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Robert F. Curl Jr.
Robert Floyd Curl Jr. (August 23, 1933 – July 3, 2022) was an American chemist who was Pitzer–Schlumberger Professor of Natural Sciences and professor of chemistry at Rice University. He was awarded the Nobel Prize in Chemistry in 1996 for the discovery of the nanomaterial buckminsterfullerene, and hence the fullerene class of materials, along with Richard Smalley (also of Rice University) and Harold Kroto of the University of Sussex. Early life and education Born in Alice, Texas, United States, Curl was the son of a Methodist minister. Due to his father's missionary work, his family moved several times within southern and southwestern Texas, and the elder Curl was involved in starting the San Antonio Medical Center's Methodist Hospital. Curl attributes his interest in chemistry to a chemistry set he received as a nine-year-old, recalling that he ruined the finish on his mother's porcelain stove when nitric acid boiled over onto it. He is a graduate of Thomas Jefferson ...
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Alice, Texas
Alice is a city in and the county seat of Jim Wells County, Texas, Jim Wells County, Texas, United States, in the South Texas region of the state. The population was 19,104 at the 2010 United States Census, 2010 census. Alice was established in 1888. The city was originally named "Bandana", then "Kleberg", and finally "Alice" after Alice Gertrudis King Kleberg, the daughter of Richard King (entrepreneur), Richard King, who established the King Ranch. History Alice originated from the defunct community of Collins, to the east. c. 1880, the San Antonio and Aransas Pass Railway attempted to build a line through Collins, which then had approximately 2,000 inhabitants. The townspeople were not amenable to selling their land to the railroad company; consequently, the railroad site was moved 3 miles west, and in 1883, a depot called "Bandana" was established at its junction with the Corpus Christi, San Diego and Rio Grande Railway. Bandana soon became a thriving cattle-shipping point, a ...
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Methodist
Methodism, also called the Methodist movement, is a Protestant Christianity, Christian Christian tradition, tradition whose origins, doctrine and practice derive from the life and teachings of John Wesley. George Whitefield and John's brother Charles Wesley were also significant early leaders in the movement. They were named ''Methodists'' for "the methodical way in which they carried out their Christian faith". Methodism originated as a Christian revival, revival movement within Anglicanism with roots in the Church of England in the 18th century and became a separate denomination after Wesley's death. The movement spread throughout the British Empire, the United States and beyond because of vigorous Christian mission, missionary work, and today has about 80 million adherents worldwide. Most List of Methodist denominations, Methodist denominations are members of the World Methodist Council. Wesleyan theology, which is upheld by the Methodist denominations, focuses on Sanc ...
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Bond Rotation Barrier
In chemistry, rotamers are chemical species that differ from one another primarily due to rotations about one or more single bonds. Various arrangements of atoms in a molecule that differ by rotation about single bonds can also be referred to as conformations. Conformers/rotamers differ little in their energies, so they are almost never separable in a practical sense. Rotations about single bonds are subject to small energy barriers. When the time scale for interconversion is long enough for isolation of individual rotamers (usually arbitrarily defined as a half-life of interconversion of 1000 seconds or longer), the species are termed atropisomers (''see:'' atropisomerism). The ring-flip of substituted cyclohexanes constitutes a common form of conformers. The study of the energetics of bond rotation is referred to as conformational analysis. In some cases, conformational analysis can be used to predict and explain product selectivity, mechanisms, and rates of reactions. Conform ...
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Microwave Spectroscopy
Microwave spectroscopy is the spectroscopy method that employs microwaves, i.e. electromagnetic radiation at GHz frequencies, for the study of matter. History The ammonia molecule NH3 is shaped like a pyramid 0.38 Å in height, with an equilateral triangle of hydrogens forming the base.The nitrogen situated on the axis has two equivalent equilibrium positions above and below the triangle of hydrogens, and this raises the possibility of the nitrogen tunneling up and down, through the plane of the H-atoms. In 1932 Dennison et al. ... analyzed the vibrational energy of this molecule and concluded that the vibrational energy would be split into pairs by the presence of these two equilibrium positions. The next year Wright and Randall observed ... a splitting of 0.67 cm–1 in far infrared lines, corresponding to a frequency of 20 GHz, the value predicted by theory. In 1934 Cleeton and Williams ... constructed a grating echelle spectrometer in order to measure this splitting directl ...
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Edgar Bright Wilson
Edgar Bright Wilson Jr. (December 18, 1908 – July 12, 1992) was an American chemist. Wilson was a prominent and accomplished chemist and teacher, recipient of the National Medal of Science in 1975, Guggenheim Fellowships in 1949 and 1970, the Elliott Cresson Medal in 1982, and a number of honorary doctorates. He was a member of both the American Academy of Arts and Sciences, the American Philosophical Society, and the United States National Academy of Sciences. He was also the Theodore William Richards Professor of Chemistry, Emeritus at Harvard University. One of his sons, Kenneth G. Wilson, was awarded the Nobel Prize in physics in 1982. E. B. Wilson was a student and protégé of Nobel laureate Linus Pauling and was a coauthor with Pauling of ''Introduction to Quantum Mechanics'', a graduate level textbook in Quantum Mechanics. Wilson was also the thesis advisor of Nobel laureate Dudley Herschbach. Wilson was elected to the first class of the Harvard Society of Fellows. W ...
