|
X-ray Emission Spectroscopy
X-ray emission spectroscopy (XES) is a form of X-ray spectroscopy in which a core electron is excited by an incident X-ray photon and then this excited state decays by emitting an X-ray photon to fill the core hole. The energy of the emitted photon is the energy difference between the involved electronic levels. The analysis of the energy dependence of the emitted photons is the aim of the X-ray emission spectroscopy. XES is also sometimes referred to as X-ray fluorescence, X-ray Fluorescence (XRF) spectroscopy, and while the terms can be used interchangeably, XES more often describes high energy resolution techniques while XRF studies a wider energy range at lower resolution. There are several types of XES and can be categorized as non-resonant XES (XES), which includes K_-measurements, valence-to-core (VtC/V2C)-measurements, and (K_)-measurements, or as resonant XES (RXES or Resonant inelastic X-ray scattering, RIXS), which includes XXAS+XES 2D-measurement, high-resolution X-ray ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
X-ray Spectroscopy
X-ray spectroscopy is a general term for several Spectroscopy, spectroscopic techniques for characterization of materials by using x-ray radiation. Characteristic X-ray spectroscopy When an electron from the inner shell of an atom is excited by the energy of a photon, it moves to a higher energy level. When it returns to the low energy level, the energy it previously gained by excitation is emitted as a photon of one of the wavelengths uniquely characteristic of the element. Analysis of the X-ray emission spectrum produces qualitative results about the elemental composition of the specimen. Comparison of the specimen's spectrum with the spectra of samples of known composition produces quantitative results (after some mathematical corrections for absorption, fluorescence and atomic number). Atoms can be excited by a high-energy beam of charged particles such as electrons (in an electron microscope for example), protons (see PIXE) or a beam of X-rays (see X-ray fluorescence, or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Neutron
The neutron is a subatomic particle, symbol or , that has no electric charge, and a mass slightly greater than that of a proton. The Discovery of the neutron, neutron was discovered by James Chadwick in 1932, leading to the discovery of nuclear fission in 1938, the first self-sustaining nuclear reactor (Chicago Pile-1, 1942) and the first nuclear weapon (Trinity (nuclear test), Trinity, 1945). Neutrons are found, together with a similar number of protons in the atomic nucleus, nuclei of atoms. Atoms of a chemical element that differ only in neutron number are called isotopes. Free neutrons are produced copiously in nuclear fission and nuclear fusion, fusion. They are a primary contributor to the nucleosynthesis of chemical elements within stars through fission, fusion, and neutron capture processes. Neutron stars, formed from massive collapsing stars, consist of neutrons at the density of atomic nuclei but a total mass more than the Sun. Neutron properties and interactions ar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
RIXS
Resonant inelastic X-ray scattering (RIXS) is an advanced X-ray spectroscopy technique. In the last two decades RIXS has been widely exploited to study the electronic, magnetic and structural properties of quantum materials and molecules. It is a resonant X-rays photon-in photon-out energy loss and momentum resolved spectroscopy, capable of measuring the energy and momentum transferred to specific excitations proper of the sample under study. The use of X-rays guarantees bulk sensitivity, as opposed to Electron energy loss spectroscopy, electron spectroscopies, and the tuning of the incoming X-rays to a specific absorption edge allows for element and chemical specificity. Due to the intrinsic inefficiency of the RIXS process, extremely Brightness, brilliant sources of X-rays are crucial. In addition to that, the possibility to tune the energy of the incoming X-rays is compelling to match a chosen resonance. These two strict conditions make RIXS to be necessarily performed at syn ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Element (chemistry)
A chemical element is a chemical substance whose atoms all have the same number of protons. The number of protons is called the atomic number of that element. For example, oxygen has an atomic number of 8: each oxygen atom has 8 protons in its nucleus. Atoms of the same element can have different numbers of neutrons in their nuclei, known as isotopes of the element. Two or more atoms can combine to form molecules. Some elements form molecules of atoms of said element only: e.g. atoms of hydrogen (H) form diatomic molecules (H). Chemical compounds are substances made of atoms of different elements; they can have molecular or non-molecular structure. Mixtures are materials containing different chemical substances; that means (in case of molecular substances) that they contain different types of molecules. Atoms of one element can be transformed into atoms of a different element in nuclear reactions, which change an atom's atomic number. Historically, the term "chemical element" ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxidation State
In chemistry, the oxidation state, or oxidation number, is the hypothetical Electrical charge, charge of an atom if all of its Chemical bond, bonds to other atoms are fully Ionic bond, ionic. It describes the degree of oxidation (loss of electrons) of an atom in a chemical compound. Conceptually, the oxidation state may be positive, negative or zero. Beside nearly-pure ionic bonding, many covalent bonds exhibit a strong ionicity, making oxidation state a useful predictor of charge. The oxidation state of an atom does not represent the "real" charge on that atom, or any other actual atomic property. This is particularly true of high oxidation states, where the ionization energy required to produce a multiply positive ion is far greater than the energies available in chemical reactions. Additionally, the oxidation states of atoms in a given compound may vary depending on Electronegativities of the elements (data page), the choice of electronegativity scale used in their calculation. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
