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Lead Sulfate
Lead(II) sulfate (PbSO4) is a white solid, which appears white in microcrystalline form. It is also known as ''fast white'', ''milk white'', ''sulfuric acid lead salt'' or ''anglesite''. It is often seen in the plates/electrodes of car batteries, as it is formed when the battery is discharged (when the battery is recharged, then the lead sulfate is transformed back to metallic lead and sulfuric acid on the negative terminal or lead dioxide and sulfuric acid on the positive terminal). Lead sulfate is poorly soluble in water. Structure Anglesite (lead(II) sulfate, ) adopts the same orthorhombic crystal structure as celestite ( strontium sulfate, ) and barite (barium sulfate, ). All three minerals' structures are in the space group ''Pbnm'' (number 62). Each lead(II) ion is surrounded by 12 oxygen atoms from 7 sulfate ions, forming a PbO12 polyhedron. The lead–oxygen distances range from 2.612 Å to 3.267 Å and the average distance is 2.865 Å. Manufacturing Lead(II) sulfate ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Anglesite
Anglesite is a lead sulfate mineral with the chemical formula PbSO4. It occurs as an oxidation product of primary lead sulfide ore, galena. Anglesite occurs as prismatic orthorhombic crystals and earthy masses, and is isomorphous with barite and celestine. It contains 74% of lead by mass and therefore has a high specific gravity of 6.3. Anglesite's color is white or gray with pale yellow streaks. It may be dark gray if impure. It was first recognized as a mineral species by William Withering in 1783, who discovered it in the Parys copper-mine in Anglesey; the name anglesite, from this locality, was given by F. S. Beudant in 1832. The crystals from Anglesey, which were formerly found abundantly on a matrix of dull limonite, are small in size and simple in form, being usually bounded by four faces of a prism and four faces of a dome; they are brownish-yellow in colour owing to a stain of limonite. Crystals from some other localities, notably from in Sardinia, are transparent a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead–acid Battery
The lead–acid battery is a type of rechargeable battery first invented in 1859 by French physicist Gaston Planté. It was the first type of rechargeable battery to be invented. Compared to modern rechargeable batteries, lead–acid batteries have relatively low energy density. Despite this, they are able to supply high surge currents. These features, along with their low cost, make them attractive for use in motor vehicles in order to provide the high current required by starter motors. Lead–acid batteries suffer from relatively short cycle lifespan (usually less than 500 deep cycles) and overall lifespan (due to the ''double sulfation'' in the discharged state), as well as long charging times. As they are not as expensive when compared to newer technologies, lead–acid batteries are widely used even when surge current is not important and other designs could provide higher energy densities. In 1999, lead–acid battery sales accounted for 40–50% of the value from batteries ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead(II)-sulfate-xtal-Pb-coordination-3D-bs-17
Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable nuclide, stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its Amphoterism, amphoteric nature; lead and lead oxides react with acids and base (chemistry), bases, and it tends to form covalent bonds. Lead compounds, Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Coordination Geometry
The coordination geometry of an atom is the geometrical pattern defined by the atoms around the central atom. The term is commonly applied in the field of inorganic chemistry, where diverse structures are observed. The coordination geometry depends on the number, not the type, of ligands bonded to the metal centre as well as their locations. The number of atoms bonded is the coordination number. The geometrical pattern can be described as a polyhedron where the vertices of the polyhedron are the centres of the coordinating atoms in the ligands. The coordination preference of a metal often varies with its oxidation state. The number of coordination bonds (coordination number) can vary from two in as high as 20 in . One of the most common coordination geometries is octahedral, where six ligands are coordinated to the metal in a symmetrical distribution, leading to the formation of an octahedron if lines were drawn between the ligands. Other common coordination geometries are tet ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
American Mineralogist
''American Mineralogist: An International Journal of Earth and Planetary Materials'' is a peer-reviewed scientific journal covering the general fields of mineralogy, crystallography, geochemistry, and petrology. It is an official journal of the Mineralogical Society of America, publishing both subscription and open access articles. The journal is a hybrid open-access journal. The editors-in-chief are Hongwu Xu (Los Alamos National Laboratory), and Don Baker (McGill University). History The journal was established in 1916, with the first issue appearing in July of that year, under the auspices of the ''Philadelphia Mineralogical Society'', the ''New York Mineralogical Club'', and the ''Mineral Collectors' Association''. On December 30, 1919, the Mineralogical Society of America was formed and ''American Mineralogist'' became the society's journal. Abstracting and indexing The ''American Mineralogist'' is abstracted and indexed in Chemical Abstracts, the Science Citation Index, Ge ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
List Of Space Groups
