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Lead(II) Carbonate
Lead(II) carbonate is the chemical compound with the chemical formula . It is a white, toxic solid. It occurs naturally as the mineral cerussite. Structure Like all metal carbonates, lead(II) carbonate adopts a dense, highly crosslinked structure consisting of intact and metal cation sites. As verified by X-ray crystallography, the Pb(II) centers are seven-coordinate, being surrounded by multiple carbonate ligands. The carbonate centers are bonded bidentate to a single Pb and bridge to five other Pb sites. Production and use Lead carbonate is manufactured by passing carbon dioxide into a cold dilute solution of lead(II) acetate, or by shaking a suspension of a lead salt more soluble than the carbonate with ammonium carbonate at a low temperature to avoid formation of basic lead carbonate. : Lead carbonate is used as a catalyst to polymerize formaldehyde to poly(oxymethylene). It improves the bonding of chloroprene to wire. Regulations The supply and use of this compound is r ...
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Cerussite
Cerussite (also known as lead carbonate or white lead ore) is a mineral consisting of lead carbonate with the chemical formula PbCO3, and is an important ore of lead. The name is from the Latin ''cerussa'', white lead. ''Cerussa nativa'' was mentioned by Conrad Gessner in 1565, and in 1832 F. S. Beudant applied the name ''céruse'' to the mineral, whilst the present form, cerussite, is due to W. Haidinger (1845). Miners' names in early use were lead-spar and white-lead-ore. Cerussite crystallizes in the orthorhombic crystal system and is isomorphous with aragonite. Like aragonite it is very frequently twinned, the compound crystals being pseudo-hexagonal in form. Three crystals are usually twinned together on two faces of the prism, producing six-rayed stellate groups with the individual crystals intercrossing at angles of nearly 60°. Crystals are of frequent occurrence and they usually have very bright and smooth faces. The mineral also occurs in compact granular masses, ...
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Ammonium Carbonate
Ammonium carbonate is a chemical compound with the chemical formula . It is an ammonium salt of carbonic acid. It is composed of ammonium cations and carbonate anions . Since ammonium carbonate readily degrades to gaseous ammonia and carbon dioxide upon heating, it is used as a leavening agent and also as smelling salt. It is also known as baker's ammonia and is a predecessor to the more modern leavening agents baking soda and baking powder. It is a component of what was formerly known as sal volatile and salt of hartshorn, and produces a pungent smell when baked. It comes in the form of a white powder or block, with a molar mass of 96.09 g/mol and a density of 1.50 g/cm3. It is a strong electrolyte. Production Ammonium carbonate is produced by combining carbon dioxide and aqueous ammonia. About 80,000 tons/year were produced as of 1997. : An orthorhombic ammonium carbonate monohydrate is known (). It crystallizes in an ammonia solution exposed in a carbon dioxide-rich atmos ...
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Leadhillite
Leadhillite is a lead sulfate carbonate hydroxide mineral, often associated with anglesite. It has the formula Pb4SO4(CO3)2(OH)2. Leadhillite crystallises in the Monoclinic crystal system, monoclinic system, but develops pseudo-hexagonal forms due to crystal twinning. It forms transparent to translucent variably coloured crystals with an adamantine Lustre (mineralogy), lustre. It is quite soft with a Mohs hardness of 2.5 and a relatively high specific gravity of 6.26 to 6.55. It was discovered in 1832 in the Susannah Mine, Leadhills in the county of Lanarkshire, Scotland. It is Polymorphism (materials science), trimorphous with susannite and macphersonite (these three minerals have the same formula, but different structures). Leadhillite is Monoclinic crystal system, monoclinic, susannite is Trigonal crystal system, trigonal and macphersonite is Orthorhombic crystal system, orthorhombic. Leadhillite was named in 1832 after the locality. Unit cell Leadhillite belongs to the mo ...
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Abellaite
Abellaite is a hydrous carbonate mineral discovered in the abandoned Eureka uranium mine in the village of La Torre de Capdella (Lleida province), Catalonia, Spain. The ideal chemical formula of abellaite is NaPb2(CO3)2(OH). It is named in honor of Joan Abella i Creus, a Catalan gemmologist who has long studied minerals from the Eureka mine and first found abellaite in the mine. A team composed, among others, by Jordi Ibáñez-Insa from the Institute of Earth Sciences Jaume Almera (CSIC) and by Joan Viñals and Xavier Llovet from the University of Barcelona, identified and characterized the mineral’s structure and chemical composition. Abellaite crystals are colorless to white, with a glassy or pearly appearance, and are easily crumbled. The mineral has a known synthetic analogue and is chemically similar to sanrománite. Robert Hazen et al. predicted its existence in 2015. Localities Catalonia, Spain: Eureka mine, Castell-estaó, La Torre de Cabdella, La Vall Fosca, El Pa ...
