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Ye'elimite
Ye'elimite is the naturally occurring form of anhydrous calcium sulfoaluminate, . It gets its name from Har Ye'elim in Israel in the Hatrurim Basin west of the Dead Sea where it was first found in nature by Shulamit Gross, an Israeli mineralogist and geologist who studied the Hatrurim Formation. The mineral is cubic, with 16 formula units per unit cell, and a cell dimension of 1.8392 nm, and is readily detected and quantified in mixtures by powder x-ray diffraction. Occurrence in cement It is alternatively called "Klein's Compound", after Alexander Klein of the University of California, Berkeley, who experimented with sulfoaluminate cements around 1960, although it was first described in 1957 by Ragozina. Ye'elimite is most commonly encountered as a constituent of sulfoaluminate cements, in which it is manufactured on the million-tonne-per-annum scale. It also occasionally occurs adventitiously in Portland-type cements.A E Moore, ''Cement Technology'', 7 (1976) pp 85, 134 ...
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Hatrurim Formation
The Hatrurim Formation or Mottled Zone is a geologic formation with outcrops all around the Dead Sea Basin: in the Negev Desert in Israel, in the Judaean Desert on the West Bank, and in western Jordan. It includes late Cretaceous to Eocene aged impure limestone along with coal bearing chalk and marl. The rocks have been subjected to pyrometamorphism resulting from combustion of contained or underlying coal or hydrocarbon deposits. The formation is named for exposures in the Hatrurim Basin which lies west of the Dead Sea. During the 1960s, a group of scientists from the Hebrew University of Jerusalem, including Yaakov Ben-Tor, and Lisa Heller-Kallai, discovered that the Hatrurim Formation contained several rare, if not unique, mineral assemblages. The formation is the type locality for five unusual minerals and noted for other minerals serving as reference for mineral phases formed at high temperature in the clinker of Portland cement. Shulamit Gross, an Israeli geologist and ...
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Cement
A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mixed with fine aggregate produces mortar for masonry, or with sand and gravel, produces concrete. Concrete is the most widely used material in existence and is behind only water as the planet's most-consumed resource. Cements used in construction are usually inorganic, often lime- or calcium silicate-based, and are either hydraulic or less commonly non-hydraulic, depending on the ability of the cement to set in the presence of water (see hydraulic and non-hydraulic lime plaster). Hydraulic cements (e.g., Portland cement) set and become adhesive through a chemical reaction between the dry ingredients and water. The chemical reaction results in mineral hydrates that are not very water-soluble. This allows setting in wet conditions or u ...
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Shulamit Gross
Shulamit Gross (; lived 1 October 1923 – 19 Sep 2012) was an Israeli mineralogist and geologist who studied the Hatrurim Formation. Biography Gross was born as Shulamit Lifszyc in Grodno, Poland (today, Hrodna, Belarus). She was the daughter of Fryda and Mejer Lifszyc. She studied in the local Tarbut school, and later on at the Belarusian State Polytechnic Institute in Minsk. When Nazi Germany invaded the Soviet Union during the summer of 1941, she fled to Tashkent in Uzbekistan. Here she continued her studies in the faculty of geology, which she graduated cum laude in 1945. Her parents were murdered in the Treblinka extermination camp in 1943. She began a PhD in the Radioactive Micas of Central Asia, but was not permitted KGB security clearance, and her studies were terminated. After graduating, she moved to Lomonosov University in Moscow to conduct research in crystallography. Her second project considered ''"The ionic radius effect on lattice structure and mineral prope ...
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Ronneburg, Thuringia
Ronneburg () is a town in the district of Greiz, in Thuringia, Germany. It is situated 7 km east of Gera. History Within the German Empire (1871–1918), Ronneburg was part of the Duchy of Saxe-Altenburg Saxe-Altenburg () was one of the Saxon duchies held by the Ernestine duchies, Ernestine branch of the House of Wettin in present-day Thuringia. It was one of the smallest of the German states with an area of 1323 square kilometers and a populati .... References External links District Greiz Towns in Thuringia Greiz (district) {{Greiz-geo-stub ...
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Ettringite
Ettringite is a hydrous calcium aluminium sulfate mineral with formula: . It is a colorless to yellow mineral crystallizing in the trigonal crystal system, system. The prismatic crystals are typically colorless, turning white on partial dehydration. It is part of the ettringite-group which includes other sulfates such as thaumasite and bentorite.Ettringite-group
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Discovery and occurrence

Ettringite was first described in 1874 by ,Lehmann, J. (1874). Über den Ettringit, ein neues Mineral in Kalkeinschlüssen der Lava von Ettringen (Laacher Gebiet). N. Jb. Mineral. Geol. Paläont., 273–275. f ...
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Aluminium Hydroxide
Aluminium hydroxide, , is found as the mineral gibbsite (also known as hydrargillite) and its three much rarer polymorphs: bayerite, doyleite, and nordstrandite. Aluminium hydroxide is amphoteric, i.e., it has both basic and acidic properties. Closely related are aluminium oxide hydroxide, AlO(OH), and aluminium oxide or alumina (), the latter of which is also amphoteric. These compounds together are the major components of the aluminium ore bauxite. Aluminium hydroxide also forms a gelatinous precipitate in water. Structure is built up of double layers of hydroxyl groups with aluminium ions occupying two-thirds of the octahedral holes between the two layers. Four polymorphs are recognized. All feature layers of octahedral aluminium hydroxide units, with hydrogen bonds between the layers. The polymorphs differ in terms of the stacking of the layers. All forms of crystals are hexagonal : * gibbsite is also known as γ- or α- * bayerite is also known as α- or ''β ...
