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Polarisability
Polarizability usually refers to the tendency of matter, when subjected to an electric field, to acquire an electric dipole moment in proportion to that applied field. It is a property of particles with an electric charge. When subject to an electric field, the negatively charged electrons and positively charged atomic nuclei are subject to opposite forces and undergo charge separation. Polarizability is responsible for a material's dielectric constant and, at high (optical) frequencies, its refractive index. The polarizability of an atom or molecule is defined as the ratio of its induced dipole moment to the local electric field; in a crystalline solid, one considers the dipole moment per unit cell. Note that the local electric field seen by a molecule is generally different from the macroscopic electric field that would be measured externally. This discrepancy is taken into account by the Clausius–Mossotti relation (below) which connects the bulk behaviour ( polarization de ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electric Field
An electric field (sometimes called E-field) is a field (physics), physical field that surrounds electrically charged particles such as electrons. In classical electromagnetism, the electric field of a single charge (or group of charges) describes their capacity to exert attractive or repulsive forces on another charged object. Charged particles exert attractive forces on each other when the sign of their charges are opposite, one being positive while the other is negative, and repel each other when the signs of the charges are the same. Because these forces are exerted mutually, two charges must be present for the forces to take place. These forces are described by Coulomb's law, which says that the greater the magnitude of the charges, the greater the force, and the greater the distance between them, the weaker the force. Informally, the greater the charge of an object, the stronger its electric field. Similarly, an electric field is stronger nearer charged objects and weaker f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron Cloud
In quantum mechanics, an atomic orbital () is a function describing the location and wave-like behavior of an electron in an atom. This function describes an electron's charge distribution around the atom's nucleus, and can be used to calculate the probability of finding an electron in a specific region around the nucleus. Each orbital in an atom is characterized by a set of values of three quantum numbers , , and , which respectively correspond to electron's energy, its orbital angular momentum, and its orbital angular momentum projected along a chosen axis ( magnetic quantum number). The orbitals with a well-defined magnetic quantum number are generally complex-valued. Real-valued orbitals can be formed as linear combinations of and orbitals, and are often labeled using associated harmonic polynomials (e.g., ''xy'', ) which describe their angular structure. An orbital can be occupied by a maximum of two electrons, each with its own projection of spin m_s. The simp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Birefringence
Birefringence, also called double refraction, is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are described as birefringent or birefractive. The birefringence is often quantified as the maximum difference between refractive indices exhibited by the material. Crystals with non-cubic crystal structures are often birefringent, as are plastics under mechanical stress. Birefringence is responsible for the phenomenon of double refraction whereby a ray of light, when incident upon a birefringent material, is split by polarization into two rays taking slightly different paths. This effect was first described by Danish scientist Rasmus Bartholin in 1669, who observed it in Iceland spar (calcite) crystals which have one of the strongest birefringences. In the 19th century Augustin-Jean Fresnel described the phenomenon in terms of polarization, understanding ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Optical Rotation
Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity. Optical activity occurs only in chiral materials, those lacking microscopic mirror symmetry. Unlike other sources of birefringence which alter a beam's state of polarization, optical activity can be observed in fluids. This can include gases or solutions of chiral molecules such as sugars, molecules with helical secondary structure such as some proteins, and also chiral liquid crystals. It can also be observed in chiral solids such as certain crystals with a rotation between adjacent crystal planes (such as quartz) or metamaterials. When looking at the source of light, the rotation of the plane of polarization may be either to the right (dextrorotatory ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Scalar (physics)
Scalar quantities or simply scalars are physical quantities that can be described by a single pure number (a ''scalar'', typically a real number), accompanied by a unit of measurement, as in "10cm" (ten centimeters). Examples of scalar are length, mass, charge, volume, and time. Scalars may represent the magnitude of physical quantities, such as speed is to velocity. Scalars do not represent a direction. Scalars are unaffected by changes to a vector space basis (i.e., a coordinate rotation) but may be affected by translations (as in relative speed). A change of a vector space basis changes the description of a vector in terms of the basis used but does not change the vector itself, while a scalar has nothing to do with this change. In classical physics, like Newtonian mechanics, rotations and reflections preserve scalars, while in relativity, Lorentz transformations or space-time translations preserve scalars. The term "scalar" has origin in the multiplication o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molar Mass
In chemistry, the molar mass () (sometimes called molecular weight or formula weight, but see related quantities for usage) of a chemical substance ( element or compound) is defined as the ratio between the mass () and the amount of substance (, measured in moles) of any sample of the substance: . The molar mass is a bulk, not molecular, property of a substance. The molar mass is a ''weighted'' ''average'' of many instances of the element or compound, which often vary in mass due to the presence of isotopes. Most commonly, the molar mass is computed from the standard atomic weights and is thus a terrestrial average and a function of the relative abundance of the isotopes of the constituent atoms on Earth. The molecular mass (for molecular compounds) and formula mass (for non-molecular compounds, such as ionic salts) are commonly used as synonyms of molar mass, as the numerical values are identical (for all practical purposes), differing only in units ( dalton vs. g/mol o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Avogadro Constant
