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Realgar
Realgar ( ), also known as arsenic blende, ruby sulphur or ruby of arsenic, is an arsenic sulfide mineral with the chemical formula α-. It is a soft, sectile mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in association with the related mineral, orpiment (). It is orange-red in color, melts at 320 °C, and burns with a bluish flame releasing fumes of arsenic and sulfur. Realgar is soft with a Mohs hardness of 1.5 to 2 and has a specific gravity of 3.5. Its streak is orange colored. It is trimorphous with pararealgar and bonazziite. Etymology Its name comes from the Arabic ''rahj al-ġār'' ( , "powder of the mine"), via Medieval Latin, and its earliest record in English is in the 1390s. Uses Realgar is a minor ore of arsenic extracted in China, Peru, and the Philippines. Historical uses Realgar was used by firework manufacturers to create the color white in fireworks prior to the availability of powdered metals such as al ...
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Pararealgar
Pararealgar is an arsenic sulfide mineral with the chemical formula , also represented as AsS. It forms gradually from realgar under exposure to light. Its name derives from the fact that its elemental composition is identical to realgar, . It is soft with a Mohs hardness of 1 - 1.5, is yellow orange in colour, and its monoclinic prismatic crystals are very brittle, easily crumbling to powder. It is one of the sulfides of arsenic and is one of two isomers of . It forms upon exposure of the symmetrical isomer to light. Its name derives from the fact that its elemental composition is identical to realgar, . Structure Both isomers of are molecular, in contrast to the other main sulfide of arsenic, orpiment (), which is polymeric. In pararealgar, there are three kinds of As centres (and three kinds of S centres). The molecule has Cs symmetry. In realgar, the four As (and four S) centres are equivalent and the molecule has D2d symmetry. An analogous pair of isomers is also recognized ...
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Arsenic Blende
Arsenic blende or ''Arsenblende'' () is a trivial name that has partially fallen out of scientific use, used by mineralogists, as well as representatives of mining and craft professions in relation to at least two similar ore minerals — orpiment and realgar,''Krivovichev V. G.'' Mineralogical glossary. Scientific editor A. G. Bulakh. — St.Petersburg: St.Petersburg Univ. Publ. House. 2009. — 556 p. — ISBN 978-5-288-04863-0 in composition — arsenic sulfides. History of the term Both of these minerals, realgar and orpiment, have been mined for a very long time, for thousands of years. They were mined as natural dyes, as medicinal agents, and as preparations that were important in alchemical practice. Their use as pigments was very significant, both in pure form and in mixed form; for example, orpiment was constantly required to make up the green dye that was used to dye wool in the Middle Ages in Western Europe. Arsenic blende was used even more widely in medicine; for ...
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Orpiment
Orpiment, also known as ″yellow arsenic blende″ is a deep-colored, orange-yellow arsenic sulfide mineral with formula . It is found in volcanic fumaroles, low-temperature hydrothermal veins, and hot springs and may be formed through sublimation (phase transition), sublimation. Orpiment takes its name from the Latin ''auripigmentum'' (''aurum'', "gold" + ''pigmentum'', "pigment"), due to its deep-yellow color. Orpiment once was widely used in artworks, medicine, and other applications. Because of its toxicity and instability, its usage has declined. Etymology The Latin ''auripigmentum'' (''aurum'', "gold" + ''pigmentum'', "pigment") referred both to its deep-yellow color and to the historical belief that it was thought to contain gold. The Latin term was used by Pliny the Elder, Pliny in the first century CE. The Greek for orpiment was ''arsenikon'', deriving from the Greek word ''arsenikos'', meaning "male", from the belief that metals were of different sexes. This Greek te ...
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Arsenic
Arsenic is a chemical element; it has Symbol (chemistry), symbol As and atomic number 33. It is a metalloid and one of the pnictogens, and therefore shares many properties with its group 15 neighbors phosphorus and antimony. Arsenic is notoriously toxic. It occurs naturally in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. It has various Allotropes of arsenic, allotropes, but only the grey form, which has a metallic appearance, is important to industry. The primary use of arsenic is in alloys of lead (for example, in car batteries and ammunition). Arsenic is also a common n-type dopant in semiconductor electronic devices, and a component of the III–V compound semiconductor gallium arsenide. Arsenic and its compounds, especially the trioxide, are used in the production of pesticides, treated wood products, herbicides, and insecticides. These applications are declining with the increasing recognition of the persistent tox ...
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Arsenolite
Arsenolite is an arsenic mineral, chemical formula As2O3. It is formed as an oxidation product of arsenic sulfides. Commonly found as small octahedra it is white, but impurities of realgar or orpiment may give it a pink or yellow hue. It can be associated with its dimorph claudetite (a monoclinic form of As2O3) as well as realgar (As4S4), orpiment (As2S3) and erythrite, Co3(AsO4)2·8H2O. Arsenolite belongs to the minerals which are highly toxic. Occurrence It was first described in 1854 for an occurrence in the St Andreasberg District, Harz Mountains, Lower Saxony, Germany. It occurs by the oxidation of arsenic-bearing sulfides in hydrothermal veins Veins () are blood vessels in the circulatory system of humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are those of the pulmonary and fetal c .... It also occurs as a result of mine or coal seam fires. References Arsen ...
