|
Laminar Flame Speed
Laminar flame speed is an intrinsic characteristic of premixed combustible mixtures. It is the speed at which an un-stretched laminar flame will propagate through a quiescent mixture of unburned reactants. Laminar flame speed is given the symbol ''s''L. According to the thermal flame theory of Ernest-François Mallard and Le Chatelier, the un-stretched laminar flame speed is dependent on only three properties of a chemical mixture: the thermal diffusivity of the mixture, the reaction rate of the mixture and the temperature through the flame zone: s_\mathrm^ = \sqrt \alpha is thermal diffusivity, \dot is reaction rate, and the temperature subscript u is for unburned, b is for burned and i is for ignition temperature. Laminar flame speed is a property of the mixture (fuel structure, stoichiometry) and thermodynamic conditions upon mixture ignition (pressure, temperature). Turbulent flame speed is a function of the aforementioned parameters, but also heavily depends on ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Laminar
Laminar means "flat". Laminar may refer to: Terms in science and engineering: * Laminar electronics or organic electronics, a branch of material sciences dealing with electrically conductive polymers and small molecules * Laminar armour or "banded mail", armour made from horizontal overlapping rows or bands of solid armour plates * Laminar flame speed, a property of a combustible mixture * Laminar flow, a fluid flowing in parallel layers with no disruption between the layers * Laminar organization, the way certain tissues are arranged in layers * Laminar set family, a mathematical structure. *A common leaf shape. Proper nouns: * Laminar Research, a Columbia, South Carolina, software company * Icaro Laminar, an Italian hang glider design * Pazmany Laminar, a personal light aircraft designed by Ladislao Pazmany See also * Lamina (other) Lamina may refer to: People * Saa Emerson Lamina, Sierra Leonean politician * Tamba Lamina, Sierra Leonean politician and diplomat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ernest-François Mallard
Ernest-François Mallard (4 February 1833 – 6 July 1894) was a French mineralogist and a member of the French Academy of Sciences. He is also notable for his work with Henri Louis Le Chatelier in combustion as applied to mining safety. – Complete Dictionary of Scientific Biography See also * Thermal flame theory *Detonation
Detonation () is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations propagate sup ...
[...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Henry Louis Le Chatelier
Henry Louis Le Chatelier (; 8 October 1850 – 17 September 1936) was a French chemist of the late 19th and early 20th centuries. He devised Le Chatelier's principle, used by chemists to predict the effect a changing condition has on a system in chemical equilibrium. Early life Le Chatelier was born on 8 October 1850 in Paris and was the son of French materials engineer Louis Le Chatelier and Louise Durand. His father was an influential figure who played important roles in the birth of the French aluminium industry, the introduction of the Martin-Siemens processes into the iron and steel industries, and the rise of railway transportation. Le Chatelier's father profoundly influenced his son's future. Henry Louis had one sister, Marie, and four brothers, Louis (1853–1928), Alfred (1855–1929), George (1857–1935), and André (1861–1929). His mother raised the children by regimen, described by Henry Louis: "I was accustomed to a very strict discipline: it was necessary to wak ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermal Diffusivity
In thermodynamics, thermal diffusivity is the thermal conductivity divided by density and specific heat capacity at constant pressure. It is a measure of the rate of heat transfer inside a material and has SI, SI units of m2/s. It is an intensive property. Thermal diffusivity is usually denoted by lowercase alpha (), but , , (kappa), , , D_T are also used. The formula is \alpha = \frac, where : is thermal conductivity (W/(m·K)), : is specific heat capacity (J/(kg·K)), : is density (kg/m3). Together, can be considered the volumetric heat capacity (J/(m3·K)). Thermal diffusivity is a positive coefficient in the heat equation: \frac = \alpha \nabla^2 T. One way to view thermal diffusivity is as the ratio of the time derivative of temperature to its Second derivative#Generalization to higher dimensions, curvature, quantifying the rate at which temperature concavity is "smoothed out". In a substance with high thermal diffusivity, heat moves rapidly through it because the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reaction Rate
The reaction rate or rate of reaction is the speed at which a chemical reaction takes place, defined as proportional to the increase in the concentration of a product per unit time and to the decrease in the concentration of a reactant per unit time. Reaction rates can vary dramatically. For example, the oxidative rusting of iron under Earth's atmosphere is a slow reaction that can take many years, but the combustion of cellulose in a fire is a reaction that takes place in fractions of a second. For most reactions, the rate decreases as the reaction proceeds. A reaction's rate can be determined by measuring the changes in concentration over time. Chemical kinetics is the part of physical chemistry that concerns how rates of chemical reactions are measured and predicted, and how reaction-rate data can be used to deduce probable reaction mechanisms. The concepts of chemical kinetics are applied in many disciplines, such as chemical engineering, enzymology and environmental e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Turbulence
