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Picric Acid
Picric acid is an organic compound with the formula (O2N)3C6H2OH. Its IUPAC name is 2,4,6-trinitrophenol (TNP). The name "picric" comes from (''pikros''), meaning "bitter", due to its bitter taste. It is one of the most acidic phenols. Like other strongly nitrated organic compounds, picric acid is an explosive, which is its primary use. It has also been used as medicine (antiseptic, burn treatments) and as a dye. History Picric acid was probably first mentioned in the 17th-century alchemical writings of Johann Rudolf Glauber. Initially, it was made by nitrating substances such as animal horn, silk, indigo, and natural resin, the synthesis from indigo first being performed by Peter Woulfe in 1771. The German chemist Justus von Liebig had named picric acid (rendered in French as ). Picric acid was given that name by the French chemist Jean-Baptiste Dumas in 1841. Its synthesis from phenol, and the correct determination of its formula, were accomplished during 1841. In 1799 ...
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Royal Society Of Chemistry
The Royal Society of Chemistry (RSC) is a learned society and professional association in the United Kingdom with the goal of "advancing the chemistry, chemical sciences". It was formed in 1980 from the amalgamation of the Chemical Society, the Royal Institute of Chemistry, the Faraday Society, and the Society for Analytical Chemistry with a new Royal Charter and the dual role of learned society and professional body. At its inception, the Society had a combined membership of 49,000 in the world. The headquarters of the Society are at Burlington House, Piccadilly, London. It also has offices in Thomas Graham House in Cambridge (named after Thomas Graham (chemist), Thomas Graham, the first president of the Chemical Society) where ''RSC Publishing'' is based. The Society has offices in the United States, on the campuses of The University of Pennsylvania and Drexel University, at the University City Science Center in Philadelphia, Pennsylvania, in both Beijing and Shanghai, People' ...
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Phenol
Phenol (also known as carbolic acid, phenolic acid, or benzenol) is an aromatic organic compound with the molecular formula . It is a white crystalline solid that is volatile and can catch fire. The molecule consists of a phenyl group () bonded to a hydroxy group (). Mildly acidic, it requires careful handling because it can cause chemical burns. It is acutely toxic and is considered a health hazard. Phenol was first extracted from coal tar, but today is produced on a large scale (about 7 million tonnes a year) from petroleum-derived feedstocks. It is an important industrial commodity as a precursor to many materials and useful compounds, and is a liquid when manufactured. It is primarily used to synthesize plastics and related materials. Phenol and its chemical derivatives are essential for production of polycarbonates, epoxies, explosives such as picric acid, Bakelite, nylon, detergents, herbicides such as phenoxy herbicides, and numerous pharmaceuti ...
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Rock Blasting
Drilling and blasting is the controlled use of explosives and other methods, such as gas pressure blasting pyrotechnics, to break rock for excavation. It is practiced most often in mining, quarrying and civil engineering such as dam, tunnel or road construction. The result of rock blasting is often known as a rock cut. Drilling and blasting currently utilizes many different varieties of explosives with different compositions and performance properties. Higher velocity explosives are used for relatively hard rock in order to shatter and break the rock, while low velocity explosives are used in soft rocks to generate more gas pressure and a greater heaving effect. For instance, an early 20th-century blasting manual compared the effects of black powder to that of a wedge, and dynamite to that of a hammer. The most commonly used explosives in mining today are ANFO based blends due to lower cost than dynamite. Before the advent of tunnel boring machines (TBMs), drilling and b ...
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Eugène Turpin
François Eugène Turpin (30 September 1848 – 24 January 1927) was a French chemist involved in research of explosive materials. He lived in Colombes. Biography In 1881, Turpin proposed panclastites, a class of Sprengel explosives based on a mixture of a suitable fuel with dinitrogen tetroxide as an oxidizer. In 1885, based on research of Hermann Sprengel, Turpin patented the use of pressed and cast picric acid in blasting charges and artillery shells. In 1887, the French government adopted it under the name Melinite, with addition of gun cotton. Since 1888, Britain started manufacturing a very similar mixture in Lydd, Kent, under the name Lyddite. Japan followed with an improved formula known as Schimose. In 1889, a Captain Tripone stole his secret and sold it to Germany. Turpin was falsely accused of the treason and imprisoned. He was pardoned in 1893 after a campaign led by Le Petit Journal, and exonerated in 1901. In 1897, Turpin sued Jules Verne for basing Thomas ...
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Detonation
Detonation () is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations propagate supersonically through shock waves with speeds about 1 km/sec and differ from deflagrations which have subsonic flame speeds about 1 m/sec. Detonation may form from an explosion of fuel-oxidizer mixture. Compared with deflagration, detonation doesn't need to have an external oxidizer. Oxidizers and fuel mix when deflagration occurs. Detonation is more destructive than deflagrations. In detonation, the flame front travels through the air-fuel faster than sound; while in deflagration, the flame front travels through the air-fuel slower than sound. Detonations occur in both conventional solid and liquid explosives, as well as in reactive gases. TNT, dynamite, and C4 are examples of high power explosives that detonate. The detonation velocity, velocity of detonation in solid an ...
