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Scrutinyite
Scrutinyite is a rare oxide mineral and is the alpha crystalline form of lead dioxide (α-PbO2), plattnerite being the other, beta form. The mineral was first reported in 1988 and its name reflects the scrutiny and efforts required to identify it from a very limited amount of available sample material. Identification The synthetic orthorhombic form of lead dioxide, α-PbO2, was known from 1941. Although natural lead dioxide has been known, as the mineral plattnerite (β-PbO2), since 1845, its alpha form could only be recognized in 1981 and reliably identified in 1988. The new mineral was spotted in several samples collected at Bingham, New Mexico and Mapimí, Durango, Mexico. It was first thought to be minium (lead tetroxide mineral) because of its high lead content, brown color and association with other lead oxide minerals plattnerite and murdochite. Its holotype specimen consisted of crystalline plates 25–30 micrometers (μm) across and 1–2 μm thick with the total w ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
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Lead Dioxide
Lead(IV) oxide, commonly known as lead dioxide, is an inorganic compound with the chemical formula . It is an oxide where lead is in an oxidation state of +4. It is a dark-brown solid which is insoluble in water. It exists in two crystalline forms. It has several important applications in electrochemistry, in particular as the positive plate of lead acid batteries. Properties Physical Lead dioxide has two major polymorphs, alpha and beta, which occur naturally as rare minerals scrutinyite and plattnerite, respectively. Whereas the beta form had been identified in 1845, α- was first identified in 1946 and found as a naturally occurring mineral 1988. The alpha form has orthorhombic symmetry, space group Pbcn (No. 60), Pearson symbol ''oP''12, lattice constants ''a'' = 0.497 nm, ''b'' = 0.596 nm, ''c'' = 0.544 nm, ''Z'' = 4 (four formula units per unit cell). The lead atoms are six-coordinate. The symmetry of the beta form is tetragonal, space group P42/mnm ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
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Oxide Mineral
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. Minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. Simple oxides *XO form **Periclase group *** Periclase *** Manganosite **Zincite group *** Zincite *** Bromellite *** Tenorite *** Litharge * form ** Cuprite **Ice * form **Hematite group ***Corundum ***Hematite *** Ilmenite * form **Rutile group ***Rutile *** Pyrolusite *** Cassiterite ** Baddeleyite ** Uraninite ** Thorianite * form **Spinel group ***Spinel ***Gahnite ***Magnetite *** Franklinite ***Chromite ** Chrysoberyl ** Columbite *Hydroxide subgroup: **Brucite ** Manganite ** Romanèchite **Goethite group: *** Diaspore ***Goethite Nickel–Strunz class 4: oxides IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 20 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
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Oxide Minerals
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. Minerals with complex anion groups such as the Silicate mineral, silicates, Sulfate mineral, sulfates, carbonate mineral, carbonates and Phosphate mineral, phosphates are classed separately. Simple oxides *XO form **Periclase group ***Periclase ***Manganosite **Zincite group ***Zincite ***Bromellite ***Tenorite ***Litharge * form **Cuprite **Ice * form **Hematite group ***Corundum ***Hematite ***Ilmenite * form **Rutile group ***Rutile ***Pyrolusite ***Cassiterite **Baddeleyite **Uraninite **Thorianite * form **Spinel group ***Spinel ***Gahnite ***Magnetite ***Franklinite ***Chromite **Chrysoberyl **Columbite *Hydroxide subgroup: **Brucite **Manganite **Romanèchite **Goethite group: ***Diaspore ***Goethite Nickel–Strunz class 4: oxides Internationa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
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Oxide Mineral
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. Minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. Simple oxides *XO form **Periclase group *** Periclase *** Manganosite **Zincite group *** Zincite *** Bromellite *** Tenorite *** Litharge * form ** Cuprite **Ice * form **Hematite group ***Corundum ***Hematite *** Ilmenite * form **Rutile group ***Rutile *** Pyrolusite *** Cassiterite ** Baddeleyite ** Uraninite ** Thorianite * form **Spinel group ***Spinel ***Gahnite ***Magnetite *** Franklinite ***Chromite ** Chrysoberyl ** Columbite *Hydroxide subgroup: **Brucite ** Manganite ** Romanèchite **Goethite group: *** Diaspore ***Goethite Nickel–Strunz class 4: oxides IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 20 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
