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Time-correlated Single Photon Counting
Ultrafast laser spectroscopy is a category of spectroscopy, spectroscopic techniques using ultrashort pulse lasers for the study of dynamics on extremely short time scales (attoseconds to nanoseconds). Different methods are used to examine the dynamics of charge carriers, atoms, and molecules. Many different procedures have been developed spanning different time scales and photon energy ranges; some common methods are listed below. Attosecond-to-picosecond spectroscopy Dynamics on the femtosecond time scale are in general too fast to be measured electronically. Most measurements are done by employing a sequence of ultrashort light pulses to initiate a process and record its dynamics. The temporal width (duration) of the light pulses has to be on the same scale as the dynamics that are to be measured or even shorter. Light sources Titanium-sapphire laser Ti-sapphire lasers are tunable lasers that emit red and near-infrared light (700 nm- 1100 nm).Ti-sapphire laser oscill ...
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Spectroscopy
Spectroscopy is the field of study that measures and interprets electromagnetic spectra. In narrower contexts, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum. Spectroscopy, primarily in the electromagnetic spectrum, is a fundamental exploratory tool in the fields of astronomy, chemistry, materials science, and physics, allowing the composition, physical structure and electronic structure of matter to be investigated at the atomic, molecular and macro scale, and over astronomical distances. Historically, spectroscopy originated as the study of the wavelength dependence of the absorption by gas phase matter of visible light dispersed by a prism. Current applications of spectroscopy include biomedical spectroscopy in the areas of tissue analysis and medical imaging. Matter waves and acoustic waves can also be considered forms of radiative energy, and recently gravitational waves have been associa ...
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Bremsstrahlung
In particle physics, bremsstrahlung (; ; ) is electromagnetic radiation produced by the deceleration of a charged particle when deflected by another charged particle, typically an electron by an atomic nucleus. The moving particle loses kinetic energy, which is converted into radiation (i.e., photons), thus satisfying the law of conservation of energy. The term is also used to refer to the process of producing the radiation. Bremsstrahlung has a continuous spectrum, which becomes more intense and whose peak intensity shifts toward higher frequencies as the change of the energy of the decelerated particles increases. Broadly speaking, bremsstrahlung or braking radiation is any radiation produced due to the acceleration (positive or negative) of a charged particle, which includes synchrotron radiation (i.e., photon emission by a relativistic particle), cyclotron radiation (i.e. photon emission by a non-relativistic particle), and the emission of electrons and positrons during ...
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Case Western Reserve University
Case Western Reserve University (CWRU) is a Private university, private research university in Cleveland, Ohio, United States. It was established in 1967 by a merger between Western Reserve University and the Case Institute of Technology. Case Western Reserve University comprises eight schools that offer more than 100 undergraduate programs and about 160 graduate and professional options across fields in STEM, medicine, arts, and the humanities. In 2024, the university enrolled 12,475 students (6,528 undergraduate plus 5,947 graduate and professional) from all 50 states and 106 countries and employed more than 1,182 full-time faculty members. The university's athletic teams, Case Western Reserve Spartans, play in NCAA Division III as a founding member of the University Athletic Association. Case Western Reserve University is a member of the Association of American Universities and is Carnegie Classification of Institutions of Higher Education, classified among "R1: Doctoral Univ ...
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Optical Modulator
An optical modulator is a device which is used to modulate a beam of light. The beam may be carried over free space, or propagated through an optical waveguide (optical fibre). Depending on the parameter of a light beam which is manipulated, modulators may be categorized into amplitude modulators, phase modulators, polarization modulators, etc. The easiest way to obtain modulation of intensity of a light beam is to modulate the current driving the light source, e.g. a laser diode. This sort of modulation is called ''direct modulation'', as opposed to the external modulation performed by a light modulator. For this reason light modulators are, e.g. in fiber-optic communications, called ''external light modulators''. With laser diodes where narrow linewidth is required, direct modulation is avoided due to a high bandwidth "chirping" effect when applying and removing the current to the laser. Optical modulators are used with superconductors which work properly only at low temperat ...
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Chirp
A chirp is a signal in which the frequency increases (''up-chirp'') or decreases (''down-chirp'') with time. In some sources, the term ''chirp'' is used interchangeably with sweep signal. It is commonly applied to sonar, radar, and laser systems, and to other applications, such as in spread-spectrum communications (see chirp spread spectrum). This signal type is biologically inspired and occurs as a phenomenon due to dispersion (a non-linear dependence between frequency and the propagation speed of the wave components). It is usually compensated for by using a matched filter, which can be part of the propagation channel. Depending on the specific performance measure, however, there are better techniques both for radar and communication. Since it was used in radar and space, it has been adopted also for communication standards. For automotive radar applications, it is usually called linear frequency modulated waveform (LFMW). In spread-spectrum usage, surface acoustic wave (S ...
