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Lanthanum Trifluoride
Lanthanum trifluoride is a refractory ionic compound of lanthanum and fluorine. The chemical formula is . The LaF3 structure Bonding is ionic with lanthanum highly coordinated. The cation sits at the center of a trigonal prism. Nine fluorine atoms are close: three at the bottom corners of the trigonal prism, three in the faces of the trigonal prism, and three at top corners of the trigonal prism. There are also two fluorides a little further away above and below the prism. The cation can be considered 9-coordinate or 11-coordinate. At 300 K, the structure allows the formation of Schottky defects with an activation energy of 0.07 eV, and free flow of fluoride ions with an activation energy of 0.45 eV, making the crystal unusually electrically conductive. The larger sized rare earth elements (lanthanides), which are those with smaller atomic number, also form trifluorides with the LaF3 structure. Some actinides do as well. Applications This white salt is som ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rhombohedral
In geometry, a rhombohedron (also called a rhombic hexahedron or, inaccurately, a rhomboid) is a special case of a parallelepiped in which all six faces are congruent rhombus, rhombi. It can be used to define the rhombohedral lattice system, a Honeycomb (geometry), honeycomb with rhombohedral cells. A rhombohedron has two opposite Apex_(geometry), apices at which all face angles are equal; a prolate rhombohedron has this common angle acute, and an oblate rhombohedron has an obtuse angle at these vertices. A cube is a special case of a rhombohedron with all sides square. Special cases The common angle at the two apices is here given as \theta. There are two general forms of the rhombohedron: oblate (flattened) and prolate (stretched). In the oblate case \theta > 90^\circ and in the prolate case \theta < 90^\circ. For the figure is a cube. Certain proportions of the rhombs give rise to some well-known special cases. These typically occur in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Actinide
The actinide () or actinoid () series encompasses at least the 14 metallic chemical elements in the 5f series, with atomic numbers from 89 to 102, actinium through nobelium. Number 103, lawrencium, is also generally included despite being part of the 6d transition series. The actinide series derives its name from the first element in the series, actinium. The informal chemical symbol An is used in general discussions of actinide chemistry to refer to any actinide. The 1985 IUPAC nomenclature of inorganic chemistry, IUPAC ''Red Book'' recommends that ''actinoid'' be used rather than ''actinide'', since the suffix ''-ide'' normally indicates a negative ion. However, owing to widespread current use, ''actinide'' is still allowed. Actinium through nobelium are f-block elements, while lawrencium is a d-block element and a transition metal. The series mostly corresponds to the filling of the 5f electron shell, although as isolated atoms in the ground state many have anomalous configu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluorides
Fluoride (). According to this source, is a possible pronunciation in British English. is an inorganic, monatomic anion of fluorine, with the chemical formula (also written ), whose salts are typically white or colorless. Fluoride salts typically have distinctive bitter tastes, and are odorless. Its salts and minerals are important chemical reagents and industrial chemicals, mainly used in the production of hydrogen fluoride for fluorocarbons. Fluoride is classified as a weak base since it only partially associates in solution, but concentrated fluoride is corrosive and can attack the skin. Fluoride is the simplest fluorine anion. In terms of charge and size, the fluoride ion resembles the hydroxide ion. Fluoride ions occur on Earth in several minerals, particularly fluorite, but are present only in trace quantities in bodies of water in nature. Nomenclature Fluorides include compounds that contain ionic fluoride and those in which fluoride does not dissociate. The nome ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lanthanum Compounds
Lanthanum is a chemical element; it has symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements between lanthanum and lutetium in the periodic table, of which lanthanum is the first and the prototype. Lanthanum is traditionally counted among the rare earth elements. Like most other rare earth elements, its usual oxidation state is +3, although some compounds are known with an oxidation state of +2. Lanthanum has no biological role in humans but is used by some bacteria. It is not particularly toxic to humans but does show some antimicrobial activity. Lanthanum usually occurs together with cerium and the other rare earth elements. Lanthanum was first found by the Swedish chemist Carl Gustaf Mosander in 1839 as an impurity in cerium nitrate – hence the name ''lanthanum'', from the ancient Greek (), meaning 'to lie hidden'. Although it ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Levinson Modifier
Levinson is an Ashkenazi Jewish surname meaning "son of Levi". Notable people with the surname include: * Aaron Levinson (born 1963), American producer, musician, composer and record label owner * André Levinson (1887–1933), French dance journalist * Anna Levinson (1939–2015), German entomologist * Arik Levinson, American economist * Arthur D. Levinson (born 1950), American businessman * Barry Levinson (1932–1987), American film producer * Barry Levinson (born 1942), American film director and screenwriter * Bernard M. Levinson (born 1952), American biblical scholar * Boris Levinson (1919–2002), Russian theatre and film actor * Dan Levinson (born 1965), American jazz musician * Dana Aliya Levinson (born 1992), American television writer, actress, and Jewish transgender advocate * Daniel Levinson (1920–1994), American psychologist * Daniel R. Levinson (born 1949), American attorney and government official * David Levinson, multiple people * Ed Levinson (1898–19 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluocerite
Fluocerite, also known as tysonite, is a mineral consisting of cerium and lanthanum fluorides, with the chemical formula . The end members are classified as two different mineral types depending on the cation, fluocerite-(Ce) and fluocerite-(La), corresponding respectively to lanthanum trifluoride and cerium trifluoride. Both crystallize in the trigonal system. Fluocerite-(Ce) was first described (without the Ce) in 1845 from hydrothermal veins in granite in Sweden. Fluocerite-(La) was first described in 1969 from the type locality in central Kazakhstan. The name tysonite was given in 1880 to the same type of mineral found in Colorado. Tysonite-type structure is used for rare-earth fluorides with the P3c1 space group In mathematics, physics and chemistry, a space group is the symmetry group of a repeating pattern in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of the pattern that ... structure. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluoride Selective Electrode
