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Superheating
In thermodynamics, superheating (sometimes referred to as boiling retardation, or boiling delay) is the phenomenon in which a liquid is heated to a temperature higher than its boiling point, without boiling. This is a so-called ''metastable state'' or '' metastate'', where boiling might occur at any time, induced by external or internal effects.Debenedetti, P.G.Metastable Liquids: Concepts and Principles; Princeton University Press: Princeton, NJ, USA, 1996.Maris, H., Balibar, S. (2000"Negative Pressures and Cavitation in Liquid Helium"Physics Today 53, 29 Superheating is achieved by heating a homogeneous substance in a clean container, free of nucleation sites, while taking care not to disturb the liquid. This may occur by microwaving water in a very smooth container. Disturbing the water may cause an unsafe eruption of hot water and result in burns. Cause Water is said to "boil" when bubbles of water vapor grow without bound, bursting at the surface. For a vapor bubble ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Subcooling
The term subcooling (also called undercooling) refers to the intentional process of cooling a liquid below its normal boiling point. For example, water boils at 373 K; at room temperature (293 K) liquid water is termed "subcooled". Subcooling is a common stage in refrigeration cycles and steam turbine cycles. Some rocket engines use subcooled propellants. In refrigeration systems, subcooling the refrigerant is necessary to ensure the completion of the remaining stages of the refrigeration cycle. The subcooling stage provides certainty that the refrigerant is fully liquid before it reaches the next step on the cycle, the thermal expansion valve, where the presence of gas can be disruptive.Ibrahim Dinçer, Refrigeration Systems and Applications. John Wiley & Sons, Second Edition, 2010, pp. 169-170/ref> Subcooling is often accomplished in heat exchangers. Subcooling and superheating, which are similar and inverse processes, are both important for the stability and well ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Superheating
In thermodynamics, superheating (sometimes referred to as boiling retardation, or boiling delay) is the phenomenon in which a liquid is heated to a temperature higher than its boiling point, without boiling. This is a so-called ''metastable state'' or '' metastate'', where boiling might occur at any time, induced by external or internal effects.Debenedetti, P.G.Metastable Liquids: Concepts and Principles; Princeton University Press: Princeton, NJ, USA, 1996.Maris, H., Balibar, S. (2000"Negative Pressures and Cavitation in Liquid Helium"Physics Today 53, 29 Superheating is achieved by heating a homogeneous substance in a clean container, free of nucleation sites, while taking care not to disturb the liquid. This may occur by microwaving water in a very smooth container. Disturbing the water may cause an unsafe eruption of hot water and result in burns. Cause Water is said to "boil" when bubbles of water vapor grow without bound, bursting at the surface. For a vapor bubble ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Microwave Oven
A microwave oven, or simply microwave, is an electric oven that heats and cooks food by exposing it to electromagnetic radiation in the microwave frequency range. This induces Dipole#Molecular dipoles, polar molecules in the food to rotate and produce thermal energy (heat) in a process known as dielectric heating. Microwave ovens heat food quickly and efficiently because the heating effect is fairly uniform in the outer of a homogeneous, high-water-content food item. The development of the cavity magnetron in the United Kingdom made possible the production of electromagnetic waves of a small enough wavelength (microwaves) to efficiently heat up water molecules. American electrical engineer Percy Spencer is generally credited with developing and patenting the world's first commercial microwave oven, the "Radarange", which was first sold in 1947. He based it on British radar technology which had been developed before and during World War II. Raytheon later licensed its patents ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Microwaving
A microwave oven, or simply microwave, is an electric oven that heats and cooks food by exposing it to electromagnetic radiation in the microwave frequency range. This induces polar molecules in the food to rotate and produce thermal energy (heat) in a process known as dielectric heating. Microwave ovens heat food quickly and efficiently because the heating effect is fairly uniform in the outer of a homogeneous, high-water-content food item. The development of the cavity magnetron in the United Kingdom made possible the production of electromagnetic waves of a small enough wavelength (microwaves) to efficiently heat up water molecules. American electrical engineer Percy Spencer is generally credited with developing and patenting the world's first commercial microwave oven, the "Radarange", which was first sold in 1947. He based it on British radar technology which had been developed before and during World War II. Raytheon later licensed its patents for a home-use microwa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Supercooling
Supercooling, also known as undercooling, is the process of lowering the temperature of a liquid below its freezing point without it becoming a solid. Per the established international definition, supercooling means ''‘cooling a substance below the normal freezing point without solidification’.'' IIR International Dictionary of Refrigeration, http://dictionary.iifiir.org/search.php ASHRAE Terminology, https://www.ashrae.org/technical-resources/free-resources/ashrae-terminology While it can be achieved by different physical means, the postponed solidification is most often due to the absence of nucleation, seed crystals or nuclei around which a crystal structure can form. The supercooling of water can be achieved without any special techniques other than chemical demineralization, down to . Supercooled water can occur naturally, for example in the atmosphere, animals or plants. This phenomenon was first identified in 1724 by Daniel Gabriel Fahrenheit, while developing Fahren ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nucleation Site