XAS Measurement Against HERFD
X-ray absorption spectroscopy (XAS) is a set of advanced techniques used for probing the local environment of matter at atomic level and its electronic structure. The experiments require access to synchrotron radiation facilities for their intense and tunable X-ray beams. Samples can be in the gas phase, solutions, or solids. Background XAS data are obtained by tuning the photon energy, using a crystalline monochromator, to a range where core electrons can be excited (0.1-100 keV). The edges are, in part, named by which core electron is excited: the principal quantum numbers n = 1, 2, and 3, correspond to the K-, L-, and M-edges, respectively. For instance, excitation of a 1s electron occurs at the K-edge, while excitation of a 2s or 2p electron occurs at an L-edge (Figure 1). There are three main regions found on a spectrum generated by XAS data, which are then thought of as separate spectroscopic techniques (Figure 2): # The ''absorption threshold'' determined by the tra ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
X-ray Absorption Near Edge Structure
X-ray absorption near edge structure (XANES), also known as near edge X-ray absorption fine structure (NEXAFS), is a type of absorption spectroscopy that indicates the features in the X-ray absorption spectra ( XAS) of condensed matter due to the photoabsorption cross section for electronic transitions from an atomic core level to final states in the energy region of 50–100 eV above the selected atomic core level ionization energy, where the wavelength of the photoelectron is larger than the interatomic distance between the absorbing atom and its first neighbour atoms. Terminology Both XANES and NEXAFS are acceptable terms for the same technique. XANES name was invented in 1980 by Antonio Bianconi to indicate strong absorption peaks in X-ray absorption spectra in condensed matter due to multiple scattering resonances above the ionization energy. The name NEXAFS was introduced in 1983 by Jo Stohr and is synonymous with XANES, but is generally used when applied to surface and molec ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Siegbahn Notation
The Siegbahn notation is used in X-ray spectroscopy to name the spectral lines that are characteristic to elements. It was introduced by Manne Siegbahn. The characteristic lines in X-ray emission spectra correspond to atomic electronic transitions where an electron jumps down to a vacancy in one of the inner shells of an atom. Such a hole in an inner shell may have been produced by bombardment with electrons in an X-ray tube, by other particles as in PIXE, by other X-rays in X-ray fluorescence or by radioactive decay of the atom's nucleus. Although still widely used in spectroscopy, this notation is unsystematic and often confusing. For these reasons, International Union of Pure and Applied Chemistry (IUPAC) recommends another nomenclature. History The use of the letters K and L to denote X-rays originates in a 1911 paper by Charles Glover Barkla, titled ''The Spectra of the Fluorescent Röntgen Radiations'' ("Röntgen radiation" is an archaic name for "X-rays"). By 1913, H ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ligand Field Theory
Ligand field theory (LFT) describes the bonding, orbital arrangement, and other characteristics of coordination complexes. It represents an application of molecular orbital theory to transition metal complexes. A transition metal ion has nine valence atomic orbitals - consisting of five ''n''d, one (''n''+1)s, and three (''n''+1)p orbitals. These orbitals have the appropriate energy to form bonding interactions with ligands. The LFT analysis is highly dependent on the geometry of the complex, but most explanations begin by describing octahedral complexes, where six ligands coordinate with the metal. Other complexes can be described with reference to crystal field theory. Inverted ligand field theory (ILFT) elaborates on LFT by breaking assumptions made about relative metal and ligand orbital energies. History Ligand field theory resulted from combining the principles laid out in molecular orbital theory and crystal field theory, which describe the loss of degeneracy of metal d ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rowland Circle With Two Orders
Rowland may refer to: Places United States *Rowland Heights, California, an unincorporated community in Los Angeles County *Rowland, Kentucky, an unincorporated community * Rowland Township, Michigan *Rowland, Missouri, an unincorporated community * Rowland Township, North Carolina **Rowland, North Carolina, a town * Rowland, Nevada, a ghost town * Rowland, Oregon, a ghost town Elsewhere *Rowland, Derbyshire, England, a village and civil parish *Rowland (crater), on the Moon People *Rowland (given name), people so named *Rowland (surname), people so named Other *The title character of Childe Rowland, a fairy tale by Joseph Jacobs, based on a Scottish ballad *Rowland Institute for Science, now part of Harvard University *Rowland Theater, Pittsburgh, Pennsylvania, United States See also *Rowland House (other) *Rowland Park (other) *Roland (other) Roland (died 778) was a Frankish military leader in Charlemagne's service, and subject of the epic poem '' T ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rowland Circle
X-ray fluorescence (XRF) is the emission of characteristic "secondary" (or fluorescent) X-rays from a material that has been excited by being bombarded with high-energy X-rays or gamma rays. The phenomenon is widely used for elemental analysis and chemical analysis, particularly in the investigation of metals, glass, ceramics and building materials, and for research in geochemistry, forensic science, archaeology and art objects such as paintings. Underlying physics When materials are exposed to short-wavelength X-rays or to gamma rays, ionization of their component atoms may take place. Ionization consists of the ejection of one or more electrons from the atom, and may occur if the atom is exposed to radiation with an energy greater than its ionization energy. X-rays and gamma rays can be energetic enough to expel tightly held electrons from the inner orbitals of the atom. The removal of an electron in this way makes the electronic structure of the atom unstable, and electro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
