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Tetraethylmethane
Tetraethylmethane is a branched alkane with 9 carbon atoms. It is a highly flammable and volatile liquid at room temperature. It is one of the isomers of nonane. References See *Neopentane Neopentane, also called 2,2-dimethylpropane, is a double-branched-chain alkane with five carbon atoms. Neopentane is a flammable gas at room temperature and pressure which can condense into a highly volatile liquid on a cold day, in an ice bath, ... External links * {{cite journal , doi = 10.1021/jo981779m , title = Molecular Structure of 3,3-Diethylpentane (Tetraethylmethane) in the Gas Phase as Determined by Electron Diffraction and ab Initio Calculations , journal = The Journal of Organic Chemistry , volume = 64 , issue = 12 , pages = 4226–4232 , year = 1999 , last1 = Alder , first1 = Roger W. , last2 = Allen , first2 = Paul R. , last3 = Hnyk , first3 = Drahomír , last4 = Rankin , first4 = David W. H. , last5 = Robertson , first5 = Heather E. , last6 = Smart , f ...
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2,2-Dimethylbutane
2,2-Dimethylbutane, trivially known as neohexane, is an organic compound with formula C6H14 or (H3C-)3-C-CH2-CH3. It is therefore an alkane, indeed the most compact and branched of the hexane isomers — the only one with a quaternary carbon and a butane (C4) backbone. Synthesis 2,2-Dimethylbutane can be synthesised by the hydroisomerisation of 2,3-dimethylbutane using an acid catalyst. It can also be synthesised by isomerization of ''n''-pentane in the presence of a catalyst containing combinations of one or more of palladium, platinum, rhodium and rhenium on a matrix of zeolite, alumina, silicon dioxide or other materials. Such reactions create a mixture of final products including isopentane, ''n''-hexane, 3-methylpentane, 2-methylpentane, 2,3-dimethylbutane and 2,2-dimethylbutane. Since the composition of the final mixture is temperature dependant the desired final component can be obtained choice of catalyst and by combinations of temperature control and distillations. ...
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2,3-Dimethylbutane
2,3-Dimethylbutane is an isomer of hexane. It has the chemical formula In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, ... (CH3)2CHCH(CH3)2. It is a colorless liquid which boils at 57.9 °C. References Alkanes {{Hydrocarbon-stub ...
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Triptane
Triptane, or 2,2,3-trimethylbutane, is an organic chemical compound with the molecular formula C7 H16 or (H3C-)3C-C(-CH3)2H. It is therefore an alkane, specifically the most compact and heavily branched of the heptane isomers, the only one with a butane (C4) backbone. Triptane is commonly used as an anti-knock additive in aviation fuels. See also *List of gasoline additives Petrol additives increase petrol's octane rating or act as corrosion inhibitors or lubricants, thus allowing the use of higher compression ratios for greater efficiency and power. Types of additives include metal deactivators, corrosion inhibitor ... References Hydrocarbons Alkanes {{Hydrocarbon-stub ...
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Tetramethylbutane
Tetramethylbutane, sometimes called hexamethylethane, is a hydrocarbon with formula C8H18 or (H3C-)3C-C(-CH3)3. It is the most heavily branched and most compact of the many octane isomers, the only one with a butane (C4) backbone. Because of its highly symmetrical structure, it has a very high melting point and a short liquid range; in fact, it is the smallest saturated acyclic hydrocarbon that appears as a solid at a room temperature of 25 °C. (Among cyclic hydrocarbons, cubane, C8H8 is even smaller and is also solid at room temperature.) It is also the most stable C8H18 isomer, with a heat of formation lower than that of ''n''-octane, a fact that has been attributed to stabilizing dispersive interactions (electron correlation) between the methyl groups (protobranching). The compound can be obtained by reaction of Grignard reagent tert-Butylmagnesium bromide with ethyl bromide, or of ethylmagnesium bromide with ''tert''-butyl bromide in the presence of manganese ...
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2,2,4-Trimethylpentane
2,2,4-Trimethylpentane, also known as isooctane or iso-octane, is an organic compound with the formula (CH3)3CCH2CH(CH3)2. It is one of several isomers of octane (C8H18). This particular isomer is the standard 100 point on the octane rating scale (the zero point is ''n''-heptane). It is an important component of gasoline, frequently used in relatively large proportions (around 10%) to increase the knock resistance of fuel. Strictly speaking, if the standard meaning of ‘iso’ is followed, the name ''isooctane'' should be reserved for the isomer 2-methylheptane. However, 2,2,4-trimethylpentane is by far the most important isomer of octane and historically it has been assigned this name. Production Isooctane is produced on a massive scale in the petroleum industry by alkylation of isobutene with isobutane. This process is conducted in alkylation units in the presence of acid catalysts. It can also be produced from isobutylene by dimerization using an Amberlyst catalyst ...