In thermodynamics, nucleation is the first step in the formation of either a new thermodynamic phase or structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that determines how long an observer has to wait before the new phase or self-organized structure appears. For example, if a volume of water is cooled (at atmospheric pressure) significantly below 0°C, it will tend to freeze into ice, but volumes of water cooled only a few degrees below 0°C often stay completely free of ice for long periods (supercooling). At these conditions, nucleation of ice is either slow or does not occur at all. However, at lower temperatures nucleation is fast, and ice crystals appear after little or no delay. Nucleation is a common mechanism which generates first-order phase transitions, and it is the start of the process of forming a new thermodynamic phase. In contrast, new phases at continuous phase transitions start to ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nucleation
In thermodynamics, nucleation is the first step in the formation of either a new Phase (matter), thermodynamic phase or Crystal structure, structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that determines how long an observer has to wait before the new phase or self-organized structure appears. For example, if a volume of water is cooled (at atmospheric pressure) significantly below 0°C, it will tend to Freezing, freeze into ice, but volumes of water cooled only a few degrees below 0°C often stay completely free of ice for long periods (supercooling). At these conditions, nucleation of ice is either slow or does not occur at all. However, at lower temperatures nucleation is fast, and ice crystals appear after little or no delay. Nucleation is a common mechanism which generates first-order phase transitions, and it is the start of the process of forming a new thermodynamic phase. In contrast, new phas ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boiling Chip
A boiling chip, boiling stone, or porous bit anti-bumping granule is a tiny, unevenly shaped piece of substance added to liquids to make them boil more calmly. Boiling chips are frequently employed in distillation and heating. When a liquid becomes superheated, a speck of dust or a stirring rod can cause violent flash boiling. Boiling chips provide nucleation sites so the liquid boils smoothly without becoming superheated or bumping. Use Boiling chips should not be added to liquid that is already near its boiling point, as this could also induce flash boiling. Boiling chips should not be used when cooking unless they are suitable for food-grade applications. The structure of a boiling chip traps liquid while in use, meaning that they cannot be re-used in laboratory setups. They also don't work well under vacuum; if a solution is boiling under vacuum, it is best to constantly stir it instead. Materials Boiling chips are typically made of a porous material, such as alu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boiling
Boiling or ebullition is the rapid phase transition from liquid to gas or vapor, vapour; the reverse of boiling is condensation. Boiling occurs when a liquid is heated to its boiling point, so that the vapour pressure of the liquid is equal to the pressure exerted on the liquid by the Standard atmosphere (unit), surrounding atmosphere. Boiling and evaporation are the two main forms of liquid vapourization. There are two main types of boiling: nucleate boiling, where small bubbles of vapour form at discrete points; and critical heat flux boiling, where the boiling surface is heated above a certain critical temperature and a film of vapour forms on the surface. Transition boiling is an intermediate, unstable form of boiling with elements of both types. The boiling point of water is 100 °C or 212 °F but is lower with the decreased atmospheric pressure found at higher altitudes. Boiling water is used as a method of making it potable by killing Microorganism, microbes an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metastability
In chemistry and physics, metastability is an intermediate energetic state within a dynamical system other than the system's state of least energy. A ball resting in a hollow on a slope is a simple example of metastability. If the ball is only slightly pushed, it will settle back into its hollow, but a stronger push may start the ball rolling down the slope. Bowling pins show similar metastability by either merely wobbling for a moment or tipping over completely. A common example of metastability in science is isomerisation. Higher energy isomers are long lived because they are prevented from rearranging to their preferred ground state by (possibly large) barriers in the potential energy. During a metastable state of finite lifetime, all state-describing parameters reach and hold stationary values. In isolation: *the state of least energy is the only one the system will inhabit for an indefinite length of time, until more external energy is added to the system (unique "absolu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metastate
In statistical mechanics, the metastate is a probability measure on the space of all thermodynamic states for a system with quenched randomness. The term metastate, in this context, was first used in by Charles M. Newman and Daniel L. Stein in 1996.. Two different versions have been proposed: 1) The Aizenman-Wehr construction, a canonical ensemble approach, constructs the metastate through an ensemble of states obtained by varying the random parameters in the Hamiltonian outside of the volume being considered. 2) The Newman- Stein metastate, a microcanonical ensemble In statistical mechanics, the microcanonical ensemble is a statistical ensemble that represents the possible states of a mechanical system whose total energy is exactly specified. The system is assumed to be isolated in the sense that it canno ... approach, constructs an empirical average from a deterministic (i.e., chosen independently of the randomness) subsequence of finite-volume Gibbs distributions. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bumping (chemistry)
Bumping is a phenomenon in chemistry where homogeneous liquids boiled in a test tube or other container will superheat and, upon nucleation, rapid boiling will expel the liquid from the container. In extreme cases, the container may be broken. Cause Bumping occurs when a liquid is heated or has its pressure reduced very rapidly, typically in smooth, clean glassware. The hardest part of bubble formation is the initial formation of the bubble; once a bubble has formed, it can grow quickly. Because the liquid is typically above its boiling point, when the liquid finally starts to boil, a large vapor bubble is formed that pushes the liquid out of the test tube, typically at high speed. This rapid expulsion of boiling liquid poses a serious hazard to others and oneself in the lab. Furthermore, if a liquid is boiled and cooled back down, the chance of bumping increases on each subsequent boil, because each heating cycle progressively de-gasses the liquid, reducing the number of remai ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
