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Molluscicides
Molluscicides () are chemicals that kill molluscs. They are also known as snail baits, snail pellets, or slug pellets. These pesticides against molluscs are usually used in agriculture or gardening, in order to control gastropod pests specifically slugs and snails which damage crops or other valued plants by feeding on them. A number of chemicals can be employed as a molluscicide: * Quicklime slaked lime, and kainite, respectively kill by dehydration. Hundreds of kilograms per hectare are required. * Metal salts such as iron(III) phosphate, aluminium sulfate, and ferric sodium EDTA, relatively non-toxic, most are approved for use in organic gardening * Metaldehyde * Niclosamide * Acetylcholinesterase inhibitors (e.g. methiocarb), highly toxic to other animals and humans with a quick onset of toxic symptoms. Many chemicals have been developed as molluscicides. Slug pellets contain a carbohydrate source (e.g. durum flour) as a bulking agent. See also * Pesticide poisoning ...
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Pest (organism)
A pest is any organism harmful to humans or human concerns. The term is particularly used for creatures that damage crops, livestock, and forestry or cause a nuisance to people, especially in their homes. Humans have modified the environment for their own purposes and are intolerant of other creatures occupying the same space when their activities impact adversely on human objectives. Thus, an elephant is unobjectionable in its natural habitat but a pest when it tramples crops. Some animals are disliked because they bite or sting; wolves, snakes, wasps, ants, bed bugs, fleas and ticks belong in this category. Others enter the home; these include houseflies, which land on and contaminate food; beetles, which tunnel into the woodwork; and other animals that scuttle about on the floor at night, like rats and cockroaches, which are often associated with unsanitary conditions. Agricultural and horticultural crops are attacked by a wide variety of pests, the most important being ...
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Metaldehyde
Metaldehyde is an organic compound with the chemical formula, formula (). It is used as a pesticide against slugs and snails. It is the cyclic tetramer of acetaldehyde. Production and properties Metaldehyde is flammable, toxic if ingested in large quantities, and irritating to the skin and eyes. It has a white crystalline appearance with a menthol odor. Metaldehyde is obtained in moderate yields by treatment of acetaldehyde with chilled mineral acids. The liquid trimer, paraldehyde is also obtained. The reaction is reversible; upon heating to about 80 °C, metaldehyde and paraldehyde revert to acetaldehyde. Metaldehyde exists as a mixture of four stereoisomers, molecules that differ with respect to the relative orientation of the methyl groups on the 8-membered ring. The stereoisomers have respectively the molecular symmetries C (with symmetry of order 2), C (order 4), D (order 8), and C (order 8). All have at least one plane of reflexion, so none of them is chiral. Use ...
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Ferric Sodium EDTA
Ferric sodium EDTA, also known as sodium ferric ethylenediaminetetraacetate, is a broad spectrum molluscicide used to kill snails and slugs and protect agricultural crops and garden plants, and in particular to eliminate infestations of ''Cornu aspersum'', the common garden snail. Chemically, it is a salt of ethylenediaminetetraacetic acid (EDTA). Mechanism of action and environmental impacts Ferric sodium EDTA works by interacting with and destroying hemocyanin, a copper based compound found in the blood of molluscs and arthropods which is used to carry oxygen, similar to hemoglobin found in vertebrates, and typically kills snails and slugs in a matter of days following exposure. The compound is much safer than Metaldehyde Metaldehyde is an organic compound with the chemical formula, formula (). It is used as a pesticide against slugs and snails. It is the cyclic tetramer of acetaldehyde. Production and properties Metaldehyde is flammable, toxic if ingested in large ... and ...
