|
Triethylene Glycol Dimethyl Ether
Triethylene glycol dimethyl ether (also called triglyme) is a glycol ether used as a solvent. See also * Monoglyme * Diglyme Diglyme, or bis(2-methoxyethyl) ether, is an organic compound with the chemical formula . It is a colorless liquid with a slight ether-like odor. It is a solvent with a high boiling point. It is the dimethyl ether of diethylene glycol. The name '' ... * Tetraglyme References Glycol ethers {{Ether-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Glycol Ether
Glycol ethers are a class of chemical compounds consisting of alkyl ethers that are based on glycols such as ethylene glycol or propylene glycol. They are commonly used as solvents in paints and cleaners. They have good solvent properties while having higher boiling points than the lower-molecular-weight ethers and Alcohol (chemistry), alcohols. History The name "Cellosolve" was registered in 1924 as a United States trademark by Carbide & Carbon Chemicals Corporation (a division of Union_Carbide , Union Carbide Corporation) for "Solvents for Gums, Resins, Cellulose Esters, and the Like". "Ethyl Cellosolve" or simply "Cellosolve" consists mainly of ethylene glycol monoethyl ether and was introduced as a lower-cost solvent alternative to ethyl lactate. "Butyl Cellosolve" (ethylene glycol monobutyl ether) was introduced in 1928, and "Methyl Cellosolve" (ethylene glycol monomethyl ether) in 1929. Types Glycol ethers are designated "E-series" or "P-series" for those made from ethylene ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Monoglyme
Dimethoxyethane, also known as glyme, monoglyme, dimethyl glycol, ethylene glycol dimethyl ether, dimethyl cellosolve, and DME, is a colorless, aprotic, and liquid ether that is used as a solvent, especially in batteries. Dimethoxyethane is miscible with water. Production Monoglyme is produced industrially by the reaction of dimethylether with ethylene oxide: :CH3OCH3 + CH2CH2O → CH3OCH2CH2OCH3 Applications as solvent and ligand left, 144px, Structure of the coordination complex NbCl3(dimethoxyethane)(3-hexyne). Together with a high-permittivity solvent (e.g. propylene carbonate), dimethoxyethane is used as the low-viscosity component of the solvent for electrolytes of lithium batteries. In the laboratory, DME is used as a coordinating solvent. Dimethoxyethane is often used as a higher-boiling-point alternative to diethyl ether and tetrahydrofuran. Dimethoxyethane acts as a bidentate ligand for some metal cations. It is therefore often used in organometallic chemistry. Grig ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diglyme
Diglyme, or bis(2-methoxyethyl) ether, is an organic compound with the chemical formula . It is a colorless liquid with a slight ether-like odor. It is a solvent with a high boiling point. It is the dimethyl ether of diethylene glycol. The name ''diglyme'' is a portmanteau of ''diglycol methyl ether''. It is miscible with water as well as organic solvents. It is prepared by a reaction of dimethyl ether and ethylene oxide over an acid catalyst. Solvent Because of its resistance to strong bases, diglyme is favored as a solvent for reactions of alkali metal reagents even at high temperatures. Rate enhancements in reactions involving organometallic reagents, such as Grignard reactions or metal hydride reductions, have been observed when using diglyme as a solvent. Diglyme is also used as a solvent in hydroboration reactions with diborane. It serves as a chelate for alkali metal cations, leaving anions more Activity coefficient, active. Safety The European Chemicals Agency lists di ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetraglyme
Tetraethylene glycol dimethyl ether (TEGDME or tetraglyme) is a polar aprotic solvent with excellent chemical and thermal stability. Its high boiling point and stability makes it an ideal candidate for separation processes and high temperature reactions. TEGDME is also used in lithium-ion battery technology and combined with trifluoroethanol as a working pair for organic absorption heat pump An absorption heat pump (AHP) is a heat pump driven by thermal energy such as combustion of natural gas, steam solar-heated water, air or Geothermal heat pump, geothermal-heated water differently from compression heat pumps that are driven by mec ...s. TEGDME is listed as a Substance of Very High Concern under REACH regulations. References {{reflist External links Santa-Cruz Biotechnology MSDSSigma Aldrich MSDS, including an explicit warning related to reproductive health not present in the Santa-Cruz Biotechnology MSDS Glycol ethers ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
