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Photoexcitation
Photoexcitation in crystal Photoexcitation is the production of an excited state of a quantum system by photon absorption. The excited state originates from the interaction between a photon and the quantum system. Photons carry energy that is determined by the wavelengths of the light that carries the photons. Objects that emit light with longer wavelengths, emit photons carrying less energy. In contrast to that, light with shorter wavelengths emit photons with more energy. When the photon interacts with a quantum system, it is therefore important to know what wavelength one is dealing with. A shorter wavelength will transfer more energy to the quantum system than longer wavelengths. On the atomic and molecular scale photoexcitation is the photoelectrochemical process of electron excitation by photon absorption, when the energy of the photon is too low to cause photoionization. The absorption of the photon takes place in accordance with Planck's quantum theory. Photoexcitati ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photoelectrochemical Process
Photoelectrochemical processes are processes in photoelectrochemistry; they usually involve transforming light into other forms of energy. These processes apply to photochemistry, optically pumped lasers, sensitized solar cells, luminescence, and photochromism. Electron excitation Electron excitation is the movement of an electron to a higher energy state. This can either be done by photoexcitation (PE), where the original electron absorbs the photon and gains all the photon's energy or by electrical excitation (EE), where the original electron absorbs the energy of another, energetic electron. Within a semiconductor crystal lattice, thermal excitation is a process where lattice vibrations provide enough energy to move electrons to a higher energy band. When an excited electron falls back to a lower energy state again, it is called electron relaxation. This can be done by radiation of a photon or giving the energy to a third spectator particle as well. In physics there is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dye-sensitized Solar Cell
A dye-sensitized solar cell (DSSC, DSC, DYSC or Grätzel cell) is a low-cost solar cell belonging to the group of thin film solar cells. It is based on a semiconductor formed between a photo-sensitized anode and an electrolyte, a '' photoelectrochemical'' system. The modern version of a dye solar cell, also known as the Grätzel cell, was originally co-invented in 1988 by Brian O'Regan and Michael Grätzel at UC Berkeley and this work was later developed by the aforementioned scientists at the École Polytechnique Fédérale de Lausanne (EPFL) until the publication of the first high efficiency DSSC in 1991. Michael Grätzel has been awarded the 2010 Millennium Technology Prize for this invention. The DSSC has a number of attractive features; it is simple to make using conventional roll-printing techniques, is semi-flexible and semi-transparent which offers a variety of uses not applicable to glass-based systems, and most of the materials used are low-cost. In practice it has ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron Excitation
Electron excitation is the transfer of a bound electron to a more energetic, but still bound state. This can be done by photoexcitation (PE), where the electron absorbs a photon and gains all its energy. Or it is achieved through collisional excitation (CE), where the electron receives energy from a collision with another, energetic electron. Within a semiconductor crystal lattice, thermal excitation is a process where lattice vibrations provide enough energy to transfer electrons to a higher energy band such as a more energetic sublevel or energy level. When an excited electron falls back to a state of lower energy, it undergoes electron relaxation (deexcitation). This is accompanied by the emission of a photon (radiative relaxation/spontaneous emission) or by a transfer of energy to another particle. The energy released is equal to the difference in energy levels between the electron energy states. Excited states in nuclear, atomic, and molecule systems have distinct energ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Laser Pumping
Laser pumping is the act of energy transfer from an external source into the gain medium of a laser. The energy is absorbed in the medium, producing excited states in its atoms. When for a period of time the number of particles in one excited state exceeds the number of particles in the ground state or a less-excited state, population inversion is achieved. In this condition, the mechanism of stimulated emission can take place and the medium can act as a laser or an optical amplifier. The pump power must be higher than the lasing threshold of the laser. The pump energy is usually provided in the form of light or electric current, but more exotic sources have been used, such as Chemical reaction, chemical or nuclear reactions. Optical pumping Pumping cavities A laser pumped with an arc lamp or a flashlamp is usually pumped through the lateral wall of the lasing medium, which is often in the form of a crystal rod containing a metallic impurity or a glass tube containing a liquid d ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Delta Baryon
