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Liesegang
Liesegang rings () are a phenomenon seen in many, if not most, chemical systems undergoing a precipitation reaction under certain conditions of concentration and in the absence of convection. Rings are formed when weakly soluble salts are produced from reaction of two soluble substances, one of which is dissolved in a gel medium. The phenomenon is most commonly seen as rings in a Petri dish or bands in a test tube; however, more complex patterns have been observed, such as dislocations of the ring structure in a Petri dish, helices, and "Saturn rings" in a test tube. Despite continuous investigation since rediscovery of the rings in 1896, the mechanism for the formation of Liesegang rings is still unclear. History The phenomenon was first noticed in 1855 by the German chemist Friedlieb Ferdinand Runge. He observed them in the course of experiments on the precipitation of reagents in blotting paper. In 1896 the German chemist Raphael Eduard Liesegang, Raphael E. Liesegang noted t ...
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Raphael Eduard Liesegang
Raphael Eduard Liesegang () (1 November 1869 – 13 November 1947) was a German chemist, photographer and entrepreneur born in Elberfeld. He is known for his work on Liesegang rings. He also helped develop the methods of capillary analysis, a precursor to paper chromatography, published a paper on the possibility of television (years before the discovery of the electron), contributed to chromosome theory, worked on properties of aerosols and gelatins, the origins of silicosis, the role of carbon dioxide in plant life and the mechanism of both black and white and colour photographic processes. The son of a painter (and eventual photographer), Liesegang longed for an artistic career but lacked the ability to draw or paint. His father would later invent a camera and photography would go on to be one of Liesegangs passions. Research into photographic emulsions led to his personal discovery of Liesegang rings. He was not the first person to observe the effect, but they bear his nam ...
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Wilhelm Ostwald
Wilhelm Friedrich Ostwald (; – 4 April 1932) was a Latvian chemist and philosopher. Ostwald is credited with being one of the founders of the field of physical chemistry, with Jacobus Henricus van 't Hoff, Walther Nernst and Svante Arrhenius. He received the Nobel Prize in Chemistry in 1909 for his scientific contributions to the fields of catalysis, chemical equilibria and reaction velocities. Following his 1906 retirement from academic life, Ostwald became much involved in philosophy, art, and politics. He made significant contributions to each of these fields. He has been described as a polymath. Early life and education Ostwald was born ethnically Baltic German in Riga, Russian Empire (now Latvia) to master-cooper Gottfried Wilhelm Ostwald and Elisabeth Leuckel. He was the middle child of three, born after Eugen and before Gottfried. Ostwald developed an interest in science as a child and conducted experiments at his home, particularly related to fireworks and photogr ...
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Friedlieb Ferdinand Runge
Friedlieb Ferdinand Runge (8 February 1794 – 25 March 1867) was a German analytical chemist. Runge identified the mydriatic (pupil dilating) effects of belladonna (deadly nightshade) extract, identified caffeine, and discovered the first coal tar dye ( aniline blue). Early life Friedlieb Ferdinand Runge was born near Hamburg on 8 February 1794. From a young age, Runge conducted chemical experiments, serendipitously identifying the mydriatic (pupil dilating) effects of belladonna (deadly nightshade) extract. Career In 1819, Runge was invited to show Goethe how belladonna caused dilation of the pupil, which Runge did, using a cat as an experimental subject. Goethe was so impressed with the demonstration that :"Nachdem Goethe mir seine größte Zufriedenheit sowol über die Erzählung des durch scheinbaren schwarzen Staar Geretteten, wie auch über das andere ausgesprochen, übergab er mir noch eine Schachtel mit Kaffeebohnen, die ein Grieche ihm als etwas Vorzügliches ...
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Carbonates
A carbonate is a salt of carbonic acid, (), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate group . The term is also used as a verb, to describe carbonation: the process of raising the concentrations of carbonate and bicarbonate ions in water to produce carbonated water and other carbonated beverageseither by the addition of carbon dioxide gas under pressure or by dissolving carbonate or bicarbonate salts into the water. In geology and mineralogy, the term "carbonate" can refer both to carbonate minerals and carbonate rock (which is made of chiefly carbonate minerals), and both are dominated by the carbonate ion, . Carbonate minerals are extremely varied and ubiquitous in chemically precipitated sedimentary rock. The most common are calcite or calcium carbonate, , the chief constituent of limestone (as well as the main component of mo ...