The Avogadro constant, commonly denoted or , is an SI defining constant with an exact value of when expressed in reciprocal moles. It defines the ratio of the number of constituent particles to the amount of substance in a sample, where the particles in question are any designated elementary entity, such as molecules, atoms, ions, ion pairs. The numerical value of this constant is known as the Avogadro number, commonly denoted . The Avogadro ''number'' is an exact number equal to the number of constituent particles in one mole of any substance (by definition of the mole), historically derived from the experimental determination of the number of atoms in 12 grams of carbon-12 (12C) before the 2019 revision of the SI. Both the constant and the number are named after the Italian physicist and chemist Amedeo Avogadro. The Avogadro constant is used as a proportionality factor in relating the ''amount of substance'' , in a sample of a substance , to the corresponding n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molar Refractivity
Molar refractivity, R_m, is a measure of the total polarizability of a mole of a substance. For a perfect dielectric which is made of one type of molecule, the molar refractivity is proportional to the polarizability of a single molecule of the substance. For real materials, intermolecular interactions (the effect of the induced dipole moment of one molecule on the field felt by nearby molecules) give rise to a density dependence. The molar refractivity is commonly expressed as a sum of components, where the leading order is the value for a perfect dielectric, followed by the density-dependent corrections: : R_m = A + B\cdot\rho + C\cdot\rho^2 + ... The coefficients A, B, C, ... are called the refractivity virial coefficients. Some research papers are dedicated to finding the values of the subleading coefficients of different substances. In other contexts, the material can be assumed to be approximately perfect, so that the only coefficient of interest is A . The coefficien ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxford University Press
Oxford University Press (OUP) is the publishing house of the University of Oxford. It is the largest university press in the world. Its first book was printed in Oxford in 1478, with the Press officially granted the legal right to print books by decree in 1586. It is the second-oldest university press after Cambridge University Press, which was founded in 1534. It is a department of the University of Oxford. It is governed by a group of 15 academics, the Delegates of the Press, appointed by the Vice Chancellor, vice-chancellor of the University of Oxford. The Delegates of the Press are led by the Secretary to the Delegates, who serves as OUP's chief executive and as its major representative on other university bodies. Oxford University Press has had a similar governance structure since the 17th century. The press is located on Walton Street, Oxford, Walton Street, Oxford, opposite Somerville College, Oxford, Somerville College, in the inner suburb of Jericho, Oxford, Jericho. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Permittivity
In electromagnetism, the absolute permittivity, often simply called permittivity and denoted by the Greek letter (epsilon), is a measure of the electric polarizability of a dielectric material. A material with high permittivity polarizes more in response to an applied electric field than a material with low permittivity, thereby storing more energy in the material. In electrostatics, the permittivity plays an important role in determining the capacitance of a capacitor. In the simplest case, the electric displacement field resulting from an applied electric field E is \mathbf = \varepsilon\ \mathbf ~. More generally, the permittivity is a thermodynamic State function, function of state. It can depend on the Dispersion (optics), frequency, Nonlinear optics, magnitude, and Anisotropy, direction of the applied field. The International System of Units, SI unit for permittivity is farad per meter (F/m). The permittivity is often represented by the relative permittivity which is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Angstrom
The angstrom (; ) is a unit of length equal to m; that is, one ten-billionth of a metre, a hundred-millionth of a centimetre, 0.1 nanometre, or 100 picometres. The unit is named after the Swedish physicist Anders Jonas Ångström (1814–1874). It was originally spelled with Swedish letters, as Ångström and later as ångström (). The latter spelling is still listed in some dictionaries, but is now rare in English texts. Some popular US dictionaries list only the spelling ''angstrom''. The unit's symbol is Å, which is a letter of the Swedish alphabet, regardless of how the unit is spelled. However, "A" or "A.U." may be used in less formal contexts or typographically limited media. The angstrom is often used in the natural sciences and technology to express sizes of atoms, molecules, microscopic biological structures, and lengths of chemical bonds, arrangement of atoms in crystals, wavelengths of electromagnetic radiation, and dimensions of integrated circuit part ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
International System Of Units
The International System of Units, internationally known by the abbreviation SI (from French ), is the modern form of the metric system and the world's most widely used system of measurement. It is the only system of measurement with official status in nearly every country in the world, employed in science, technology, industry, and everyday commerce. The SI system is coordinated by the International Bureau of Weights and Measures, which is abbreviated BIPM from . The SI comprises a coherent system of units of measurement starting with seven base units, which are the second (symbol s, the unit of time), metre (m, length), kilogram (kg, mass), ampere (A, electric current), kelvin (K, thermodynamic temperature), mole (mol, amount of substance), and candela (cd, luminous intensity). The system can accommodate coherent units for an unlimited number of additional quantities. These are called coherent derived units, which can always be represented as products of powers of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