The Delta baryons (or baryons, also called Delta resonances) are a family of subatomic particle made of three up or down quarks (u or d quarks), the same constituent quarks that make up the more familiar protons and neutrons. Properties Four closely related baryons exist: (constituent quarks: uuu), (uud), (udd), and (ddd), which respectively carry an electric charge of , , , and . The baryons have a mass of about ; their third component of isospin \; I_3 = \pm\tfrac ~\mathsf~ \pm\tfrac\;; and they are required to have an intrinsic spin of or higher (half-integer units). Ordinary nucleons (symbol N, meaning either a proton or neutron), by contrast, have a mass of about , and both intrinsic spin and isospin of . The (uud) and (udd) particles are higher-mass spin-excitations of the proton (, uud) and neutron (, udd), respectively. The and , however, have no direct nucleon analogues: For example, even though their charges ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nucleon
In physics and chemistry, a nucleon is either a proton or a neutron, considered in its role as a component of an atomic nucleus. The number of nucleons in a nucleus defines the atom's mass number. Until the 1960s, nucleons were thought to be elementary particles, not made up of smaller parts. Now they are understood as composite particles, made of three quarks bound together by the strong interaction. The interaction between two or more nucleons is called internucleon interaction or nuclear force, which is also ultimately caused by the strong interaction. (Before the discovery of quarks, the term "strong interaction" referred to just internucleon interactions.) Nucleons sit at the boundary where particle physics and nuclear physics overlap. Particle physics, particularly quantum chromodynamics, provides the fundamental equations that describe the properties of quarks and of the strong interaction. These equations describe quantitatively how quarks can bind together into protons ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photochromic
Photochromism is the reversible change of color upon exposure to light. It is a transformation of a chemical species (photoswitch) between two forms through the absorption of electromagnetic radiation (photoisomerization), where each form has a different absorption spectrum. This reversible structural or geometric change in photochromic molecules affects their electronic configuration, molecular strain energy, and other properties. History In 1867, Carl Julius Fritzsche reported the concept of photochromism, indicating that orange tetracene solution lost its color in daylight but regained it in darkness. Later, similar behavior was observed by both Edmund ter Meer and Phipson. Ter Meer documented the color change of the potassium salt of dinitroethane, which appeared red in daylight and yellow in the dark. Phipson also recorded that a painted gatepost appeared black during the day and white at night due to a zinc pigment, likely lithopone. In 1899, Willy Marckwald, Willy Markwald, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Germanium
Germanium is a chemical element; it has Symbol (chemistry), symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid or a nonmetal in the carbon group that is chemically similar to silicon. Like silicon, germanium naturally Chemical reaction, reacts and forms complexes with oxygen in nature. Because it seldom appears in high concentration, germanium was found comparatively late in the Timeline of chemical element discoveries, discovery of the elements. Germanium ranks 50th Abundance of elements in Earth's crust, in abundance of the elements in the Earth's crust. In 1869, Dmitri Mendeleev Mendeleev's predicted elements, predicted its existence and some of its Chemical property, properties from its position on his periodic table, and called the element ekasilicon. On February 6, 1886, Clemens Winkler at Freiberg University found the new element, along with silver and sulfur, in the mineral argyrodite. Winkle ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Population Inversion
In physics, specifically statistical mechanics, a population inversion occurs when a system (such as a group of atoms or molecules) exists in a state in which more members of the system are in higher, excited states than in lower, unexcited energy states. It is called an "inversion" because in many familiar and commonly encountered physical systems in thermal equilibrium, this is not possible. This concept is of fundamental importance in laser science because the production of a population inversion is a necessary step in the workings of a standard laser. Boltzmann distributions and thermal equilibrium To understand the concept of a population inversion, it is necessary to understand some thermodynamics and the way that light interacts with matter. To do so, it is useful to consider a very simple assembly of atoms forming a laser medium. Assume there is a group of ''N'' atoms, each of which is capable of being in one of two energy states: either # The ''ground state'', with ene ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photochemistry
Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet (wavelength from 100 to 400 Nanometre, nm), visible light, visible (400–750 nm), or infrared radiation (750–2500 nm). In nature, photochemistry is of immense importance as it is the basis of photosynthesis, vision, and the formation of vitamin D with sunlight. It is also responsible for the appearance of DNA mutations leading to skin cancers. Photochemical reactions proceed differently than temperature-driven reactions. Photochemical paths access high-energy intermediates that cannot be generated thermally, thereby overcoming large Activation energy, activation barriers in a short period of time, and allowing reactions otherwise inaccessible by thermal processes. Photochemistry can also be destructive, as illustrated by the photodegradation of plastics. Concept Grotthuss–Dra ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
