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Spinels
The spinels are any of a class of minerals of general formulation which crystallise in the cubic (isometric) crystal system, with the X anions (typically chalcogens, like oxygen and sulfur) arranged in a cubic close-packed lattice and the cations A and B occupying some or all of the octahedral and tetrahedral sites in the lattice.H-J MeyerFestkörperchemiein: H-J Meyer (ed.), ''Riedel Moderne Anorganische Chemie'', Walter de Gruyter, 2012, . Retrieved 15 April 2018. Although the charges of A and B in the prototypical spinel structure are +2 and +3, respectively (), other combinations incorporating divalent, trivalent, or tetravalent cations, including magnesium, zinc, iron, manganese, aluminium, chromium, titanium, and silicon, are also possible. The anion is normally oxygen; when other chalcogenides constitute the anion sublattice the structure is referred to as a thiospinel. A and B can also be the same metal with different valences, as is the case with magnetite, (as ), which ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spinel
Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , a diminutive form of ''spine,'' in reference to its pointed crystals. Properties Spinel crystallizes in the isometric system; common crystal forms are octahedron, octahedra, usually Crystal twinning, twinned. It has no true Cleavage (crystal), cleavage, but shows an octahedral Parting (crystal), parting and a conchoidal fracture. Its Mohs scale of mineral hardness, hardness is 8, its specific gravity is 3.5–4.1, and it is transparent to opaque with a vitreous to dull Lustre (mineralogy), luster. It may be colorless, but is usually various shades of red, lavender (color), lavender, blue, green, brown, black, or yellow. Chromium(III) causes the red color in spinel from Burma. Some spinels are among the most famous gemstones; among them are the Black Prince's Ruby and the "Timur ruby" in the British Crown Jewels ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pleonaste
Ceylonite (first cited 1793) and pleonaste (first cited 1801) or pleonast are dingy blue or grey to black varieties of spinel group, spinel. Ceylonite, named for the island of Ceylon, is a ferroan spinel with Mg:Fe from 3:1 and 1:1, and little or no ferric iron. Pleonaste is named from the Greek language, Greek for 'abundant,' for its many crystal forms, and is distinguished chemically by low Mg:Fe ratios of approximately 1:3. It is sometimes used as a gemstone.Precious stones and gems, their history and distinguishing characteristics By Edwin William Streeter, p.33-34 Composition The mineral ceylonite has the chemical composition of (Mg, Fe2+) Al2O4, putting it into a group of minerals known as the spinel group, or the oxide spinels. The oxide spinels have a formula of the model [A][B]2O4; where [A] is commonly Fe2+, Mg2+, or Mn2+, and [B] is Fe3+, Al3+, or Cr3+. It is an iron-rich variety of the spinel mineral species. Structure Ceylonite has the structural formula [A]Al2O4, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ruby
Ruby is a pinkish-red-to-blood-red-colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sapphires; given that the rest of the corundum species are called as such, rubies are sometimes referred to as "red sapphires". Ruby is one of the traditional cardinal gems, alongside amethyst, sapphire, emerald, and diamond. The word ''ruby'' comes from ''ruber'', Latin for red. The color of a ruby is due to the presence of chromium. Some gemstones that are popularly or historically called rubies, such as the Black Prince's Ruby in the British Imperial State Crown, are actually spinels. These were once known as "Balas rubies". The quality of a ruby is determined by its color, cut, and clarity, which, along with carat weight, affect its value. The brightest and most valuable shade of red, called blood-red or pigeon blood, commands a lar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Minerals'; p. 1. In the series ''Geology: Landforms, Minerals, and Rocks''. Rosen Publishing Group. The Geology, geological definition of mineral normally excludes compounds that occur only in living organisms. However, some minerals are often biogenic (such as calcite) or organic compounds in the sense of chemistry (such as mellite). Moreover, living organisms often synthesize inorganic minerals (such as hydroxylapatite) that also occur in rocks. The concept of mineral is distinct from rock (geology), rock, which is any bulk solid geologic material that is relatively homogeneous at a large enough scale. A rock may consist of one type of mineral or may be an aggregate (geology), aggregate of two or more different types of minerals, spaci ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thiospinel
The thiospinel group is a group of sulfide minerals with a general formula where A is nominally a +2 metal, B is a +3 metal and X is -2 sulfide or similar anion (selenide or telluride). ''Thio'' refers to sulfur and ''spinel'' indicates their isometric spinel-like structure. As the chalcogens S, Se and Te are less electronegative than oxygen, the bonding in these materials is generally more covalent than in the oxospinels. Some are (magnetic) semiconductors but others display, at times complicated, metallic behavior, often coupled with equally complicated magnetic properties. The assignment of oxidation state In chemistry, the oxidation state, or oxidation number, is the hypothetical Electrical charge, charge of an atom if all of its Chemical bond, bonds to other atoms are fully Ionic bond, ionic. It describes the degree of oxidation (loss of electrons ...s is also not always as straightforward as in the more ionic oxocompounds, as is shown in the case of carrollite. Group m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lithium Ion Battery