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Disiloxane
Disiloxane has the chemical formula . It is the simplest known siloxane with hydrogen only R groups. The molecule contains six equivalent Si−H bonds and two equivalent Si−O bonds. Disiloxane exists as a colorless, pungent gas under standard conditions. However, it is generally safe for human use as evidence in its widespread use in cosmetics. It is also commonly known as disilyl ether, disilyl oxide, and perhydrodisiloxane Structure Disiloxane has a simple structure that consists of a siloxane bond (Si−O−Si) and hydrogen R groups. The structure of disiloxane has been studied by a variety of spectroscopic methods such as electron diffraction, X-ray crystallography, dipole moment, and nuclear magnetic resonance spectroscopy. Due to their unusual nature, the Si−O−Si bond angles are commonly studied. These bonds typically exhibit angles that are larger than average, around 130 to 160 degrees, and larger bond lengths are not uncommon. For example, in the solid state at ...
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Bond Angle
Molecular geometry is the three-dimensional arrangement of the atoms that constitute a molecule. It includes the general shape of the molecule as well as bond lengths, bond angles, torsional angles and any other geometrical parameters that determine the position of each atom. Molecular geometry influences several properties of a substance including its reactivity, polarity, phase of matter, color, magnetism and biological activity. The angles between bonds that an atom forms depend only weakly on the rest of a molecule, i.e. they can be understood as approximately local and hence transferable properties. Determination The molecular geometry can be determined by various spectroscopic methods and diffraction methods. IR, microwave and Raman spectroscopy can give information about the molecule geometry from the details of the vibrational and rotational absorbance detected by these techniques. X-ray crystallography, neutron diffraction and electron diffraction can give molecu ...
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Infrared Spectroscopy
Infrared spectroscopy (IR spectroscopy or vibrational spectroscopy) is the measurement of the interaction of infrared radiation with matter by absorption, emission, or reflection. It is used to study and identify chemical substances or functional groups in solid, liquid, or gaseous forms. It can be used to characterize new materials or identify and verify known and unknown samples. The method or technique of infrared spectroscopy is conducted with an instrument called an infrared spectrometer (or spectrophotometer) which produces an infrared spectrum. An IR spectrum can be visualized in a graph of infrared light absorbance (or transmittance) on the vertical axis vs. frequency, wavenumber or wavelength on the horizontal axis. Typical units of wavenumber used in IR spectra are reciprocal centimeters, with the symbol cm−1. Units of IR wavelength are commonly given in micrometers (formerly called "microns"), symbol μm, which are related to the wavenumber in a reciprocal way ...
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Doctorate
A doctorate (from Latin ''doctor'', meaning "teacher") or doctoral degree is a postgraduate academic degree awarded by universities and some other educational institutions, derived from the ancient formalism '' licentia docendi'' ("licence to teach"). In most countries, a research degree qualifies the holder to teach at university level in the degree's field or work in a specific profession. There are a number of doctoral degrees; the most common is the Doctor of Philosophy (PhD), awarded in many different fields, ranging from the humanities to scientific disciplines. Many universities also award honorary doctorates to individuals deemed worthy of special recognition, either for scholarly work or other contributions to the university or society. History Middle Ages The term ''doctor'' derives from Latin, meaning "teacher" or "instructor". The doctorate (Latin: ''doctoratus'') appeared in medieval Europe as a license to teach Latin (''licentia docendi'') at a university. Its ...
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Bachelor Of Science
A Bachelor of Science (BS, BSc, B.S., B.Sc., SB, or ScB; from the Latin ') is a bachelor's degree that is awarded for programs that generally last three to five years. The first university to admit a student to the degree of Bachelor of Science was the University of London in 1860. In the United States, the Lawrence Scientific School first conferred the degree in 1851, followed by the University of Michigan in 1855. Nathaniel Shaler, who was Harvard's Dean of Sciences, wrote in a private letter that "the degree of Bachelor of Science came to be introduced into our system through the influence of Louis Agassiz, who had much to do in shaping the plans of this School." Whether Bachelor of Science or Bachelor of Arts degrees are awarded in particular subjects varies between universities. For example, an economics student may graduate as a Bachelor of Arts in one university but as a Bachelor of Science in another, and occasionally, both options are offered. Some universities follo ...
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San Antonio, Texas
San Antonio ( ; Spanish for "Anthony of Padua, Saint Anthony") is a city in the U.S. state of Texas and the most populous city in Greater San Antonio. San Antonio is the List of Texas metropolitan areas, third-largest metropolitan area in Texas and the List of Metropolitan Statistical Areas, 24th-largest metropolitan area in the United States at 2.6 million people in the 2020 United States census. It is the most populous city in and the county seat of Bexar County. San Antonio is the List of United States cities by population, seventh-most populous city in the United States, and the second-most populous in the Southern United States List of municipalities in Texas, and Texas, after Houston. Founded as a Spanish colonization of the Americas, Spanish mission and colonial outpost in 1718, the city in 1731 became the first chartered civil settlement in what is now present-day Texas. The area was then part of the Spanish Empire. From 1821 to 1836, it was part of the Mexico, Mexican ...
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Thomas Jefferson High School (San Antonio, TX)
Thomas Jefferson High School is a public high school in San Antonio, Texas and is one of ten high schools in the San Antonio Independent School District. Completed in 1932 at a cost of $1,250,000, it was the third high school built in the city. During 20222023, Jefferson High School had an enrollment of 1,686 students and a student to teacher ratio of 14.40. The school received an overall rating of "B" from the Texas Education Agency for the 20212022 school year. History The SAISD school board paid $94,588.75 to buy "Spanish Acres," a property, to develop the third high school in San Antonio. Construction began in the fall of 1930 and ended in January 1932.School History
." Thomas Jefferson High School. Retrieved on September 13, 2016.
It was built for over $1.25 million.
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