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All Gas-phase Iodine Laser
All gas-phase iodine laser (AGIL)Anil K. Maini. is a chemical laser using gaseous iodine as a lasing medium. Like the chemical oxygen iodine laser (COIL), it operates at the 1.315 μm wavelength (near-infrared). Purpose AGIL was developed in order to eliminate the problems with aqueous chemistry of the COILs. AGIL uses a reaction of chlorine atoms with gaseous hydrazoic acid, resulting in excited molecules of chloronitrene (NCl), which then pass their energy to the iodine atoms much like the singlet oxygen does in COIL. The iodine atoms then emit the laser radiation itself. Benefits AGIL has numerous advantages over COIL. The chemicals are all in gaseous phase, therefore easier to work with than liquids, especially in microgravity conditions. The chemicals are also lighter, which is a significant advantage in aerospace applications. See also * List of laser articles This is a list of laser topics. A * 3D printing, additive manufacturing * Abnormal reflection * Above-thresh ...
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Chemical Laser
A chemical laser is a laser that obtains its energy from a chemical reaction. Chemical lasers can reach continuous wave output with power reaching to megawatt levels. They are used in industry for cutting and drilling. Common examples of chemical lasers are the chemical oxygen iodine laser (COIL), all gas-phase iodine laser (AGIL), and the hydrogen fluoride (HF) and deuterium fluoride (DF) lasers, all operating in the mid-infrared region. There is also a DF–CO2 laser ( deuterium fluoride–carbon dioxide), which, like COIL, is a "transfer laser." The HF and DF lasers are unusual, in that there are several molecular energy transitions with sufficient energy to cross the threshold required for lasing. Since the molecules do not collide frequently enough to re-distribute the energy, several of these laser modes operate either simultaneously, or in extremely rapid succession, so that an HF or DF laser appears to operate simultaneously on several wavelengths unless a wavele ...
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Iodine
Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at , and boils to a violet gas at . The element was discovered by the French chemist Bernard Courtois in 1811 and was named two years later by Joseph Louis Gay-Lussac, after the Ancient Greek , meaning 'violet'. Iodine occurs in many oxidation states, including iodide (I−), iodate (), and the various periodate anions. As the heaviest essential mineral nutrient, iodine is required for the synthesis of thyroid hormones. Iodine deficiency affects about two billion people and is the leading preventable cause of intellectual disabilities. The dominant producers of iodine today are Chile and Japan. Due to its high atomic number and ease of attachment to organic compounds, it has also found favour as a non-toxic radiocontrast material. Because of the spec ...
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Lasing Medium
The active laser medium (also called a gain medium or lasing medium) is the source of optical gain within a laser. The gain results from the stimulated emission of photons through electronic or molecular transitions to a lower energy state from a higher energy state previously populated by a pump source. Examples of active laser media include: * Certain crystals, typically doped with rare-earth ions (e.g. neodymium, ytterbium, or erbium) or transition metal ions (titanium or chromium); most often yttrium aluminium garnet ( Y3 Al5 O12), yttrium orthovanadate (YVO4), or sapphire (Al2O3); and not often caesium cadmium bromide ( Cs Cd Br3) (solid-state lasers) * Glasses, e.g. silicate or phosphate glasses, doped with laser-active ions; * Gases, e.g. mixtures of helium and neon (HeNe), nitrogen, argon, krypton, carbon monoxide, carbon dioxide, or metal vapors; ( gas lasers) * Semiconductors, e.g. gallium arsenide (GaAs), indium gallium arsenide (InGaAs), or gallium nitride (GaN ...
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Chemical Oxygen Iodine Laser
A chemical oxygen iodine laser (COIL) is a near–infrared chemical laser. As the beam is infrared, it cannot be seen with the naked eye. It is capable of output power scaling up to megawatts in continuous mode. Its output wavelength is 1315 nm, a transition wavelength of atomic iodine. Principles of operation The laser is fed with gaseous chlorine, molecular iodine, and an aqueous mixture of hydrogen peroxide and potassium hydroxide. The aqueous peroxide solution undergoes chemical reaction with chlorine, producing heat, potassium chloride, and oxygen in excited state, singlet delta oxygen. Spontaneous transition of excited oxygen to the triplet sigma ground state is forbidden giving the excited oxygen a spontaneous lifetime of about 45 minutes. This allows the singlet oxygen to transfer its energy to the iodine atoms present in the gas stream;the atomic transition 2P3/2 to 2P1/2 in atomic iodine is nearly resonant with the singlet oxygen, so the energy transfer duri ...