A lithium-ion or Li-ion battery is a type of rechargeable battery that uses the reversible intercalation of Li+ ions into electronically conducting solids to store energy. Li-ion batteries are characterized by higher specific energy, energy density, and energy efficiency and a longer cycle life and calendar life than other types of rechargeable batteries. Also noteworthy is a dramatic improvement in lithium-ion battery properties after their market introduction in 1991; over the following 30 years, their volumetric energy density increased threefold while their cost dropped tenfold. In late 2024 global demand passed per year, while production capacity was more than twice that. The invention and commercialization of Li-ion batteries has had a large impact on technology, as recognized by the 2019 Nobel Prize in Chemistry. Li-ion batteries have enabled portable consumer electronics, laptop computers, cellular phones, and electric cars. Li-ion batteries also see significant us ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cuprospinel
Cuprospinel is a mineral. Cuprospinel is an inverse spinel with the chemical formula CuFe2O4, where copper substitutes some of the iron cations in the structure. Its structure is similar to that of magnetite, Fe3O4, yet with slightly different chemical and physical properties due to the presence of copper. The type locality (geology), type locality of cuprospinel is Baie Verte, Newfoundland and Labrador, Baie Verte, Newfoundland and Labrador, Newfoundland, Canada, where the mineral was found in an exposed ore dump. The mineral was first characterized by Ernest Henry Nickel, a mineralogist with the Department of Energy, Mines and Resources in Australia, in 1973. Cuprospinel is also found in other places, for example, in Hubei province, China and at Tolbachik volcano in Kamchatka, Russia. Structural properties Cuprospinel, like many other spinels has the general formula AB2O4. Yet, cuprospinel is an ''inverse'' spinel in that its ''A'' element, in this case copper (Cu2+), only o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Octahedral Molecular Geometry
In chemistry, octahedral molecular geometry, also called square bipyramidal, describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The octahedron has eight faces, hence the prefix '' octa''. The octahedron is one of the Platonic solids, although octahedral molecules typically have an atom in their centre and no bonds between the ligand atoms. A perfect octahedron belongs to the point group Oh. Examples of octahedral compounds are sulfur hexafluoride SF6 and molybdenum hexacarbonyl Mo(CO)6. The term "octahedral" is used somewhat loosely by chemists, focusing on the geometry of the bonds to the central atom and not considering differences among the ligands themselves. For example, , which is not octahedral in the mathematical sense due to the orientation of the bonds, is referred to as octahedral. The concept of octahedral coordination geometry was developed by Alfred ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Close-packing
In geometry, close-packing of equal spheres is a dense arrangement of congruent spheres in an infinite, regular arrangement (or lattice). Carl Friedrich Gauss proved that the highest average density – that is, the greatest fraction of space occupied by spheres – that can be achieved by a lattice packing is :\frac \approx 0.74048. The same packing density can also be achieved by alternate stackings of the same close-packed planes of spheres, including structures that are aperiodic in the stacking direction. The Kepler conjecture states that this is the highest density that can be achieved by any arrangement of spheres, either regular or irregular. This conjecture was proven by Thomas Hales. The highest density is so far known only for 1, 2, 3, 8, and 24 dimensions. Many crystal structures are based on a close-packing of a single kind of atom, or a close-packing of large ions with smaller ions filling the spaces between them. The cubic and hexagonal arrangements are very cl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cubic Crystal System
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There are three main varieties of these crystals: *Primitive cubic (abbreviated ''cP'' and alternatively called simple cubic) *Body-centered cubic (abbreviated ''cI'' or bcc) *Face-centered cubic (abbreviated ''cF'' or fcc) Note: the term fcc is often used in synonym for the ''cubic close-packed'' or ccp structure occurring in metals. However, fcc stands for a face-centered cubic Bravais lattice, which is not necessarily close-packed when a motif is set onto the lattice points. E.g. the diamond and the zincblende lattices are fcc but not close-packed. Each is subdivided into other variants listed below. Although the ''unit cells'' in these crystals are conventionally taken to be cubes, the primitive unit cells often are not. Bravais lattices The three Bravais latices ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Galaxite
Galaxite, also known as 'mangan-spinel' is an Cubic crystal system, isometric mineral belonging to the spinel group of oxide minerals, oxides with the ideal chemical formula . It is sometimes used as a gemstone.Tables of Gemstone Identification By Roger Dedeyne, Ivo Quintens, p.282 Occurrence It was first described in 1932 for an occurrence at Bald Knob, Alleghany County, North Carolina near its namesakes, the town of Galax, Virginia, named after the plant galax or wandflower which grows in the area. Galaxite generally occurs as small granular aggregates with a red-brownish tone. It has a vitreous Lustre (mineralogy), luster and leaves a brownish-red streak. It is rated 7.5 on the Mohs Scale. It occurs in carbonate-rich Metamorphism, metamorphosed manganese ore deposits. It occurs associated with alleghanyite, rhodonite, sonolite, spessartine, tephroite, kutnohorite, manganhumite, jacobsite, kellyite and alabandite in the Bald Knob area. Associated minerals include katoptrite, mag ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