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2,3,3-Trimethylpentane
2,3,3-Trimethylpentane is a chemical compound in the family of hydrocarbons which has a formula of C8H18. It is an isomer In chemistry, isomers are molecules or polyatomic ions with identical molecular formulae – that is, same number of atoms of each element – but distinct arrangements of atoms in space. Isomerism is existence or possibility of isomers. ... of octane. References {{DEFAULTSORT:Trimethylpentane, 2,3,3- Alkanes ...
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2,3,4-Trimethylpentane
2,3,4-Trimethylpentane is a branched alkane In organic chemistry Organic chemistry is a subdiscipline within chemistry involving the science, scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms tha .... It is one of the isomers of octane. References External links2,3,4-Trimethylpentaneat environmentalchemistry.com {{DEFAULTSORT:Trimethylpentane, 2,3,4- Alkanes ...
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Tetra-tert-butylmethane
Tetra-''tert''-butylmethane is a hypothetical organic compound with formula C17H36, consisting of four ''tert''-butyl groups bonded to a central carbon atom. It would be an alkane, specifically the most compact branched isomer of heptadecane. Some calculations suggests this compound cannot exist due to the steric hindrance among the closely packed ''tert''-butyl groups, which would make it one of the smallest, if not the smallest itself, saturated and acyclic hydrocarbon that cannot exist. Other calculations suggest that the molecule would be stable, with the C–C bonds to the central ("methane") carbon having a length Length is a measure of distance. In the International System of Quantities, length is a quantity with dimension distance. In most systems of measurement a base unit for length is chosen, from which all other units are derived. In the Inte ... of 166.1 pm — longer than the typical C−C bond in order to reduce steric effects, but still shorter than ...
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2,3-Dimethylhexane
2,3-Dimethylhexane is a structural isomer In chemistry, a structural isomer (or constitutional isomer in the IUPAC nomenclature) of a compound is another compound whose molecule has the same number of atoms of each element, but with logically distinct bonds between them. The term met ... of octane. References {{DEFAULTSORT:Dimethylhexane, 2,3- Alkanes Hydrocarbons ...
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2,5-Dimethylhexane
2,5-Dimethylhexane is a branched alkane used in the aviation industry in low revolutions per minute helicopters. As an isomer In chemistry, isomers are molecules or polyatomic ions with identical molecular formulae – that is, same number of atoms of each element – but distinct arrangements of atoms in space. Isomerism is existence or possibility of isomers. ... of octane, the boiling point is very close to that of octane, but can in pure form be slightly lower. 2,5-Dimethylhexane is moderately toxic. References {{DEFAULTSORT:Dimethylhexane, 2,5- Alkanes ...
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Neopentane
Neopentane, also called 2,2-dimethylpropane, is a double-branched-chain alkane with five carbon atoms. Neopentane is a flammable gas at room temperature and pressure which can condense into a highly volatile liquid on a cold day, in an ice bath, or when compressed to a higher pressure. Neopentane is the simplest alkane with a quaternary carbon, and has achiral tetrahedral symmetry. It is one of the three structural isomers with the molecular formula C5H12 (pentanes), the other two being ''n''-pentane and isopentane. Out of these three, it is the only one to be a gas at standard conditions; the others are liquids. Nomenclature The traditional name neopentane was still retained in the 1993 IUPAC recommendations, but is no longer recommended according to the 2013 recommendations. The preferred IUPAC name is the systematic name 2,2-dimethylpropane, but the substituent numbers are superfluous because it is the only possible “dimethylpropane”. A neopentyl substituent, ofte ...
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Alkane
In organic chemistry Organic chemistry is a subdiscipline within chemistry involving the science, scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.Clay ..., an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which all the carbon–carbon bonds are single. Alkanes have the general chemical formula . The alkanes range in complexity from the simplest case of methane (), where ''n'' = 1 (sometimes called the parent molecule), to arbitrarily large and complex molecules, like Higher alkanes#Nonatetracontane to tetrapentacontane, pentacontane () or 6-ethyl-2-methyl-5-(1-methylethyl) octane, an isomer of tetradecane (). The International Union of Pure and Applied Chemistry (IUPAC) defines ...
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