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Alkali Metal Nitrate
Alkali metal nitrates are chemical compounds consisting of an alkali metal (lithium, sodium, potassium, rubidium and caesium) and the nitrate ion. Only two are of major commercial value, the sodium and potassium salts. They are white, water-soluble salts with melting points ranging from 255 °C () to 414 °C () on a relatively narrow span of 159 °C The melting point of the alkali metal nitrates tends to increase from 255 °C to 414 °C (with an anomaly for rubidium being not properly aligned in the series) as the atomic mass and the ionic radius (naked cation) of the alkaline metal increases, going down in the column. Similarly, but not presented here in the table, the solubility of these salts in water also decreases with the atomic mass of the metal. Applications Sodium and potassium nitrates are commonly used as fertilizers. As they are also strong oxidizers, they enter pyrotechnic compositions and the manufacturing of explosives. Eutectic mixtures of alkali metal ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitrite
The nitrite polyatomic ion, ion has the chemical formula . Nitrite (mostly sodium nitrite) is widely used throughout chemical and pharmaceutical industries. The nitrite anion is a pervasive intermediate in the nitrogen cycle in nature. The name nitrite also refers to organic compounds having the –ONO group, which are esters of nitrous acid. Production Sodium nitrite is made industrially by passing a mixture of nitrogen oxides into aqueous sodium hydroxide or sodium carbonate solution: : : The product is purified by recrystallization. Alkali metal nitrites are thermally stable up to and beyond their melting point (441 °C for KNO2). Ammonium nitrite can be made from dinitrogen trioxide, N2O3, which is formally the anhydride of nitrous acid: :2 NH3 + H2O + N2O3 → 2 NH4NO2 Structure The nitrite ion has a symmetrical structure (C2v molecular point group, symmetry), with both N–O bonds having equal length and a bond angle of about 115°. In valence bond theory, it is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cesium Nitrate
Caesium nitrate or cesium nitrate is a salt with the chemical formula Cs NO3. An alkali metal nitrate, it is used in pyrotechnic compositions, as a colorant and an oxidizer, e.g. in decoys and illumination flares. The caesium emissions are chiefly due to two powerful spectral lines at 852.113 nm and 894.347 nm. Caesium nitrate prisms are used in infrared spectroscopy, in x-ray phosphors, and in scintillation counter A scintillation counter is an instrument for detecting and measuring ionizing radiation by using the Electron excitation, excitation effect of incident radiation on a Scintillation (physics), scintillating material, and detecting the resultant li ...s.. It is also used in making optical glasses and lenses. As with other alkali metal nitrates, caesium nitrate decomposes on gentle heating to give caesium nitrite: : Caesium also forms two unusual acid nitrates, which can be described as CsNO3·HNO3 and CsNO3·2HNO3 (melting points 100 °C and 36–3 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lithium Nitrate
Lithium nitrate is an inorganic compound with the formula LiNO3. It is the lithium salt of nitric acid (an alkali metal nitrate). The salt is deliquescent, absorbing water to form the hydrated form, lithium nitrate trihydrate. Its eutectics are of interest for heat transfer fluids.Wietelmann, Ulrich and Bauer, Richard J. (2005) "Lithium and Lithium Compounds" in ''Ullmann's Encyclopedia of Industrial Chemistry'', Wiley-VCH: Weinheim. . It is made by treating lithium carbonate or lithium hydroxide with nitric acid. Uses This deliquescent colourless salt is an oxidizing agent used in the manufacture of red-colored fireworks and flares. Thermal storage The hydrated form, lithium nitrate trihydrate, has an extremely high specific heat of fusion, , and hence can be used for thermal energy storage at its melt temperature of 303.3 K. Lithium nitrate has been proposed as a medium to store heat collected from the sun for cooking. A Fresnel lens would be used to melt solid lithium ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fireworks
Fireworks are Explosive, low explosive Pyrotechnics, pyrotechnic devices used for aesthetic and entertainment purposes. They are most commonly used in fireworks displays (also called a fireworks show or pyrotechnics), combining a large number of devices in an outdoor setting. Such displays are the focal point of many cultural and religious Celebration (party), celebrations, though mismanagement could lead to List of fireworks accidents and incidents, fireworks accidents. Fireworks take many forms to produce four primary effects: noise, light, smoke, and floating materials (confetti most notably). They may be designed to burn with colored flames and sparks including red, orange, yellow, green, blue, purple and silver. They are generally classified by where they perform, either 'ground' or 'aerial'. Aerial fireworks may have their own Air propulsion, propulsion (skyrocket) or be shot into the air by a Mortar (weapon), mortar (aerial shell). Most fireworks consist of a paper or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molten Salt
Molten salt is salt which is solid at standard temperature and pressure but liquified due to elevated temperature. A salt that is liquid even at standard temperature and pressure is usually called a room-temperature ionic liquid, and molten salts are technically a class of ionic liquids. Examples As a reference, molten sodium chloride, table salt has a melting point (m.p.) of . A variety of eutectic mixtures have been developed with lower melting points: Chlorides *Lithium chloride and potassium chloride, m.p. . Nitrates Alkali metal nitrates are relatively low melting and thermally stable. The least stable, (m.p. ) decomposes only at . At the other extreme, cesium nitrate melts at and decomposes at 584 °C. *60:40 mixture of sodium nitrate and potassium nitrate is a liquid between . It has a heat of fusion of 161 J/g, and a heat capacity of 1.53 J/(g·K). *1:1 mixture :, m.p. . *40:7:53 ::, m. p. , stable to . Uses Molten salts have a variety of uses. Production of magnes ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Eutectic Mixture
