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Atmospheric Methane Removal
Atmospheric methane removal is a category of potential approaches being researched to accelerate the breakdown of methane that is in the atmosphere, for mitigating some of the impacts of climate change. Atmospheric methane has increased since pre-industrial times from 0.7 ppm to 1.9 ppm, more than doubling in concentration. The increase in methane from industrialization is linked to natural methane sinks failure in accommodating for the increase in methane due to anthropogenic activities. From 2010 to 2019, methane emissions caused 0.5 °C (about 30%) of observed global warming. Global methane emissions approached a record 600 Tg CH4 per year in 2017. Methane is a potent greenhouse gas with a lifetime of up to 12 years. With the ability to undergo reactions converting methane to carbon dioxide which has a lifetime in the hundreds of thousands of years, methane is an impactful greenhouse gas. Atmospheric methane is a more powerful greenhouse gas than carbon dioxide with a global war ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atmospheric Methane
Atmospheric methane is the methane present in Earth's atmosphere. The concentration of atmospheric methane is increasing due to methane emissions, and is causing climate change. Methane is one of the most potent greenhouse gases. Methane's radiative forcing (RF) of climate is direct, and it is the second largest contributor to human-caused climate forcing in the historical period. Methane is a major source of water vapour in the stratosphere through oxidation; and water vapour adds about 15% to methane's radiative forcing effect. The global warming potential (GWP) for methane is about 84 in terms of its impact over a 20-year timeframe, and 28 in terms of its impact over a 100-year timeframe. See Table 8.7. Since the beginning of the Industrial Revolution (around 1750), the methane concentration in the atmosphere has increased by about 160%, and human activities almost entirely caused this increase. Since 1750 methane has contributed 3% of greenhouse gas (GHG) emissions in terms of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iron(III) Chloride
Iron(III) chloride describes the inorganic compounds with the formula (H2O)x. Also called ferric chloride, these compounds are some of the most important and commonplace compounds of iron. They are available both in anhydrous and in hydrated forms, which are both hygroscopic. They feature iron in its +3 oxidation state. The anhydrous derivative is a Lewis acid, while all forms are mild oxidizing agents. It is used as a water cleaner and as an etchant for metals. Electronic and optical properties All forms of ferric chloride are paramagnetic, owing to the presence of unpaired electrons residing in 3d orbitals. Although Fe(III) chloride can be octahedral or tetrahedral (or both, see structure section), all of these forms have five unpaired electrons, one per d-orbital. The high spin d5 electronic configuration requires that d-d electronic transitions are spin forbidden, in addition to violating the Laporte rule. This double forbidden-ness results in its solutions being ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photolysis
Photodissociation, photolysis, photodecomposition, or photofragmentation is a chemical reaction in which molecules of a chemical compound are broken down by absorption of light or photons. It is defined as the interaction of one or more photons with one target molecule that dissociates into two fragments. Here, “light” is broadly defined as radiation spanning the vacuum ultraviolet (VUV), ultraviolet (UV), visible, and infrared (IR) regions of the electromagnetic spectrum. To break covalent bonds, photon energies corresponding to visible, UV, or VUV light are typically required, whereas IR photons may be sufficiently energetic to detach ligands from coordination complexes or to fragment supramolecular complexes. Photolysis in photosynthesis Photolysis is part of the light-dependent reaction, light phase, photochemical phase, or Hill reaction of photosynthesis. The general reaction of photosynthetic photolysis can be given in terms of photons as: :\ce + 2 \text \longri ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photocatalysis
In chemistry, photocatalysis is the acceleration of a photoreaction in the presence of a photocatalyst, the excited state of which "repeatedly interacts with the reaction partners forming reaction intermediates and regenerates itself after each cycle of such interactions." In many cases, the catalyst is a solid that upon irradiation with UV- or visible light generates electron–hole pairs that generate free radicals. Photocatalysts belong to three main groups; heterogeneous, homogeneous, and plasmonic antenna-reactor catalysts. The use of each catalysts depends on the preferred application and required catalysis reaction. History Early mentions (1911–1938) The earliest mention came in 1911, when German chemist Dr. Alexander Eibner integrated the concept in his research of the illumination of zinc oxide (ZnO) on the bleaching of the dark blue pigment, Prussian blue. Around this time, Bruner and Kozak published an article discussing the deterioration of oxalic acid in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Marine Cloud Brightening
Marine cloud brightening (MCB), also known as marine cloud seeding or marine cloud engineering, may be a way to make stratocumulus clouds over the sea brighter, thus reflecting more sunlight back into space in order to limit global warming. It is one of two such methods that might feasibly have a substantial climate impact, but is lower in the atmosphere than stratospheric aerosol injection. It may be able to keep local areas from overheating. If used on a large scale it might reduce the Earth's albedo; and so, in combination with greenhouse gas emissions reduction, limit climate change and its risks to people and the environment. If implemented, the cooling effect would be expected to be felt rapidly and to be reversible on fairly short time scales. However, technical barriers remain to large-scale marine cloud brightening, and it could not offset all the current warming. As clouds are complicated and poorly understood, the risks of marine cloud brightening are unclear as of 2 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cloud Condensation Nuclei