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Near-infrared
Infrared (IR; sometimes called infrared light) is electromagnetic radiation (EMR) with wavelengths longer than that of visible light but shorter than microwaves. The infrared spectral band begins with the waves that are just longer than those of red light (the longest waves in the visible spectrum), so IR is invisible to the human eye. IR is generally (according to ISO, CIE) understood to include wavelengths from around to . IR is commonly divided between longer-wavelength thermal IR, emitted from terrestrial sources, and shorter-wavelength IR or near-IR, part of the solar spectrum. Longer IR wavelengths (30–100 μm) are sometimes included as part of the terahertz radiation band. Almost all black-body radiation from objects near room temperature is in the IR band. As a form of EMR, IR carries energy and momentum, exerts radiation pressure, and has properties corresponding to wave–particle duality, both those of a wave and of a subatomic particle, particle, the photon. I ...
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Chlorine
Chlorine is a chemical element; it has Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidizing agent, oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity on the revised Electronegativity#Pauling electronegativity, Pauling scale, behind only oxygen and fluorine. Chlorine played an important role in the experiments conducted by medieval Alchemy, alchemists, which commonly involved the heating of chloride Salt (chemistry), salts like ammonium chloride (sal ammoniac) and sodium chloride (common salt), producing various chemical substances containing chlorine such as hydrogen chloride, mercury(II) chloride (corrosive sublimate), and . However, the nature of fre ...
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Hydrazoic Acid
Hydrazoic acid, also known as hydrogen azide, azic acid or azoimide, This also contains a detailed description of the contemporaneous production process. is a compound with the chemical formula . It is a colorless, volatile, and explosive liquid at room temperature and pressure. It is a compound of nitrogen and hydrogen, and is therefore a pnictogen hydride. It was first isolated in 1890 by Theodor Curtius. The acid has few applications, but its conjugate base, the azide ion, is useful in specialized processes. Hydrazoic acid, like its fellow mineral acids, is soluble in water. Undiluted hydrazoic acid is dangerously explosive with a standard enthalpy of formation ΔfHo (l, 298K) = +264 kJ/mol. When dilute, the gas and aqueous solutions (<10%) can be safely prepared but should be used immediately; because of its low boiling point, hydrazoic acid is enriched upon evaporation and condensation such that dilute solutions incapable of explosion can form droplets in the headspace of th ...
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Nitrene
In chemistry, a nitrene or imene () is the nitrogen analogue of a carbene. The nitrogen atom is uncharged and valence (chemistry)#monovalent, monovalent, so it has only 6 electrons in its valence level—two covalent bonded and four non-bonded electrons. It is therefore considered an electrophile due to the octet rule, unsatisfied octet. A nitrene is a reactive intermediate and is involved in many chemical reactions. The simplest nitrene, HN, is called imidogen, and that term is sometimes used as a synonym for the nitrene class. Electron configuration In the simplest case, the linear N–H molecule (imidogen) has its nitrogen atom sp hybrid orbital, sp hybridized, with two of its four non-bonded electrons as a lone pair in an sp orbital and the other two occupying a degenerate orbital, degenerate pair of p orbitals. The electron configuration is consistent with Hund's rule: the low energy form is a triplet state, triplet with one electron in each of the p orbitals and the high en ...
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Microgravity
Weightlessness is the complete or near-complete absence of the sensation of weight, i.e., zero apparent weight. It is also termed zero g-force, or zero-g (named after the g-force) or, incorrectly, zero gravity. Weight is a measurement of the force on an object at rest in a relatively strong gravitational field (such as on the surface of the Earth). These weight-sensations originate from contact with supporting floors, seats, beds, scales, and the like. A sensation of weight is also produced, even when the gravitational field is zero, when contact forces act upon and overcome a body's inertia by mechanical, non- gravitational forces- such as in a centrifuge, a rotating space station, or within an accelerating vehicle. When the gravitational field is non-uniform, a body in free fall experiences tidal forces and is not stress-free. Near a black hole, such tidal effects can be very strong, leading to ''spaghettification''. In the case of the Earth, the effects are minor, especiall ...
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List Of Laser Articles
This is a list of laser topics. A * 3D printing, additive manufacturing * Abnormal reflection * Above-threshold ionization * Absorption spectroscopy * Accelerator physics * Acoustic microscopy * Acousto-optic deflector * Acousto-optic modulator * Acousto-optical spectrometer * Acousto-optics * Active laser medium * Active optics * Advanced Precision Kill Weapon System * Advanced Tactical Laser * Afocal system * Airborne laser * Airborne wind turbine * Airy beam * ALKA * All gas-phase iodine laser * Ambient ionization * Amplified spontaneous emission * Analytical chemistry * Aneutronic fusion * Antiproton Decelerator * Apache Arrowhead * Apache Point Observatory Lunar Laser-ranging Operation * Arago spot * Argon fluoride laser * Argus laser * Asterix IV laser * Astrophysical maser * Atmospheric-pressure laser ionization * Atom interferometer * Atom laser * Atom probe * Atomic clock * Atomic coherence * Atomic fountain * Atomic line filter * Ato ...
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