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Quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical formula of Silicon dioxide, SiO2. Quartz is, therefore, classified structurally as a Silicate mineral#Tectosilicates, framework silicate mineral and compositionally as an oxide mineral. Quartz is the second most abundant mineral in Earth's continental crust, behind feldspar. Quartz exists in two forms, the normal α-quartz and the high-temperature β-quartz, both of which are chiral. The transformation from α-quartz to β-quartz takes place abruptly at . Since the transformation is accompanied by a significant change in volume, it can easily induce microfracturing of ceramics or rocks passing through this temperature threshold. There are many different varieties of quartz, several of which are classifi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
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Orthorhombic Minerals
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal. Bravais lattices There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , row oC, column Primitive, where the cell parameters are given as a1 = a2, α = β = 90° it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the prim ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
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Lead Minerals
Lead () is a chemical element; it has symbol Pb (from Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited to organolead compounds. Like the lighter members of the group, lead tends to bond with itself; it can form chains and polyhe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
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Pearson Symbol
The Pearson symbol, or Pearson notation, is used in crystallography as a means of describing a crystal structure. It was originated by William Burton Pearson and is used extensively in Pearson's handbook of crystallographic data for intermetallic phases. The symbol is made up of two letters followed by a number. For example: * Diamond structure, cF8 * Rutile structure, tP6 Construction The two letters in the Pearson symbol specify the Bravais lattice, and more specifically, the lower-case letter specifies the Crystal system, crystal family, while the upper-case letter the Lattice (group), lattice type. The number at the end of the Pearson symbol gives the number of the atoms in the conventional unit cell (atoms which satisfy 1 > x,y,z \geq 0 for the atom's position (x,y,z) in the unit cell). [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
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Space Group
In mathematics, physics and chemistry, a space group is the symmetry group of a repeating pattern in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of the pattern that leave it unchanged. In three dimensions, space groups are classified into 219 distinct types, or 230 types if chiral copies are considered distinct. Space groups are discrete cocompact groups of isometries of an oriented Euclidean space in any number of dimensions. In dimensions other than 3, they are sometimes called Bieberbach groups. In crystallography, space groups are also called the crystallographic or Fedorov groups, and represent a description of the symmetry of the crystal. A definitive source regarding 3-dimensional space groups is the ''International Tables for Crystallography'' . History Space groups in 2 dimensions are the 17 wallpaper groups which have been known for several centuries, though the proof that the list ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
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Hydroxyl
In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydroxy groups. Both the negatively charged anion , called hydroxide, and the neutral radical , known as the hydroxyl radical, consist of an unbonded hydroxy group. According to IUPAC definitions, the term ''hydroxyl'' refers to the hydroxyl radical () only, while the functional group is called a ''hydroxy group''. Properties Water, alcohols, carboxylic acids, and many other hydroxy-containing compounds can be readily deprotonated due to a large difference between the electronegativity of oxygen (3.5) and that of hydrogen (2.1). Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack thi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
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Energy-dispersive X-ray Spectroscopy
Energy-dispersive X-ray spectroscopy (EDS, EDX, EDXS or XEDS), sometimes called energy dispersive X-ray analysis (EDXA or EDAX) or energy dispersive X-ray microanalysis (EDXMA), is an analytical technique used for the elemental analysis or chemical characterization of a sample. It relies on an interaction of some source of X-ray excitation and a sample. Its characterization capabilities are due in large part to the fundamental principle that each element has a unique atomic structure allowing a unique set of peaks on its electromagnetic emission spectrum (which is the main principle of spectroscopy). The peak positions are predicted by the Moseley's law with accuracy much better than experimental resolution of a typical EDX instrument. To stimulate the emission of characteristic X-rays from a specimen a beam of electrons or X-ray is focused into the sample being studied. At rest, an atom within the sample contains ground state (or unexcited) electrons in discrete energy levels ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |