller weste ...
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Generally Recognized As Safe
Generally recognized as safe (GRAS) is a United States Food and Drug Administration (FDA) designation that a chemical or substance added to food is considered safe by experts under the conditions of its intended use. An ingredient with a GRAS designation is exempted from the usual Federal Food, Drug, and Cosmetic Act (FFDCA) food additive tolerance requirements. The concept of food additives being "generally recognized as safe" was first described in the Food Additives Amendment of 1958, and all additives introduced after this time had to be evaluated by new standards. Some examples of substances recognized as GRAS include ascorbic acid (vitamin C), citric acid, and salt, which are all commonly used in food preservation and flavoring. The FDA list of GRAS notices is updated approximately each month, as of 2021. History On 6 September 1958, the Food Additives Amendment of 1958 was signed into law, with a list of 700 food substances that were exempt from the then-new requirement ...
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Substance Of Very High Concern
A substance of very high concern (SVHC) is a chemical substance (or part of a group of chemical substances) which has been proposed as a candidate for inclusion on the Authorization or Restriction list (seeECHA Lists of REACH. The addition of a substance to the SVHC Candidate List by the European Chemicals Agency (ECHA) is the first step in the procedure for the authorisation or restriction of a chemical. It is expected that industries operating in EU member states abide by the regulations of REACH and submit chemicals for consideration when appropriate. The first list of SVHCs was published on 28 October 2008 with the list being updated biannually since then. The most recent update occurred in June 2024, bringing the size to 241 SVHCs. Criteria The criteria are given in article 57 of the REACH Regulation. A substance ''may'' be proposed as an SVHC if it meets one or more of the following criteria: *it is carcinogenic; *it is mutagenic; *it is toxic for reproduction; *it ...
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