Cloud condensation nuclei (CCNs), also known as cloud seeds, are small particles typically 0.2 μm, or one hundredth the size of a cloud droplet. CCNs are a unique subset of aerosols in the atmosphere on which water vapour condenses. This can affect the radiative properties of clouds and the overall atmosphere. Water vapour requires a non- gaseous surface to make the transition to a liquid; this process is called condensation. In the atmosphere of Earth, this surface presents itself as tiny solid or liquid particles called CCNs. When no CCNs are present, water vapour can be supercooled at about for 5–6 hours before droplets spontaneously form. This is the basis of the cloud chamber for detecting subatomic particles. The concept of CCN (must associate to a supersaturation ratio) is used in cloud seeding, which tries to encourage rainfall by seeding the air with condensation nuclei (CN, which does not associate to supersaturation ratio). It has further been suggested that ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iron Fertilization
Iron fertilization is the intentional introduction of iron-containing compounds (like iron sulfate) to iron-poor areas of the ocean surface to stimulate phytoplankton production. This is intended to enhance biological productivity and/or accelerate carbon dioxide () sequestration from the atmosphere. Iron is a trace element necessary for photosynthesis in plants. It is highly insoluble in sea water and in a variety of locations is the limiting nutrient for phytoplankton growth. Large algal blooms can be created by supplying iron to iron-deficient ocean waters. These blooms can nourish other organisms. Ocean iron fertilization is an example of a geoengineering technique. Iron fertilization attempts to encourage phytoplankton growth, which removes carbon from the atmosphere for at least a period of time. This technique is controversial because there is limited understanding of its complete effects on the marine ecosystem, including side effects and possibly large deviations ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photocatalytic Methane Oxidation Cycle
In chemistry, photocatalysis is the acceleration of a photoreaction in the presence of a photocatalyst, the excited state of which "repeatedly interacts with the reaction partners forming reaction intermediates and regenerates itself after each cycle of such interactions." In many cases, the catalyst is a solid that upon irradiation with UV- or visible light generates electron–hole pairs that generate free radicals. Photocatalysts belong to three main groups; heterogeneous, homogeneous, and plasmonic antenna-reactor catalysts. The use of each catalysts depends on the preferred application and required catalysis reaction. History Early mentions (1911–1938) The earliest mention came in 1911, when German chemist Dr. Alexander Eibner integrated the concept in his research of the illumination of zinc oxide (ZnO) on the bleaching of the dark blue pigment, Prussian blue. Around this time, Bruner and Kozak published an article discussing the deterioration of oxalic acid in th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boundary Layer
In physics and fluid mechanics, a boundary layer is the thin layer of fluid in the immediate vicinity of a Boundary (thermodynamic), bounding surface formed by the fluid flowing along the surface. The fluid's interaction with the wall induces a No-slip condition, no-slip boundary condition (zero velocity at the wall). The flow velocity then monotonically increases above the surface until it returns to the bulk flow velocity. The thin layer consisting of fluid whose velocity has not yet returned to the bulk flow velocity is called the velocity boundary layer. The air next to a human is heated, resulting in gravity-induced convective airflow, which results in both a velocity and thermal boundary layer. A breeze disrupts the boundary layer, and hair and clothing protect it, making the human feel cooler or warmer. On an aircraft wing, the velocity boundary layer is the part of the flow close to the wing, where viscosity, viscous forces distort the surrounding non-viscous flow. In ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aerosol
An aerosol is a suspension (chemistry), suspension of fine solid particles or liquid Drop (liquid), droplets in air or another gas. Aerosols can be generated from natural or Human impact on the environment, human causes. The term ''aerosol'' commonly refers to the mixture of particulates in air, and not to the particulate matter alone. Examples of natural aerosols are fog, mist or dust. Examples of human caused aerosols include particulate air pollutants, mist from the discharge at hydroelectric dams, irrigation mist, perfume from Spray nozzle, atomizers, smoke, dust, Pesticide, sprayed pesticides, and medical treatments for respiratory illnesses. Several types of atmospheric aerosol have a significant effect on Earth's climate: volcanic, desert dust, sea-salt, that originating from biogenic sources and human-made. Volcanic aerosol forms in the stratosphere after an eruption as droplets of sulfuric acid that can prevail for up to two years, and reflect sunlight, lowering tempera ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Troposphere
The troposphere is the lowest layer of the atmosphere of Earth. It contains 80% of the total mass of the Atmosphere, planetary atmosphere and 99% of the total mass of water vapor and aerosols, and is where most weather phenomena occur. From the planetary surface of the Earth, the average height of the troposphere is in the tropics; in the middle latitudes; and in the high latitudes of the polar regions in winter; thus the average height of the troposphere is . The term ''troposphere'' derives from the Greek words ''tropos'' (rotating) and ''sphere, sphaira'' (sphere) indicating that rotational turbulence mixes the layers of air and so determines the structure and the phenomena of the troposphere. The rotational friction of the troposphere against the planetary surface affects the flow of the air, and so forms the planetary boundary layer (PBL) that varies in height from hundreds of meters up to . The measures of the PBL vary according to the latitude, the landform, and the t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Methane
Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes it an economically attractive fuel, although capturing and storing it is difficult because it is a gas at standard temperature and pressure. In the Earth's atmosphere methane is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. Methane is an Organic chemistry, organic Organic compound, compound, and among the simplest of organic compounds. Methane is also a hydrocarbon. Naturally occurring methane is found both below ground and under the seafloor and is formed by both geological and biological processes. The largest reservoir of methane is under the seafloor in the form of methane clathrates. When methane reaches the surface and the Atmosphere of Earth, atmosphere, it is known as atmospheric methane. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