A eutectic system or eutectic mixture ( ) is a type of a homogeneous mixture that has a melting point lower than those of the constituents. The lowest possible melting point over all of the mixing ratios of the constituents is called the ''eutectic temperature''. On a phase diagram, the eutectic temperature is seen as the eutectic point (see plot on the right). Non-eutectic mixture ratios have different melting temperatures for their different constituents, since one component's Crystal structure, lattice will melt at a lower temperature than the other's. Conversely, as a non-eutectic mixture cools down, each of its components solid, solidifies into a lattice at a different temperature, until the entire mass is solid. A non-eutectic mixture thus does not have a single melting/freezing point temperature at which it changes phase, but rather a temperature at which it changes between liquid and slush (known as the liquidus) and a lower temperature at which it changes between slush ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Explosive
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances. The potential energy stored in an explosive material may, for example, be: * chemical energy, such as nitroglycerin or grain dust * pressurized gas, such as a gas cylinder, aerosol can, or boiling liquid expanding vapor explosion * nuclear energy, such as in the fissile isotopes uranium-235 and plutonium-239 Explosive materials may be categorized by the speed at which they expand. Materials that detonate (the front of the chemical reaction moves faster through the material than the speed of sound) are said to be "high explosives" and materials that deflagrate ar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pyrotechnic Composition
A pyrotechnic composition is a substance or mixture of substances designed to produce an effect by heat, light, sound, gas/smoke or a combination of these, as a result of non-detonative self-sustaining exothermic reaction, exothermic chemical reactions. Pyrotechnic substances do not rely on oxygen from external sources to sustain the reaction. Types Basic types of pyrotechnic compositions are: * flash powder – burns very fast, produces explosions and/or bright flashes of light * gunpowder – burns slower than flash powder, produces large amount of gases * solid propellants – produce large amount of hot gases, used as sources of kinetic energy for rockets and projectiles * pyrotechnic initiators – produce large amount of heat, flames, and/or hot sparks, used to ignite other compositions * gas generators – produce large amount of gas, either high volume at short time (for actuators and ejection charges, often using solid propellants) or controlled flow rate (e.g. chemical ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxidizer
An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or " accepts"/"receives" an electron from a (called the , , or ''electron donor''). In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide, and the halogens. In one sense, an oxidizing agent is a chemical species that undergoes a chemical reaction in which it gains one or more electrons. In that sense, it is one component in an oxidation–reduction (redox) reaction. In the second sense, an oxidizing agent is a chemical species that transfers electronegative atoms, usually oxygen, to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fertilizer
A fertilizer or fertiliser is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from liming materials or other non-nutrient soil amendments. Many sources of fertilizer exist, both natural and industrially produced. For most modern agricultural practices, fertilization focuses on three main macro nutrients: nitrogen (N), phosphorus (P), and potassium (K) with occasional addition of supplements like rock flour for micronutrients. Farmers apply these fertilizers in a variety of ways: through dry or pelletized or liquid application processes, using large agricultural equipment, or hand-tool methods. Historically, fertilization came from natural or organic sources: compost, animal manure, human manure, harvested minerals, crop rotations, and byproducts of human-nature industries (e.g. fish processing waste, or bloodmeal from animal slaughter). However, starting in the 19th cen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alkaline Metal
The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K),The symbols Na and K for sodium and potassium are derived from their Latin names, ''natrium'' and ''kalium''; these are still the origins of the names for the elements in some languages, such as German and Russian. rubidium (Rb), caesium (Cs), and francium (Fr). Together with hydrogen they constitute Group (periodic table)#Group names, group 1, which lies in the s-block of the periodic table. All alkali metals have their outermost electron in an s-orbital: this shared electron configuration results in their having very similar characteristic properties. Indeed, the alkali metals provide the best example of periodic trends, group trends in properties in the periodic table, with elements exhibiting well-characterised Homologous series, homologous behaviour. This family of elements is also known as the lithium family after its leading element. The alkali metals are all shiny, hardness, sof ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cation
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons (e.g. K+ ( potassium ion)) while an anion is a negatively charged ion with more electrons than protons (e.g. Cl− ( chloride ion) and OH− ( hydroxide ion)). Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed ''monatomic ions'', ''atomic ions'' or ''simple ions'', while ions consisting of two or more atoms are termed polyatomic ions or ''molecular ions''. If only a + or − is present, it indic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
