Lithium Oxalate
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Lithium Oxalate
Lithium oxalate is an organic compound with the chemical formula . It is a salt of lithium metal and oxalic acid. It consists of lithium cations and oxalate anions . Lithium oxalate is soluble in water and converts to lithium oxide when heated. Synthesis One of the methods of synthesis is the reaction of direct neutralization of oxalic acid with lithium hydroxide: : Properties The compound crystallizes in the monoclinic system, cell parameters ''a'' = 3.400 Å, ''b'' = 5.156 Å, ''c'' = 9.055 Å, ''β'' = 95.60°, ''Z'' = 4. Lithium oxalate decomposes when heated at : : Applications In pyrotechnics Pyrotechnics is the science and craft of creating fireworks, but also includes safety matches, oxygen candles, Pyrotechnic fastener, explosive bolts (and other fasteners), parts of automotive airbags, as well as gas-pressure blasting in mining, q ..., the compound is used to color the flame red. References {{Oxalates Inorganic compounds Lithium salts Oxalates ...
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Sigma Aldrich
Sigma-Aldrich (formally MilliporeSigma) is an American chemical, life science, and biotechnology company owned by the multinational chemical conglomerate Merck Group. Sigma-Aldrich was created in 1975 by the merger of Sigma Chemical Company and Aldrich Chemical Company. It grew through various acquisitions until it had over 9,600 employees and was listed on the Fortune 1000. The company has two United States headquarters, in St. Louis and Burlington, MA and has operations in approximately 40 countries. In 2015, the multinational chemical conglomerate Merck Group acquired Sigma-Aldrich for $17 billion. The company is currently a part of Merck's life science business and in combination with Merck's earlier acquired Millipore Corporation, Millipore, operates as MilliporeSigma. It is headquartered in Burlington, Massachusetts, United States. History Sigma Chemical Company of St. Louis and Aldrich Chemical Company of Milwaukee were both American specialty chemical companies when they ...
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Cations
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons (e.g. K+ ( potassium ion)) while an anion is a negatively charged ion with more electrons than protons (e.g. Cl− ( chloride ion) and OH− (hydroxide ion)). Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed ''monatomic ions'', ''atomic ions'' or ''simple ions'', while ions consisting of two or more atoms are termed polyatomic ions or ''molecular ions''. If only a + or − is present, it indica ...
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Inorganic Compounds
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. All allotropes (structurally different pure forms of an element) and some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, graphene, etc.), carbon monoxide , carbon dioxide , carbides, and salts of inorganic anions such as carbonates, cyanides, cyanates, thiocyanates, isothiocyanates, etc. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it cannot occur within living things. History Friedrich Wöhler's conver ...
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Flame Test
A flame test is relatively quick test for the presence of some elements in a sample. The technique is archaic and of questionable reliability, but once was a component of qualitative inorganic analysis. The phenomenon is related to pyrotechnics and atomic emission spectroscopy. The color of the flames is understood through the principles of atomic electron transition and photoemission, where varying elements require distinct energy levels (photons) for electron transitions. History Robert Bunsen invented the now-famous Bunsen burner in 1855, which was useful in flame tests due to its non-luminous flame that did not disrupt the colors emitted by the test materials. The Bunsen burner, combined with a prism (filtering the color interference of contaminants), led to the creation of the spectroscope, capable of emitting the spectral emission of various elements. In 1860, the unexpected appearance of sky-blue and dark red was observed in spectral emissions by Robert Bunsen ...
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Pyrotechnics
Pyrotechnics is the science and craft of creating fireworks, but also includes safety matches, oxygen candles, Pyrotechnic fastener, explosive bolts (and other fasteners), parts of automotive airbags, as well as gas-pressure blasting in mining, quarrying, and demolition. This trade relies upon self-contained and self-sustained exothermic chemical reactions to make heat, light, gas, smoke and/or sound. The name etymology, comes from the Greek words ''pyr'' (πυρ; 'fire') and ''technikós'' (τεχνικός; 'artistic'). Improper use of pyrotechnics could lead to List of pyrotechnic incidents, pyrotechnic accidents. People responsible for the safe storage, handling, and functioning of pyrotechnic devices are known as pyrotechnicians. Proximate pyrotechnics Explosions, flashes, smoke, flames, fireworks and other pyrotechnic-driven effects used in the entertainment industry are referred to as proximate pyrotechnics. Proximate refers to the pyrotechnic device's location relative to ...