In fluid dynamics, turbulence or turbulent flow is fluid motion characterized by chaotic changes in pressure and flow velocity. It is in contrast to laminar flow, which occurs when a fluid flows in parallel layers with no disruption between those layers. Turbulence is commonly observed in everyday phenomena such as surf, fast flowing rivers, billowing storm clouds, or smoke from a chimney, and most fluid flows occurring in nature or created in engineering applications are turbulent. Turbulence is caused by excessive kinetic energy in parts of a fluid flow, which overcomes the damping effect of the fluid's viscosity. For this reason, turbulence is commonly realized in low viscosity fluids. In general terms, in turbulent flow, unsteady vortices appear of many sizes which interact with each other, consequently drag due to friction effects increases. The onset of turbulence can be predicted by the dimensionless Reynolds number, the ratio of kinetic energy to viscous damping ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Eddy (fluid Dynamics)
In fluid dynamics, an eddy is the swirling of a fluid and the reverse current (water), current created when the fluid is in a Turbulence, turbulent flow regime. The moving fluid creates a space devoid of downstream-flowing fluid on the downstream side of the object. Fluid behind the obstacle flows into the void creating a swirl of fluid on each edge of the obstacle, followed by a short reverse flow of fluid behind the obstacle flowing upstream, toward the back of the obstacle. This phenomenon is naturally observed behind large emergent rocks in swift-flowing rivers. An eddy is a movement of fluid that deviates from the general flow of the fluid. An example for an eddy is a vortex which produces such deviation. However, there are other types of eddies that are not simple vortices. For example, a Rossby wave is an eddy which is an undulation that is a deviation from mean flow, but does not have the local closed streamlines of a vortex. Swirl and eddies in engineering The propensi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flame Speed
The flame speed is the measured rate of expansion of the flame front in a combustion reaction. Whereas ''flame velocity'' is generally used for a fuel, a related term is explosive velocity, which is the same relationship measured for an explosive. Combustion engineers differentiate between the laminar flame speed and turbulent flame speed. Flame speed is typically measured in m/s, cm/s, etc. In engines In an internal combustion engine, the flame speed of a fuel is a property which determines its ability to undergo controlled combustion without detonation. Flame speed is used along with adiabatic flame temperature to help determine the engine's efficiency. According to one source, "...high flame-speed combustion processes, which closely approximate constant-volume processes, should reflect in high efficiencies.''NASA Technical Note'', May 1977,Emissions and Total Energy Consumption of a Multicylinder Piston Engine Running on Gasoline and a Hydrogen-Gasoline Mixture" The flame spee ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Kinetics
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is different from chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate. Chemical kinetics includes investigations of how experimental conditions influence the speed of a chemical reaction and yield information about the reaction's mechanism and transition states, as well as the construction of mathematical models that also can describe the characteristics of a chemical reaction. History The pioneering work of chemical kinetics was done by German chemist Ludwig Wilhelmy in 1850. He experimentally studied the rate of inversion of sucrose and he used integrated rate law for the determination of the reaction kinetics of this reaction. His work was noticed 34 years later by Wilhelm Ostwald. In 1864, Peter Waage and Cato Guldberg published the law ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Activation Energy Asymptotics
Activation energy asymptotics (AEA), also known as large activation energy asymptotics, is an asymptotic analysis used in the combustion field utilizing the fact that the reaction rate is extremely sensitive to temperature changes due to the large activation energy of the chemical reaction. History The techniques were pioneered by the Russian scientists Yakov Borisovich Zel'dovich, David A. Frank-Kamenetskii and co-workers in the 30s, in their study on premixed flames and thermal explosions ( Frank-Kamenetskii theory), but not popular to western scientists until the 70s. In the early 70s, due to the pioneering work of Williams B. Bush, Francis E. Fendell, Forman A. Williams, Amable Liñán and John F. Clarke, it became popular in western community and since then it was widely used to explain more complicated problems in combustion. Method overview In combustion processes, the reaction rate \omega is dependent on temperature T in the following form ( Arrhenius law), :\omega(T) ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