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Precipitation Reaction
In an aqueous solution, precipitation is the "sedimentation of a solid material (a precipitate) from a liquid solution". The solid formed is called the precipitate. In case of an inorganic chemical reaction leading to precipitation, the chemical reagent causing the solid to form is called the precipitant. The clear liquid remaining above the precipitated or the centrifuged solid phase is also called the supernate or supernatant. The notion of precipitation can also be extended to other domains of chemistry (organic chemistry and biochemistry) and even be applied to the solid phases (e.g. metallurgy and alloys) when solid impurities segregate from a solid phase. Supersaturation The precipitation of a compound may occur when its concentration exceeds its solubility. This can be due to temperature changes, solvent evaporation, or by mixing solvents. Precipitation occurs more rapidly from a strongly supersaturated solution. The formation of a precipitate can be caused by a che ...
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Ammonium Chloride
Ammonium chloride is an inorganic chemical compound with the chemical formula , also written as . It is an ammonium salt of hydrogen chloride. It consists of ammonium cations and chloride anions . It is a white crystalline salt (chemistry), salt that is highly soluble in water. Solutions of ammonium chloride are mildly acidic. In its naturally occurring mineralogic form, it is known as salammoniac. The mineral is commonly formed on burning coal dumps from condensation of coal-derived gases. It is also found around some types of volcanic vents. It is mainly used as fertilizer and a flavouring agent in Salty liquorice, some types of liquorice. It is a product of the reaction of hydrochloric acid and ammonia. Production It is a product of the Solvay process used to produce sodium carbonate: :CO2 + 2 NH3 + 2 NaCl + H2O → 2 NH4Cl + Na2CO3 Not only is that method the principal one for the manufacture of ammonium chloride, but also it is used to minimize ammonia release in some ind ...
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Hydrochloric Acid
Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is a component of the gastric acid in the digestive systems of most animal species, including humans. Hydrochloric acid is an important laboratory reagent and industrial chemical. Etymology Because it was produced from halite, rock salt according to the methods of Johann Rudolph Glauber, hydrochloric acid was historically called by European alchemists ''spirits of salt'' or ''acidum salis'' (salt acid). Both names are still used, especially in other languages, such as , , , , , , , , , , (''ensan''), zh, 盐酸 (''yánsuān''), and (''yeomsan''). Gaseous HCl was called ''marine acid air''. The name ''muriatic acid'' has the same origin (''muriatic'' means "pertaining to brine or salt", hence ''muriate'' means hydrochloride), and this ...
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Hydroxylamine Hydrochloride
Hydroxylammonium chloride is a chemical compound with the formula . It is the hydrochloric acid salt of hydroxylamine (). Hydroxylamine is a biological intermediate in nitrification (biological oxidation of ammonia with oxygen into nitrite) and in anammox (biological oxidation of nitrite and ammonium into dinitrogen gas) which are important in the nitrogen cycle in soil and in wastewater treatment plants. Applications Hydroxylammonium chloride is used in organic synthesis for preparation of oximes and hydroxamic acids from carboxylic acids, N- and O- substituted hydroxylamines, and addition reactions of carbon-carbon double bond. During the acetyl bromide method of extracting lignin from lignocellulosic biomass, hydroxylammonium chloride can be used to remove bromine and polybromide from the solution. In surface treatments, it is used in the preparation of anti-skinning agents, corrosion inhibitors, and cleaner additives. It is also a starting material for pharmaceuticals an ...
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Copper Sulfate
Copper sulfate may refer to: * Copper(II) sulfate, CuSO4, a common, greenish blue compound used as a fungicide and herbicide * Copper(I) sulfate, Cu2SO4, an unstable white solid which is uncommonly used {{chemistry index Copper compounds ...
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