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Angstrom
The angstrom (; ) is a unit of length equal to m; that is, one ten-billionth of a metre, a hundred-millionth of a centimetre, 0.1 nanometre, or 100 picometres. The unit is named after the Swedish physicist Anders Jonas Ångström (1814–1874). It was originally spelled with Swedish letters, as Ångström and later as ångström (). The latter spelling is still listed in some dictionaries, but is now rare in English texts. Some popular US dictionaries list only the spelling ''angstrom''. The unit's symbol is Å, which is a letter of the Swedish alphabet, regardless of how the unit is spelled. However, "A" or "A.U." may be used in less formal contexts or typographically limited media. The angstrom is often used in the natural sciences and technology to express sizes of atoms, molecules, microscopic biological structures, and lengths of chemical bonds, arrangement of atoms in crystals, wavelengths of electromagnetic radiation, and dimensions of integrated circuit part ...
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Crystal Structure
In crystallography, crystal structure is a description of ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from intrinsic nature of constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter. The smallest group of particles in a material that constitutes this repeating pattern is the unit cell of the structure. The unit cell completely reflects the symmetry and structure of the entire crystal, which is built up by repetitive translation of the unit cell along its principal axes. The translation vectors define the nodes of the Bravais lattice. The lengths of principal axes/edges, of the unit cell and angles between them are lattice constants, also called ''lattice parameters'' or ''cell parameters''. The symmetry properties of a crystal are described by the concept of space groups. All possible symmetric arrangements of particles in three-dimensional space ...
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Monoclinic System
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°. Bravais lattices Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic. For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;See , row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. The length a of the primitive cell below equals \frac \sqrt of the conventional cell above. Crystal classes The table below organizes the spa ...
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Lithium Hydroxide
Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While classified as a strong base, lithium hydroxide is the weakest known alkali metal hydroxide. Production The preferred feedstock is hard-rock spodumene, where the lithium content is expressed as % lithium oxide. Lithium carbonate route Lithium hydroxide is often produced industrially from lithium carbonate in a metathesis reaction with calcium hydroxide: : The initially produced hydrate is dehydrated by heating under vacuum up to 180 °C. Lithium sulfate route An alternative route involves the intermediacy of lithium sulfate: :α- spodumene → β-spodumene :β-spodumene + CaO → + ... : : The main by-products are gypsum and sodium sulphate, which have some market value. Commercial setting According to Bloomberg, Ganfeng ...
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Lithium Oxide
Lithium oxide (Lithium, Oxygen, O) or lithia is an Inorganic compound, inorganic chemical compound. It is a white or pale yellow solid. Although not specifically important, many materials are assessed on the basis of their Li2O content. For example, the Li2O content of the principal lithium mineral spodumene (LiAlSi2O6) is 8.03%. Production Lithium oxide forms along with small amounts of lithium peroxide when lithium metal is burned in the air and combines with oxygen at temperatures above 100 °C: :4Li + → 2. Pure can be produced by the thermal decomposition of lithium peroxide, , at 450 °CWietelmann, Ulrich and Bauer, Richard J. (2005) "Lithium and Lithium Compounds" in ''Ullmann's Encyclopedia of Industrial Chemistry'', Wiley-VCH: Weinheim. . :2 → 2 + Structure Solid lithium oxide adopts an antifluorite structure with four-coordinated Li+ centers and eight-coordinated oxides. The ground state gas phase molecule is linear with a bond length consistent with ...
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Anions
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons (e.g. K+ ( potassium ion)) while an anion is a negatively charged ion with more electrons than protons (e.g. Cl− ( chloride ion) and OH− (hydroxide ion)). Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed ''monatomic ions'', ''atomic ions'' or ''simple ions'', while ions consisting of two or more atoms are termed polyatomic ions or ''molecular ions''. If only a + or − is present, it indica ...
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