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Purging (gas)
In fire and explosion prevention engineering, purging refers to the introduction of an inert (i.e. non-combustible) purge gas into a closed system (e.g. a container or a process vessel) to prevent the formation of an ignitable atmosphere. Purging relies on the principle that a combustible (or flammable) gas is able to undergo combustion (explode) only if mixed with air in the right proportions. The flammability limits of the gas define those proportions, i.e. the ignitable range. Purge into service Assume a closed system (e.g. a container or process vessel), initially containing air, which shall be prepared for safe introduction of a flammable gas, for instance as part of a start-up procedure. The system can be flushed with an inert gas to reduce the concentration of oxygen so that when the flammable gas is admitted, an ignitable mixture cannot form. In NFPA 56,NFPA 56. Standard for Fire and Explosion Prevention During Cleaning and Purging of Flammable Gas Piping Systems. Nat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inert Gas
An inert gas is a gas that does not readily undergo chemical reactions with other chemical substances and therefore does not readily form chemical compounds. Though inert gases have a variety of applications, they are generally used to prevent unwanted chemical reactions with the oxygen (oxidation) and moisture (hydrolysis) in the air from degrading a sample. Generally, all noble gases except oganesson (helium, neon, argon, krypton, xenon, and radon), nitrogen, and carbon dioxide are considered inert gases. The term ''inert gas'' is context-dependent because several of the inert gases, including nitrogen and carbon dioxide, can be made to react under certain conditions. Purified argon gas is the most commonly used inert gas due to its high natural abundance (78.3% N2, 1% Ar in air) and low relative cost. Unlike noble gases, an inert gas is not necessarily elemental and is often a compound gas. Like the noble gases, the tendency for non-reactivity is due to the valence, the ou ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flammability Limits
Flammability limits or explosive limits are the ranges of fuel concentrations in relation to oxygen from the air. Combustion can range in violence from deflagration through detonation. Limits vary with temperature and pressure, but are normally expressed in terms of volume percentage at 25 °C and atmospheric pressure. These limits are relevant both in producing and optimising explosion or combustion, as in an engine, or to preventing it, as in uncontrolled explosions of build-ups of combustible gas or dust. Attaining the best combustible or explosive mixture of a fuel and air (the stoichiometric proportion) is important in internal combustion engines such as gasoline or diesel engines. The standard reference work is still that elaborated by Michael George Zabetakis, a fire safety engineering specialist, using an apparatus developed by the United States Bureau of Mines. Violence of combustion Combustion can vary in degree of violence. A deflagration is a propagation of a c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Limiting Oxygen Concentration
The limiting oxygen concentration (LOC), also known as the minimum oxygen concentration (MOC), is defined as the limiting concentration of oxygen below which combustion is not possible, independent of the concentration of fuel. It is expressed in units of volume percent of oxygen. The LOC varies with pressure and temperature. It is also dependent on the type of inert (non-flammable) gas. Limiting oxygen concentration for solid materials The effect of increasing the concentration of inert gas can be understood by viewing the inert as thermal ballast that quenches the flame temperature to a level below which the flame cannot exist. Carbon dioxide is therefore more effective than nitrogen due to its higher molar heat capacity.Drysdale:92 The concept has important practical use in fire safety engineering. For instance, to safely fill a new container or a pressure vessel with flammable gases, the atmosphere of normal air (containing 20.9 volume percent of oxygen) in the vesse ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inherent Safety
In the chemical and process industries, a process has inherent safety if it has a low level of danger even if things go wrong. Inherent safety contrasts with other processes where a high degree of hazard is controlled by protective systems. As perfect safety cannot be achieved, common practice is to talk about ''inherently safer design''. “An inherently safer design is one that avoids hazards instead of controlling them, particularly by reducing the amount of hazardous material and the number of hazardous operations in the plant.” Origins The concept of reducing rather than controlling hazards stems from British chemical engineer Trevor Kletz in 1978 paper "What You Don’t Have, Can’t Leak" on lessons from the Flixborough disaster,Kletz, Trevor (1978). “What You Don’t Have, Can’t Leak”. ''Chemistry and Industry'' pp. 287–292. and the expression "inherent safety" from a book that was an expanded version of the article.Kletz, T. A. (1984). ''Cheaper, Safer Plants ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitrogen
Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. It is a common element in the universe, estimated at Abundance of the chemical elements, seventh in total abundance in the Milky Way and the Solar System. At standard temperature and pressure, two atoms of the element chemical bond, bond to form N2, a colourless and odourless diatomic molecule, diatomic gas. N2 forms about 78% of Atmosphere of Earth, Earth's atmosphere, making it the most abundant chemical species in air. Because of the volatility of nitrogen compounds, nitrogen is relatively rare in the solid parts of the Earth. It was first discovered and isolated by Scottish physician Daniel Rutherford in 1772 and independently by Carl Wilhelm Scheele and Henry Cavendish at about the same time. The name was suggested by French chemist ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbon Dioxide
Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at normally-encountered concentrations it is odorless. As the source of carbon in the carbon cycle, atmospheric is the primary carbon source for life on Earth. In the air, carbon dioxide is transparent to visible light but absorbs infrared, infrared radiation, acting as a greenhouse gas. Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, and seawater. It is a trace gas Carbon dioxide in Earth's atmosphere, in Earth's atmosphere at 421 parts per million (ppm), or about 0.042% (as of May 2022) having risen from pre-industrial levels of 280 ppm or about 0.028%. Burning fossil fuels is the main cause of these increased concentrations, which are the primary cause of climate change.IPCC (2022Summary for pol ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Argon
Argon is a chemical element; it has symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abundant as water vapor (which averages about 4000 ppmv, but varies greatly), 23 times as abundant as carbon dioxide (400 ppmv), and more than 500 times as abundant as neon (18 ppmv). Argon is the most abundant noble gas in Earth's crust, comprising 0.00015% of the crust. Nearly all argon in Earth's atmosphere is radiogenic argon-40, derived from the decay of potassium-40 in Earth's crust. In the universe, argon-36 is by far the most common argon isotope, as it is the most easily produced by stellar nucleosynthesis in supernovas. The name "argon" is derived from the Greek word , neuter singular form of meaning 'lazy' or 'inactive', as a reference to the fact that the element undergoes almost no chemical reactions. The complete oc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Helium
Helium (from ) is a chemical element; it has chemical symbol, symbol He and atomic number 2. It is a colorless, odorless, non-toxic, inert gas, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling point is the lowest among all the Chemical element, elements, and it does not have a melting point at standard pressures. It is the second-lightest and second-most Abundance of the chemical elements, abundant element in the observable universe, after hydrogen. It is present at about 24% of the total elemental mass, which is more than 12 times the mass of all the heavier elements combined. Its abundance is similar to this in both the Sun and Jupiter, because of the very high nuclear binding energy (per nucleon) of helium-4 with respect to the next three elements after helium. This helium-4 binding energy also accounts for why it is a product of both nuclear fusion and radioactive decay. The most common isotope of helium in the universe is helium-4, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inerting (gas)
In fire and explosion prevention engineering, inerting refers to the introduction of an inert gas, inert (non-combustible) gas into a closed system (e.g. a container or a process vessel) to make a flammable atmosphere oxygen deficient and non-ignitable.NFPA 69. Standard on Explosion Prevention Systems. National Fire Protection Association.NFPA 77. Recommended Practice on Static Electricity. National Fire Protection Association. Inerting relies on the principle that a combustible (or flammable) gas is able to undergo combustion (explode) only if mixed with air in the right proportions. The flammability limits of the gas define those proportions, i.e. the ignitable range. In combustion engineering terms, the admission of inert gas can be said to dilute the oxygen below the limiting oxygen concentration. Inerting differs from Purging (gas), purging. Purging, by definition, ensures that an ignitable mixture ''never forms''. Inerting makes an ignitable mixture safe by introduction o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
ATEX
The ATEX directives are two of the EU directives describing the minimum safety requirements for workplaces and equipment used in explosive atmospheres. The name is an initialization of the term ''ATmosphères EXplosives'' ( French for "explosive atmospheres"). Directives Organizations in the EU must follow Directives to protect employees from explosion risk in areas with an explosive atmosphere. There are two ATEX Directives (one for the manufacturer and one for the user of the equipment): * The ATEX 114 "equipment" Directive 2014/34/EU - Equipment and protective systems intended for use in potentially explosive atmospheres * The ATEX 153 "workplace" Directive 1999/92/EC - Minimum requirements for improving the safety and health protection of workers potentially at risk from explosive atmospheres. Note: The ATEX 95 "equipment" Directive 94/9/EC, was withdrawn on 20 April 2016 when it was replaced by ATEX 114 Directive 2014/34/EU. ATEX Directive 2014/34/EU is mandatory ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flammability Limits
Flammability limits or explosive limits are the ranges of fuel concentrations in relation to oxygen from the air. Combustion can range in violence from deflagration through detonation. Limits vary with temperature and pressure, but are normally expressed in terms of volume percentage at 25 °C and atmospheric pressure. These limits are relevant both in producing and optimising explosion or combustion, as in an engine, or to preventing it, as in uncontrolled explosions of build-ups of combustible gas or dust. Attaining the best combustible or explosive mixture of a fuel and air (the stoichiometric proportion) is important in internal combustion engines such as gasoline or diesel engines. The standard reference work is still that elaborated by Michael George Zabetakis, a fire safety engineering specialist, using an apparatus developed by the United States Bureau of Mines. Violence of combustion Combustion can vary in degree of violence. A deflagration is a propagation of a c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Limiting Oxygen Concentration
The limiting oxygen concentration (LOC), also known as the minimum oxygen concentration (MOC), is defined as the limiting concentration of oxygen below which combustion is not possible, independent of the concentration of fuel. It is expressed in units of volume percent of oxygen. The LOC varies with pressure and temperature. It is also dependent on the type of inert (non-flammable) gas. Limiting oxygen concentration for solid materials The effect of increasing the concentration of inert gas can be understood by viewing the inert as thermal ballast that quenches the flame temperature to a level below which the flame cannot exist. Carbon dioxide is therefore more effective than nitrogen due to its higher molar heat capacity.Drysdale:92 The concept has important practical use in fire safety engineering. For instance, to safely fill a new container or a pressure vessel with flammable gases, the atmosphere of normal air (containing 20.9 volume percent of oxygen) in the vesse ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