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Aluminium Sulfate
Aluminium sulfate is a salt with the chemical formula, formula . It is soluble in water and is mainly used as a Coagulation (water treatment), coagulating agent (promoting particle collision by neutralizing charge) in the purification of drinking water and wastewater treatment plants, and also in paper manufacturing. The anhydrous form occurs naturally as a rare mineral millosevichite, found for example in volcanic environments and on burning coal-mining waste dumps. Aluminium sulfate is rarely, if ever, encountered as the anhydrous salt. It forms a number of different hydrates, of which the hexadecahydrate and octadecahydrate are the most common. The heptadecahydrate, whose formula can be written as , occurs naturally as the mineral alunogen. Aluminium sulfate is sometimes called alum or papermaker's alum in certain industries. However, the name "alum" is more commonly and properly used for any double sulfate salt with the generic formula , where ''X'' is a valence (chemistry) ...
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Lexico
''Lexico'' was a dictionary website that provided a collection of English and Spanish dictionaries produced by Oxford University Press (OUP), the publishing house of the University of Oxford. While the dictionary content on ''Lexico'' came from OUP, this website was operated by Dictionary.com, whose eponymous website hosts dictionaries by other publishers such as Random House. The website was closed and redirected to Dictionary.com on 26 August 2022. Before the Lexico site was launched, the ''Oxford Dictionary of English'' and ''New Oxford American Dictionary'' were hosted by OUP's own website ''Oxford Dictionaries Online'' (''ODO''), later known as ''Oxford Living Dictionaries''. The dictionaries' definitions have also appeared in Google Dictionary, Google definition search and the Dictionary (software), Dictionary application on macOS, among others, licensed through the Oxford Dictionaries API. History In the 2000s, OUP allowed access to content of the ''Compact Oxford Englis ...
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Iron(III) Phosphate
Iron(III) phosphate or ferric phosphate is an inorganic compound with the formula Fe PO4. Four polymorphs of anhydrous FePO4 are known. Additionally, two polymorphs of the dihydrate FePO4·(H2O)2 are known. These polymorphs have attracted interest as potential cathode materials in batteries. Structure The most common form of FePO4 adopts the structure of α-quartz. As such the material consists of tetrahedral Fe(III) and phosphate sites. As such the P and Fe have tetrahedral molecular geometry. At high pressures, a phase change occurs to a more dense structure with octahedral Fe centres. Two orthorhombic structures and a monoclinic phase are also known. In the two polymorphs of the dihydrate, the Fe centre is octahedral with two mutually cis water ligands. Uses Iron(III) phosphate can be used in steel and metal manufacturing processes. When bonded to a metal surface, iron phosphate prevents further oxidation of the metal. Its presence is partially responsible for th ...
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Pest Control
Pest control is the regulation or management of a species defined as a pest (organism), pest; such as any animal, plant or fungus that impacts adversely on human activities or environment. The human response depends on the importance of the damage done and will range from tolerance, through deterrence and management, to attempts to completely eradicate the pest. Pest control measures may be performed as part of an integrated pest management strategy. In agriculture, pests are kept at bay by Mechanical pest control, mechanical, tillage, cultural, pesticide, chemical and biological pest control , biological means. Ploughing and cultivation of the soil before sowing mitigate the pest burden, and crop rotation helps to reduce the build-up of a certain pest species. Concern about environment means limiting the use of pesticides in favour of other methods. This can be achieved by monitoring the crop, only applying Pesticide, pesticides when necessary, and by growing Variety (botany), ...
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Pesticide Poisoning
A pesticide poisoning occurs when pesticides, chemicals intended to control a pest, affect non-target organisms such as humans, wildlife, plants, or bees. There are three types of pesticide poisoning. The first of the three is a single and short-term very high level of exposure which can be experienced by individuals who die by suicide, as well as pesticide formulators. The second type of poisoning is long-term high-level exposure, which can occur in pesticide formulators and manufacturers. The third type of poisoning is a long-term low-level exposure, which individuals are exposed to from sources such as pesticide residues in food as well as contact with pesticide residues in the air, water, soil, sediment, food materials, plants and animals. In developing countries, such as Sri Lanka, pesticide poisonings from short-term very high level of exposure (acute poisoning) is the most worrisome type of poisoning. However, in developed countries, such as Canada, it is the complete o ...