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Chirped Pulse Amplification
Chirped pulse amplification (CPA) is a technique for amplifying an ultrashort laser pulse up to the petawatt level, with the laser pulse being stretched out temporally and spectrally, then amplified, and then compressed again. The stretching and compression uses devices that ensure that the different color components of the pulse travel different distances. CPA for lasers was introduced by Donna Strickland and Gérard Mourou at the University of Rochester in the mid-1980s, work for which they received the Nobel Prize in Physics in 2018. CPA is the technique used by most high-powered lasers in the world. Background Before the introduction of CPA in the mid-1980s, the peak power of laser pulses was limited because a laser pulse at intensities of gigawatts per square centimeter causes serious damage to the gain medium through nonlinear processes such as self-focusing. For example, some of the most powerful compressed CPA laser beams, even in an unfocused large aperture (afte ...
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Pulse Shaping
In electronics and telecommunications, pulse shaping is the process of changing a transmitted pulses' waveform to optimize the signal for its intended purpose or the communication channel. This is often done by limiting the bandwidth of the transmission and filtering the pulses to control intersymbol interference. Pulse shaping is particularly important in RF communication for fitting the signal within a certain frequency band and is typically applied after line coding and modulation. Need for pulse shaping Transmitting a signal at high modulation rate through a band-limited channel can create intersymbol interference. The reason for this is Fourier correspondences (see Fourier transform). A bandlimited signal corresponds to an infinite time signal, that causes neighboring pulses to overlap. As the modulation rate increases, the signal's bandwidth increases. When the spectrum of the signal is uniformly rectangular, a sinc shape results in the time domain. This happens if the b ...
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Spectral Phase Interferometry For Direct Electric-field Reconstruction
In ultrafast optics, spectral phase interferometry for direct electric-field reconstruction (SPIDER) is an ultrashort pulse measurement technique originally developed by Chris Iaconis and Ian Walmsley. The basics SPIDER is an interferometric ultrashort pulse measurement technique in the frequency domain based on shearing interferometer, spectral shearing interferometry. Spectral shearing interferometry is similar in concept to lateral shearing interferometry, except the shearing is performed in the frequency domain. The spectral shear is typically generated by sum-frequency mixing the test pulse with two different quasi-monochromatic frequencies (usually derived by chirping a copy of the pulse itself), although it can also be achieved by spectral filtering or even with linear electro-optic modulators for picosecond pulses. The interference between the two upconverted pulses allows the spectral phase at one frequency to be referenced to the spectral phase at a different frequency, ...
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Frequency-resolved Optical Gating
Frequency-resolved optical gating (FROG) is a general method for measuring the Spectral density, spectral phase of Ultrashort pulse, ultrashort laser pulses, which range from subfemtosecond to about a nanosecond in length. Invented in 1991 by Rick Trebino and Daniel J. Kane, FROG was the first technique to solve this problem, which is difficult because, ordinarily, to measure an event in time, a shorter event is required with which to measure it. For example, to measure a soap bubble popping requires a strobe light with a shorter duration to freeze the action. Because ultrashort laser pulses are the shortest events ever created, before FROG, it was thought by many that their complete measurement in time was not possible. FROG, however, solved the problem by measuring an "auto-spectrogram" of the pulse, in which the pulse gates itself in a nonlinear optical medium and the resulting gated piece of the pulse is then spectrally resolved as a function of the delay between the two pulse ...
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Optical Autocorrelation
In optics, various autocorrelation functions can be experimentally realized. The field autocorrelation may be used to calculate the spectrum of a source of light, while the intensity autocorrelation and the interferometric autocorrelation are commonly used to ''estimate'' the duration of ultrashort pulses produced by modelocking, modelocked lasers. The laser pulse duration cannot be easily measured by optoelectronic methods, since the response time of photodiodes and oscilloscopes are at best of the order of 200 femtoseconds, yet laser pulses can be made as short as a few femtoseconds. In the following examples, the autocorrelation signal is generated by the nonlinear process of second-harmonic generation (SHG). Other techniques based on two-photon absorption may also be used in autocorrelation measurements, as well as higher-order nonlinear optical processes such as third-harmonic generation, in which case the mathematical expressions of the signal will be slightly modified, bu ...
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Picosecond
A picosecond (abbreviated as ps) is a unit of time in the International System of Units (SI) equal to 10−12 or (one trillionth) of a second. That is one trillionth, or one millionth of one millionth of a second, or 0.000 000 000 001 seconds. A picosecond is to one second, as one second is to approximately 31,688.76 years. Multiple technical approaches achieve imaging within single-digit picoseconds: for example, the streak camera or intensified CCD (ICCD) cameras are able to picture the motion of light. One picosecond is equal to 1000 femtoseconds, or 1/1000 nanoseconds. Because the next SI unit is 1000 times larger, measurements of 10−11 and 10−10 second are typically expressed as tens or hundreds of picoseconds. Some notable measurements in this range include: * 1.0 picoseconds (1.0 ps) – cycle time for electromagnetic frequency 1 terahertz (THz), an inverse unit. This corresponds to a wavelength of 0.3 mm, as can be calculated by multiplying ...
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