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Sulfide Mineral
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide () as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenide mineral, selenides, the telluride mineral, tellurides, the arsenide mineral, arsenides, the antimonide mineral, antimonides, the bismuthinides, the sulfarsenides and the sulfosalts.http://www.minerals.net/mineral/sort-met.hod/group/sulfgrp.htm Minerals.net Dana Classification, SulfidesKlein, Cornelis and Cornelius S. Hurlbut, Jr., 1986, ''Manual of Mineralogy'', Wiley, 20th ed., pp 269-293 Sulfide minerals are inorganic compounds. Minerals Common or important examples include: * Acanthite *Chalcocite *Bornite *Galena *Sphalerite *Chalcopyrite *Pyrrhotite *Millerite *Pentlandite *Covellite *Cinnabar *Realgar *Orpiment *Stibnite *Pyrite *Marcasite *Molybdenite Sulfarsenides: *Cobaltite *Arsenopyrite *Gersdorffite Sulfosalts: *Pyrargyrite *Pro ...
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Medieval Latin
Medieval Latin was the form of Literary Latin used in Roman Catholic Church, Roman Catholic Western Europe during the Middle Ages. It was also the administrative language in the former Western Roman Empire, Roman Provinces of Mauretania, Numidia (Roman province), Numidia and Africa (Roman province), Africa Proconsularis under the Vandals, the Exarchate of Africa, Byzantines and the Kingdom of Altava, Romano-Berber Kingdoms, until it declined after the Arab conquest of North Africa, Arab Conquest. Medieval Latin in Southern and Central Visigothic Kingdom, Visigothic Hispania, conquered by the Arabs immediately after North Africa, experienced a similar fate, only recovering its importance after the Reconquista by the Northern Christian Kingdoms. In this region it served as the primary written language, though local languages were also written to varying degrees. Latin functioned as the main medium of scholarly exchange, as the liturgical language of the Roman Catholic Church, Churc ...
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Aluminium
Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has a great affinity towards oxygen, passivation (chemistry), forming a protective layer of aluminium oxide, oxide on the surface when exposed to air. It visually resembles silver, both in its color and in its great ability to reflect light. It is soft, magnetism, nonmagnetic, and ductility, ductile. It has one stable isotope, 27Al, which is highly abundant, making aluminium the abundance of the chemical elements, 12th-most abundant element in the universe. The radioactive decay, radioactivity of aluminium-26, 26Al leads to it being used in radiometric dating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ ...
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Magnesium
Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic table), it occurs naturally only in combination with other elements and almost always has an oxidation state of +2. It reacts readily with air to form a thin Passivation (chemistry), passivation coating of magnesium oxide that inhibits further corrosion of the metal. The free metal burns with a brilliant-white light. The metal is obtained mainly by electrolysis of magnesium Salt (chemistry), salts obtained from brine. It is less dense than aluminium and is used primarily as a component in strong and lightweight magnesium alloy, alloys that contain aluminium. In the cosmos, magnesium is produced in large, aging stars by the sequential addition of three Helium nucleus, helium nuclei to a carbon nucleus. When such stars explo ...
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Titanium
Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in sea water, aqua regia, and chlorine. Titanium was discovered in Cornwall, Great Britain, by William Gregor in 1791 and was named by Martin Heinrich Klaproth after the Titans of Greek mythology. The element occurs within a number of minerals, principally rutile and ilmenite, which are widely distributed in the Earth's crust and lithosphere; it is found in almost all living things, as well as bodies of water, rocks, and soils. The metal is extracted from its principal mineral ores by the Kroll and Hunter processes. The most common compound, titanium dioxide (TiO2), is a popular photocatalyst and is used in the manufacture of white pigments. Other compounds include titanium tetrachloride (TiCl4), a component of smoke screens and cata ...
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Potassium Chlorate
Potassium chlorate is the inorganic compound with the molecular formula KClO3. In its pure form, it is a white solid. After sodium chlorate, it is the second most common chlorate in industrial use. It is a strong oxidizing agent and its most important application is in safety matches. In other applications it is mostly obsolete and has been replaced by safer alternatives in recent decades. It has been used * in fireworks, propellants and explosives, * to prepare oxygen, both in the lab and in chemical oxygen generators, * as a disinfectant, for example in dentifrices and medical mouthwashes, * in agriculture as an herbicide. Production On the industrial scale, potassium chlorate is produced by the salt metathesis reaction of sodium chlorate and potassium chloride: : The reaction is driven by the low solubility of potassium chlorate in water. The equilibrium of the reaction is shifted to the right hand side by the continuous precipitation of the product (Le Chatelier's Principle). T ...
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