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Durum
Durum wheat (), also called pasta wheat or macaroni wheat (''Triticum durum'' or ''Triticum turgidum'' subsp. ''durum''), is a tetraploid species of wheat. It is the second most cultivated species of wheat after common wheat, although it represents only 5% to 8% of global wheat production. It was developed by artificial selection of the domesticated emmer wheat strains formerly grown in Central Europe and the Near East around 7000 BC, which developed a naked, free-threshing form. Like emmer, durum wheat is awned (with bristles). It is the predominant wheat grown in the Middle East. ''Durum'' in Latin means 'hard', and the species is the hardest of all wheats. This refers to the resistance of the grain to milling, in particular of the starchy endosperm, causing dough made from its flour to be weak or "soft". This makes durum favorable for semolina and pasta and less practical for flour, which requires more work than with hexaploid wheats such as common bread wheats. Despite ...
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Methiocarb
Methiocarb is a carbamate pesticide (an acetylcholinesterase inhibitor) which is used as an insecticide, bird repellent, acaricide and molluscicide since the 1960s. Methiocarb has contact and stomach action on mites and neurotoxic effects on molluscs. Seeds treated with methiocarb also affect birds. Other names for methiocarb are mesurol and mercaptodimethur. Due to its toxicity, methiocarb approval as a plant protection product has been withdrawn by the EU effective 2020. Structure and reactivity The carbamate functional group in methiocarb can be cleaved by cholinesterase to result in the carbamate, which binds to the cholinesterase, and the phenol. Synthesis Methiocarb (3) is synthesised by Bayer from 4-methylthio-3,5-xylenol (1) and methyl isocyanate (2). The xylenol (1) will act as the nucleophile in this reaction attacking the partially positively charged carbon in the isocyanate (2). Mechanism of action Methiocarb acts by acetylcholinesterase inhibition. The pro ...
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Acetylcholinesterase Inhibitor
Acetylcholinesterase inhibitors (AChEIs) also often called cholinesterase inhibitors, inhibit the enzyme acetylcholinesterase from breaking down the neurotransmitter acetylcholine into choline and acetate, thereby increasing both the level and duration of action of acetylcholine in the central nervous system, autonomic ganglia and neuromuscular junctions, which are rich in acetylcholine receptors. Acetylcholinesterase inhibitors are one of two types of cholinesterase inhibitors; the other being butyryl-cholinesterase inhibitors. Acetylcholinesterase is the primary member of the cholinesterase enzyme family. Acetylcholinesterase inhibitors are classified as reversible, irreversible, or quasi-irreversible (also called pseudo-irreversible). Mechanism of action Organophosphates Organophosphates like tetraethyl pyrophosphate (TEPP) and sarin inhibit cholinesterases, enzymes that hydrolyze the neurotransmitter acetylcholine. The active centre of cholinesterases feature ...
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Niclosamide
Niclosamide, sold under the brand name Niclocide among others, is an anthelmintic medication used to treat tapeworm infestations, including diphyllobothriasis, hymenolepiasis, and taeniasis. It is not effective against other worms such as flukes or roundworms. It is taken by mouth. Side effects include nausea, vomiting, abdominal pain, and itchiness. It may be used during pregnancy. It works by blocking glucose uptake and oxidative phosphorylation by the worm. Niclosamide was first synthesized in 1958. It is on the World Health Organization's List of Essential Medicines. Niclosamide is not available for human use in the United States. Side effects Side effects include nausea, vomiting, abdominal pain, constipation, and itchiness. Rarely, dizziness, skin rash, drowsiness, perianal itching, or an unpleasant taste occur. For some of these reasons, praziquantel is a preferable and equally effective treatment for tapeworm infestation. Of note, niclosamide kills the po ...
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