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Aluminium Oxide
Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula . It is the most commonly occurring of several Aluminium oxide (compounds), aluminium oxides, and specifically identified as aluminium oxide. It is commonly called alumina and may also be called aloxide, aloxite, ALOX or alundum in various forms and applications and alumina is refined from bauxite. It occurs naturally in its crystalline Polymorphism (materials science), polymorphic phase (matter), phase α-Al2O3 as the mineral corundum, varieties of which form the precious gemstones ruby and sapphire,which have an alumina content approaching 100%. Al2O3 is used as feedstock to produce aluminium metal, as an abrasive owing to its hardness, and as a refractory material owing to its high melting point. Natural occurrence Corundum is the most common naturally occurring crystallinity, crystalline form of aluminium oxide. ruby, Rubies and sapphires are gem-quality forms o ...
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Calcium Carbonate
Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skeletons and pearls. Materials containing much calcium carbonate or resembling it are described as calcareous. Calcium carbonate is the active ingredient in agricultural lime and is produced when calcium ions in hard water react with carbonate ions to form limescale. It has medical use as a calcium supplement or as an antacid, but excessive consumption can be hazardous and cause hypercalcemia and digestive issues. Chemistry Calcium carbonate shares the typical properties of other carbonates. Notably, it: *reacts with acids, releasing carbonic acid which quickly disintegrates into carbon dioxide and water: : *releases carbon dioxide upon heating, called a thermal decomposition reaction, or calcination (to above 840 °C in the case of ), t ...
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Calcium Sulfate
Calcium sulfate (or calcium sulphate) is an inorganic salt with the chemical formula . It occurs in several hydrated forms; the anhydrous state (known as anhydrite) is a white crystalline solid often found in evaporite deposits. Its dihydrate form is the mineral gypsum, which may be dehydrated to produce bassanite, the hemihydrate state. Gypsum occurs in nature as crystals ( selenite) or fibrous masses ( satin spar), typically colorless to white, though impurities can impart other hues. All forms of calcium sulfate are sparingly soluble in waterFranz Wirsching "Calcium Sulfate" in Ullmann's Encyclopedia of Industrial Chemistry, 2012 Wiley-VCH, Weinheim. and cause permanent hardness when dissolved therein. Hydration states Calcium sulfate occurs at three levels of hydration with different crystallographic structures: anhydrous, dihydrate, and hemihydrate. The anhydrous ( anhydrite) crystallizes as an tightly-bound orthohombic lattice with space group Pnma, in which each ...
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Cement Chemist Notation
Cement chemist notation (CCN) was developed to simplify the formulas cement chemists use on a daily basis. It is a shorthand way of writing the chemical formula of oxides of calcium, silicon, and various metals. Abbreviations of oxides The main oxides present in cement (or in glass and ceramics) are abbreviated in the following way: Conversion of hydroxides in oxide and free water For the sake of mass balance calculations, hydroxides present in hydrated phases found in hardened cement paste, such as in portlandite, Ca(OH)2, must first be converted into oxide and water. To better understand the conversion process of hydroxide anions in oxide and water, it is necessary to consider the autoprotolysis of the hydroxyl anions; it implies a proton exchange between two OH−, like in a classical acid–base reaction: : + → + or also, :2 OH− → O2− + H2O For portlandite this gives thus the following mass balance: :Ca(OH)2 → CaO + H2O Thus portlandite can be written as ...
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Flux (metallurgy)
In metallurgy, a flux is a chemical reducing agent, flowing agent, or purifying agent. Fluxes may have more than one function at a time. They are used in both extractive metallurgy and metal joining. Some of the earliest known fluxes were sodium carbonate, potash, charcoal, coke, borax, lime, lead sulfide and certain minerals containing phosphorus. Iron ore was also used as a flux in the smelting of copper. These agents served various functions, the simplest being a reducing agent, which prevented oxides from forming on the surface of the molten metal, while others absorbed impurities into slag, which could be scraped off molten metal. Fluxes are also used in foundries for removing impurities from molten nonferrous metals such as aluminium, or for adding desirable trace elements such as titanium. As reducing agents, fluxes facilitate soldering, brazing, and welding by removing oxidation from the metals to be joined. In some applications molten flux also serves as ...
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Tricalcium Aluminate
Tricalcium aluminate Ca3Al2O6, often formulated as 3CaO·Al2O3 to highlight the proportions of the oxides from which it is made, is the most basic of the calcium aluminates. It does not occur in nature, but is an important mineral phase in Portland cement. Properties Tricalcium aluminate forms upon heating a 3:1 mixture of calcium oxide and aluminium oxide above 1300 °C. The crystals are cubic, with unit cell dimension 1.5263 nm and has density 3064 kg·m−3. It melts with decomposition at 1542 °C. The unit cell contains 8 cyclic Al6O1818− anions, which can be considered to consist of 6 corner sharing AlO4 tetrahedra. The structure of pure liquid tricalcium aluminate contains mostly AlO4 tetrahedra in an infinite network, with a slightly higher concentration of bridging oxygens than expected from the composition and around 10% unconnected AlO4 monomers and Al2O7 dimers. In Portland cement clinker, tricalcium aluminate occurs as an "interstitial phase ...
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