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White Lead
White lead is the basic lead carbonate 2PbCO3·Pb(OH)2. It is a complex Salt (chemistry), salt, containing both carbonate and hydroxide ions. White lead occurs naturally as a mineral, in which context it is known as hydrocerussite, a hydrate of cerussite. It was formerly used as an ingredient for lead paint and a cosmetic called Venetian ceruse, because of its Opacity (optics), opacity and the satiny smooth mixture it made with dryable oils. However, it tended to cause lead poisoning, and its use has been banned in most countries. Basic lead carbonate is produced by treating lead acetate with carbon dioxide and air. In the laboratory procedure treats lead acetate with urea. It occurs naturally as the mineral cerussite. The compound has been characterized by X-ray crystallography, which confirms the formula. The structure is complicated, features two kinds of Pb(II) sites, those bonded to hydroxide and those bonded to carbonate and hydroxide. Related white lead compounds White ...
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Chloroprene
Chloroprene (IUPAC name 2-chlorobuta-1,3-diene) is a chemical compound with the molecular formula CH2=CCl−CH=CH2. Chloroprene is a colorless volatile liquid, almost exclusively used as a monomer for the production of the polymer polychloroprene, better known as neoprene, a type of synthetic rubber. History Although it may have been discovered earlier, chloroprene was largely developed by DuPont during the early 1930s, specifically with the formation of neoprene in mind. The chemists Elmer K. Bolton, Wallace Carothers, Arnold Collins and Ira Williams are generally accredited with its development and commercialisation although the work was based upon that of Julius Arthur Nieuwland, with whom they collaborated. Production Chloroprene is produced in three steps from 1,3-butadiene: (i) chlorination, (ii) isomerization of part of the product stream, and (iii) dehydrochlorination of 3,4-dichlorobut-1-ene. Chlorine adds to 1,3-butadiene to afford a mixture of 3,4-dichlorobut-1-e ...
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Poly(oxymethylene)
Polyoxymethylene (POM), also known as acetal, polyacetal, and polyformaldehyde, is an engineering thermoplastic used in precision parts requiring high stiffness, low friction, and excellent dimensional stability. Short-chained POM (chain length between 8 and 100 repeating units) is also better known as paraformaldehyde (PFA). As with many other synthetic polymers, polyoxymethylenes are produced by different chemical firms with slightly different formulas and sold as Delrin, Kocetal, Ultraform, Celcon, Ramtal, Duracon, Kepital, Polypenco, Tenac and Hostaform. POM is characterized by its high strength, hardness and rigidity to −40 °C. POM is intrinsically opaque white because of its high crystalline composition but can be produced in a variety of colors. POM has a density of 1.410–1.420g/cm3. Typical applications for injection-molded POM include high-performance engineering components such as small gear wheels, eyeglass frames, ball bearings, ski bindings, fasteners, g ...
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Lead(II) Acetate
Lead(II) acetate is a white crystalline chemical compound with a slightly sweet taste. Its chemical formula is usually expressed as or , where Ac represents the acetyl group. Like many other lead compounds, it causes lead poisoning. Lead acetate is soluble in water and glycerin. With water it forms the trihydrate, , a colourless or white efflorescent monoclinic crystalline substance. The substance is used as a reagent to make other lead compounds and as a fixative for some dyes. In low concentrations, it formerly served as the principal active ingredient in progressive types of hair colouring dyes. Lead(II) acetate is also used as a mordant in textile printing and dyeing, and as a drier in paints and varnishes. It was historically used as a sweetener and preservative in wines and in other foods and for cosmetics. Production Lead(II) acetate can be made by boiling elemental lead in acetic acid and hydrogen peroxide. This method will also work with lead(II) carbonat ...
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Ethanol
Ethanol (also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound with the chemical formula . It is an Alcohol (chemistry), alcohol, with its formula also written as , or EtOH, where Et is the pseudoelement symbol for ethyl group, ethyl. Ethanol is a Volatility (chemistry), volatile, flammable, colorless liquid with a characteristic wine-like odor and pungent taste. As a psychoactive depressant, it is the active ingredient in alcoholic beverages, and the second most consumed drug globally behind caffeine. Ethanol is naturally produced by the fermentation process of sugars by yeasts or via petrochemical processes such as ethylene hydration. Historically it was used as a general anesthetic, and has modern medical applications as an antiseptic, disinfectant, solvent for some medications, and antidote for methanol poisoning and ethylene glycol poisoning. It is used as a chemical solvent and in the Chemical synthesis, synthesis of orga ...
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Carbon Dioxide
Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at normally-encountered concentrations it is odorless. As the source of carbon in the carbon cycle, atmospheric is the primary carbon source for life on Earth. In the air, carbon dioxide is transparent to visible light but absorbs infrared, infrared radiation, acting as a greenhouse gas. Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, and seawater. It is a trace gas Carbon dioxide in Earth's atmosphere, in Earth's atmosphere at 421 parts per million (ppm), or about 0.042% (as of May 2022) having risen from pre-industrial levels of 280 ppm or about 0.028%. Burning fossil fuels is the main cause of these increased concentrations, which are the primary cause of climate change.IPCC (2022Summary for pol ...
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