There are 230 space groups in three dimensions, given by a number index, and a full name in Hermann–Mauguin notation, and a short name (international short symbol). The long names are given with spaces for readability. The groups each have a point group of the unit cell. Symbols In Hermann–Mauguin notation, space groups are named by a symbol combining the point group identifier with the uppercase letters describing the lattice type. Translations within the lattice in the form of screw axes and glide planes are also noted, giving a complete crystallographic space group. These are the Bravais lattices in three dimensions: *P primitive *I body centered (from the German ''Innenzentriert'') *F face centered (from the German ''Flächenzentriert'') *A centered on A faces only *B centered on B faces only *C centered on C faces only *R rhombohedral A reflection plane m within the point groups can be replaced by a glide plane, labeled as a, b, or c depending on which axis the glide i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Space Group
In mathematics, physics and chemistry, a space group is the symmetry group of a repeating pattern in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of the pattern that leave it unchanged. In three dimensions, space groups are classified into 219 distinct types, or 230 types if chiral copies are considered distinct. Space groups are discrete cocompact groups of isometries of an oriented Euclidean space in any number of dimensions. In dimensions other than 3, they are sometimes called Bieberbach groups. In crystallography, space groups are also called the crystallographic or Fedorov groups, and represent a description of the symmetry of the crystal. A definitive source regarding 3-dimensional space groups is the ''International Tables for Crystallography'' . History Space groups in 2 dimensions are the 17 wallpaper groups which have been known for several centuries, though the proof that the list ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Barium Sulfate
Barium sulfate (or sulphate) is the inorganic compound with the chemical formula Ba SO4. It is a white crystalline solid that is odorless and insoluble in water. It occurs in nature as the mineral barite, which is the main commercial source of barium and materials prepared from it. Its opaque white appearance and its high density are exploited in its main applications.Holleman, A. F. and Wiberg, E. (2001) ''Inorganic Chemistry'', San Diego, CA. Academic Press, . Uses Drilling fluids About 80% of the world's barium sulfate production, mostly purified mineral, is consumed as a component of oil well drilling fluid. It increases the density of the fluid, increasing the hydrostatic pressure in the well and reducing the chance of a blowout. Radiocontrast agent Barium sulfate in suspension is often used medically as a radiocontrast agent for X-ray imaging and other diagnostic procedures. It is most often used in imaging of the GI tract during what is colloquially known as a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Strontium Sulfate
Strontium sulfate (SrSO4) is the sulfate salt of strontium. It is a white crystalline powder and occurs in nature as the mineral celestine. It is poorly soluble in water to the extent of 1 part in 8,800. It is more soluble in dilute HCl and nitric acid and appreciably soluble in alkali chloride solutions (e.g. sodium chloride). Structure Strontium sulfate is a polymeric material, isostructural with barium sulfate. Crystallized strontium sulfate is utilized by a small group of radiolarian protozoa, called the Acantharea, as a main constituent of their skeleton. Applications and chemistry Strontium sulfate is of interest as a naturally occurring precursor to other strontium compounds, which are more useful. In industry it is converted to the carbonate for use as ceramic precursor and the nitrate for use in pyrotechnics. The low aqueous solubility of strontium sulfate can lead to scale formation in processes where these ions meet. For example, it can form on surfaces of equip ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Celestite
Celestine (the IMA-accepted name) or celestite is a mineral consisting of strontium sulfate ( Sr S O). The mineral is named for its occasional delicate blue color. Celestine and the carbonate mineral strontianite are the principal sources of the element strontium, commonly used in fireworks and in various metal alloys. Etymology Celestine derives its name from the Latin word ''caelestis'' meaning celestial which in turn is derived from the Latin word ''caelum'' meaning sky, air, weather, atmosphere and heaven. Occurrence Celestine occurs as crystals, and also in compact massive and fibrous forms. It is mostly found in sedimentary rocks, often associated with the minerals gypsum, anhydrite, and halite. On occasion in some localities, it may also be found with sulfur inclusions. The mineral is found worldwide, usually in small quantities. Pale blue crystal specimens are found in Madagascar. White and orange variants also occurred at Yate, Bristol, UK, where it was ext ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crystal Structure
In crystallography, crystal structure is a description of ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from intrinsic nature of constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter. The smallest group of particles in a material that constitutes this repeating pattern is the unit cell of the structure. The unit cell completely reflects the symmetry and structure of the entire crystal, which is built up by repetitive translation of the unit cell along its principal axes. The translation vectors define the nodes of the Bravais lattice. The lengths of principal axes/edges, of the unit cell and angles between them are lattice constants, also called ''lattice parameters'' or ''cell parameters''. The symmetry properties of a crystal are described by the concept of space groups. All possible symmetric arrangements of particles in three-dimensional space ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Orthorhombic Crystal System
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal In mathematics, orthogonality (mathematics), orthogonality is the generalization of the geometric notion of ''perpendicularity''. Although many authors use the two terms ''perpendicular'' and ''orthogonal'' interchangeably, the term ''perpendic .... Bravais lattices There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , ro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
