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Subpsoromic Acid
Subpsoromic acid is a depsidone with the molecular formula C17H12O8 which has been isolated from the lichen '' Ocellularia praestans''. References Lichen products Oxygen heterocycles Carboxylic acids Dioxepines Heterocyclic compounds with 3 rings Methoxy compounds Lactones {{organic-compound-stub ...
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Depsidone
Depsidones (+ " depside" + "one") are chemical compounds that are sometimes found as secondary metabolites in lichens. They are ester In chemistry, an ester is a compound derived from an oxoacid (organic or inorganic) in which at least one hydroxyl group () is replaced by an alkoxy group (), as in the substitution reaction of a carboxylic acid and an alcohol. Glycerides ...s that are both depsides and cyclic ethers. An example is norstictic acid. References {{reflist Biochemistry Carboxylate esters ...
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Ocellularia Praestans
''Ocellularia'' is a genus of lichens in the family Graphidaceae. The genus was circumscribed by Georg Friedrich Wilhelm Meyer in 1825. Species *''Ocellularia africana'' *''Ocellularia allosporoides'' *'' Ocellularia andamanica'' *''Ocellularia antillensis'' *''Ocellularia aptrootiana'' *''Ocellularia arecae'' *''Ocellularia asiatica'' *''Ocellularia auberianoides'' *''Ocellularia auratipruinosa'' *''Ocellularia aurulenta'' *''Ocellularia bahiana'' *''Ocellularia baileyi'' *''Ocellularia balangoda'' *''Ocellularia bicuspidata'' *''Ocellularia bipindensis'' *''Ocellularia bonplandiae'' *''Ocellularia brunneospora'' *''Ocellularia bullata'' *'' Ocellularia cameroonensis'' *''Ocellularia cavata'' *'' Ocellularia chiriquiensis'' *''Ocellularia clandestina'' *''Ocellularia cloonanii'' *''Ocellularia concolor'' *''Ocellularia confluens'' *''Ocellularia conglomerata'' *''Ocellularia crocea'' *''Ocellularia cruentata'' *''Ocellularia decolorata'' *''Ocellularia diacida'' *''Ocellularia ...
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Lichen Products
Lichen products, also known as lichen substances, are organic compounds produced by a lichen. Specifically, they are secondary metabolites. Lichen products are represented in several different chemical classes, including terpenoids, orcinol derivatives, chromones, xanthones, depsides, and depsidones. Over 800 lichen products of known chemical structure have been reported in the scientific literature, and most of these compound are exclusively found in lichens. Examples of lichen products include usnic acid (a dibenzofuran), atranorin (a depside), lichexanthone (a xanthone), salazinic acid (a depsidone), and isolichenan, an α-glucan. Many lichen products have biological activity, and research into these effects is ongoing. Lichen products accumulate on the outer walls of the fungal hyphae, and are quite stable. Crystal deposits can be visualised using scanning electron microscopy. For this reason, even very old herbarium specimens can be analysed. The amount of lichen products i ...
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Oxygen Heterocycles
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds. Oxygen is Earth's most abundant element, and after hydrogen and helium, it is the third-most abundant element in the universe. At standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula . Diatomic oxygen gas currently constitutes 20.95% of the Earth's atmosphere, though this has changed considerably over long periods of time. Oxygen makes up almost half of the Earth's crust in the form of oxides.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. Many major classes of organic molecules in living organisms contain oxygen atoms, such as proteins, nucleic acids, carbohydrates, and fats, as d ...
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Carboxylic Acids
In organic chemistry, a carboxylic acid is an organic acid that contains a carboxyl group () attached to an R-group. The general formula of a carboxylic acid is or , with R referring to the alkyl, alkenyl, aryl, or other group. Carboxylic acids occur widely. Important examples include the amino acids and fatty acids. Deprotonation of a carboxylic acid gives a carboxylate anion. Examples and nomenclature Carboxylic acids are commonly identified by their trivial names. They at oftentimes have the suffix ''-ic acid''. IUPAC-recommended names also exist; in this system, carboxylic acids have an ''-oic acid'' suffix. For example, butyric acid (C3H7CO2H) is butanoic acid by IUPAC guidelines. For nomenclature of complex molecules containing a carboxylic acid, the carboxyl can be considered position one of the parent chain even if there are other substituents, such as 3-chloropropanoic acid. Alternately, it can be named as a "carboxy" or "carboxylic acid" substituent on ...
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Heterocyclic Compounds With 3 Rings
A heterocyclic compound or ring structure is a cyclic compound that has atoms of at least two different elements as members of its ring(s). Heterocyclic chemistry is the branch of organic chemistry dealing with the synthesis, properties, and applications of these heterocycles. Examples of heterocyclic compounds include all of the nucleic acids, the majority of drugs, most biomass (cellulose and related materials), and many natural and synthetic dyes. More than half of known compounds are heterocycles. 59% of US FDA-approved drugs contain nitrogen heterocycles. Classification The study of heterocyclic chemistry focuses especially on unsaturated derivatives, and the preponderance of work and applications involves unstrained 5- and 6-membered rings. Included are pyridine, thiophene, pyrrole, and furan. Another large class of heterocycles refers to those fused to benzene rings. For example, the fused benzene derivatives of pyridine, thiophene, pyrrole, and furan are quin ...
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Methoxy Compounds
In organic chemistry, a methoxy group is the functional group consisting of a methyl group bound to oxygen. This alkoxy group has the formula . On a benzene ring, the Hammett equation classifies a methoxy substituent at the ''para'' position as an electron-donating group, but as an electron-withdrawing group if at the ''meta'' position. At the ''ortho'' position, steric effects are likely to cause a significant alteration in the Hammett equation prediction which otherwise follows the same trend as that of the ''para'' position. Occurrence The simplest of methoxy compounds are methanol and dimethyl ether. Other methoxy ethers include anisole and vanillin. Many alkoxides contain methoxy groups, e.g. tetramethyl orthosilicate and titanium methoxide. Such compounds are often classified as methoxides. Esters with a methoxy group can be referred to as methyl esters, and the —COOCH3 substituent is called a methoxycarbonyl. Biosynthesis In nature, methoxy groups are found on nucleo ...
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