A fluoride selective electrode is a type of ion selective electrode sensitive to the concentration of the fluoride ion. A common example is the lanthanum fluoride electrode. Lanthanum fluoride electrode In the lanthanum fluoride electrode, the sensing element is a crystal of lanthanum fluoride (LaF3), doped with europium(II) fluoride (EuF2) to create lattice vacancies. Such a crystal is an ionic conductor by virtue of the mobility of fluoride ions which jump between lattice vacancies. An electrochemical cell may be constructed using such a crystal as a membrane separating two fluoride solutions. This cell acts as a concentration cell with transference where the fluoride transport number is 1. As transference of charge through the crystal is almost exclusively due to fluoride, the electrode is highly specific to fluoride. The only ion which significantly interferes is hydroxide (OH−). Generally such "alkaline error" can be avoided by buffering the sample to a pH below 7. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Europium(II) Fluoride
Europium(II) fluoride is an inorganic compound with a chemical formula EuF2. It was first synthesized in 1937.Zhao Yongzhi, Ma Ying, Hou Shaochun, Zhang Wenjuan, Wang Jingjing, Ding Yanrong, Hao Yifan氟化亚铕研究现状 (''lit''. Research Progress of Europium(II) Fluoride). ''Chinese Rare Earths'', 2017. 38 (5): 134-140. (in Chinese) Production Europium(II) fluoride can be produced by reducing europium(III) fluoride with metallic europium or hydrogen gas.Georg Brauer: ''Handbuch der Präparativen Anorganischen Chemie''. 3., umgearb. Auflage. Band I. Enke, Stuttgart 1975, , S. 255. :\mathrm :\mathrm Properties Europium(II) fluoride is a bright yellowish solid with a fluorite structure. EuF2 can be used to dope a trivalent rare-earth fluoride, such as lanthanum fluoride, LaF3, to create a vacancy-filled structure with increased conductivity over a pure crystal. Such a crystal can be used as a fluoride-specific semipermeable membrane in a fluoride selective electrode to detect t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rutgers University
Rutgers University ( ), officially Rutgers, The State University of New Jersey, is a Public university, public land-grant research university consisting of three campuses in New Jersey. Chartered in 1766, Rutgers was originally called Queen's College and was affiliated with the Reformed Church in America, Dutch Reformed Church. It is the eighth-oldest college in the United States, the second-oldest in New Jersey (after Princeton University), and one of nine colonial colleges that were chartered before the American Revolution.Stoeckel, Althea"Presidents, professors, and politics: the colonial colleges and the American revolution", ''Conspectus of History'' (1976) 1(3):45–56. In 1825, Queen's College was renamed Rutgers College in honor of Colonel Henry Rutgers, whose substantial gift to the school had stabilized its finances during a period of uncertainty. For most of its existence, Rutgers was a Private university, private liberal arts college. It has evolved into a Mixed-sex ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
ZBLAN
ZBLAN is the most stable, and consequently the most used, fluoride glass, a subcategory of the heavy metal fluoride glass (HMFG) group. Typically its composition is 53% Zirconium tetrafluoride, ZrF4, 20% Barium fluoride, BaF2, 4% Lanthanum trifluoride, LaF3, 3% Aluminium fluoride, AlF3 and 20% Sodium fluoride, NaF. ZBLAN is not a single material but rather has a spectrum of compositions, many of which are still untried. The biggest library in the world of ZBLAN glass compositions is currently owned by Le Verre Fluore, the oldest company working on HMFG technology. Other current ZBLAN fiber manufacturers are Thorlabs and KDD Fiberlabs. Hafnium fluoride is chemically similar to zirconium fluoride, and is sometimes used in place of it. ZBLAN glass has a broad optical transmission window extending from 0.22 micrometers in the UV to 7 micrometers in the infrared. ZBLAN has low refractive index (about 1.5), a relatively low glass transition temperature (''T''g) of 260–300 °C, lo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Index Of Refraction
In optics, the refractive index (or refraction index) of an optical medium is the ratio of the apparent speed of light in the air or vacuum to the speed in the medium. The refractive index determines how much the path of light is bent, or refracted, when entering a material. This is described by Snell's law of refraction, , where and are the angle of incidence and angle of refraction, respectively, of a ray crossing the interface between two media with refractive indices and . The refractive indices also determine the amount of light that is reflected when reaching the interface, as well as the critical angle for total internal reflection, their intensity (Fresnel equations) and Brewster's angle. The refractive index, n, can be seen as the factor by which the speed and the wavelength of the radiation are reduced with respect to their vacuum values: the speed of light in a medium is , and similarly the wavelength in that medium is , where is the wavelength of that light in v ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dichroic
In optics, a dichroic material is either one which causes visible light to be split up into distinct beams of different wavelengths (colours) (not to be confused with dispersion), or one in which light rays having different polarizations are absorbed by different amounts. In beam splitters The original meaning of ''dichroic'', from the Greek ''dikhroos'', two-coloured, refers to any optical device which can split a beam of light into two beams with differing wavelengths. Such devices include mirrors and filters, usually treated with optical coatings, which are designed to reflect light over a certain range of wavelengths and transmit light which is outside that range. An example is the dichroic prism, used in some camcorders, which uses several coatings to split light into red, green and blue components for recording on separate CCD arrays, however it is now more common to have a Bayer filter to filter individual pixels on a single CCD array. This kind of dichroic device does ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