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Nitrocellulose
Nitrocellulose (also known as cellulose nitrate, flash paper, flash cotton, guncotton, pyroxylin and flash string, depending on form) is a highly flammable compound formed by nitrating cellulose through exposure to a mixture of nitric acid and sulfuric acid. One of its first major uses was as guncotton, a replacement for gunpowder as propellant in firearms. It was also used to replace gunpowder as a low-order explosive in mining and other applications. In the form of collodion, it was also a critical component in an early photographic emulsion, the use of which revolutionized photography in the 1860s. In the 20th century, it was adapted to automobile lacquer and adhesives. Production The process uses a mixture of nitric acid and sulfuric acid to convert cellulose into nitrocellulose. The quality of the cellulose is important. Hemicellulose, lignin, pentosans, and mineral salts give inferior nitrocelluloses. In organic chemistry, nitrocellulose is a nitrate ester, not a ...
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Nitroglycerine
Nitroglycerin (NG) (alternative spelling nitroglycerine), also known as trinitroglycerol (TNG), nitro, glyceryl trinitrate (GTN), or 1,2,3-trinitroxypropane, is a dense, colorless or pale yellow, oily, explosive liquid most commonly produced by nitrating glycerol with white fuming nitric acid under conditions appropriate to the formation of the nitric acid ester. Chemically, the substance is a nitrate ester rather than a nitro compound, but the traditional name is retained. Discovered in 1846 by Ascanio Sobrero, nitroglycerin has been used as an active ingredient in the manufacture of explosives, namely dynamite, and as such it is employed in the construction, demolition, and mining industries. It is combined with nitrocellulose to form double-based smokeless powder, used as a propellant in artillery and firearms since the 1880s. As is the case for many other explosives, nitroglycerin becomes more and more prone to exploding (i.e. spontaneous decomposition) as the temperature ...
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Artillery
Artillery consists of ranged weapons that launch Ammunition, munitions far beyond the range and power of infantry firearms. Early artillery development focused on the ability to breach defensive walls and fortifications during sieges, and led to heavy, fairly immobile siege engines. As technology improved, lighter, more mobile field artillery cannons were developed for battlefield use. This development continues today; modern self-propelled artillery vehicles are highly mobile weapons of great versatility generally providing the largest share of an army's total firepower. Originally, the word "artillery" referred to any group of soldiers primarily armed with some form of manufactured weapon or armour. Since the introduction of gunpowder and cannon, "artillery" has largely meant cannon, and in contemporary usage, usually refers to Shell (projectile), shell-firing Field gun, guns, howitzers, and Mortar (weapon), mortars (collectively called ''barrel artillery'', ''cannon artil ...
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High Explosive
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances. The potential energy stored in an explosive material may, for example, be: * chemical energy, such as nitroglycerin or Dust explosion, grain dust * pressure, pressurized gas compressor, gas, such as a gas cylinder, aerosol can, or boiling liquid expanding vapor explosion * nuclear weapon, nuclear energy, such as in the fissile isotopes uranium-235 and plutonium-239 Explosive materials may be categorized by the speed at which they expand. Materials that detonate (the front of the chemical reaction moves faster through the material than the speed of sound) are said to be "high ...
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Military
A military, also known collectively as armed forces, is a heavily armed, highly organized force primarily intended for warfare. Militaries are typically authorized and maintained by a sovereign state, with their members identifiable by a distinct military uniform. They may consist of one or more military branches such as an army, navy, air force, space force, marines, or coast guard. The main task of a military is usually defined as defence of their state and its interests against external armed threats. In broad usage, the terms "armed forces" and "military" are often synonymous, although in technical usage a distinction is sometimes made in which a country's armed forces may include other paramilitary forces such as armed police. Beyond warfare, the military may be employed in additional sanctioned and non-sanctioned functions within the state, including internal security threats, crowd control, promotion of political agendas, emergency services and reconstruct ...
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Hermann Sprengel
Hermann Sprengel FRS (29 August 1834 – 14 January 1906) was a German-British chemist who discovered the explosive nature of picric acid in 1873, patented safety explosives and invented the mercurial air pump. Life He was born at Schillerslage, near Hanover, on 29 August 1834. Sprengel was the son of George Sprengel. He was educated in Göttingen and earned his degree at the university at Heidelberg in 1858. He moved to England the following year and became a naturalised British subject. He was first employed as an assistant in chemical laboratory in Oxford and then moved to London to work at Guy's and St Bartholomew's Hospitals, before working in the chemical works of Thomas Farmer of Kennington (1865-1870). There he invented a generic class of materials called Sprengel explosives. In addition he invented a very robust and continuously operable device called the Sprengel Pump which could reduce the amount of air in a chamber to one-millionth of its volume paving the way ...
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Michel Eugène Chevreul
Michel Eugène Chevreul (; 31 August 1786 – 9 April 1889) was a French chemist whose work contributed to significant developments in science, medicine, and art. Chevreul's early work with animal fats revolutionized soap and candle manufacturing and led to his isolation of the Heptadecanoic acid, heptadecanoic (margaric), stearic, and oleic acid, oleic fatty acids. In the process, Chevreul became the first scientist to define the concept of a chemical compound and the first to formally characterize the nature of organic compounds; he is consequently considered a founder of modern organic chemistry. In the medical field, Chevreul was first to demonstrate that diabetes, diabetics excrete glucose in the urine and to isolate creatine. Chevreul's study of textile dyes while director of the Gobelins Manufactory in Paris led to color theory, color theories that "provided the scientific basis for Impressionist and Neo-Impressionist painting." Chevreul is one of the List of the 72 name ...
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