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Iridium Tetraiodide
Iridium(IV) iodide is a binary chemical compound of iridium Iridium is a chemical element with the symbol Ir and atomic number 77. A very hard, brittle, silvery-white transition metal of the platinum group, it is considered the second-densest naturally occurring metal (after osmium) with a density of ... and iodide with the chemical formula . Preparation Iridium(IV) iodide can be obtained by reacting dipotassium hexachloroiridate or hexachloroiridic acid with an aqueous solution of potassium iodide. Properties Iridium tetraiodide forms black crystals, does not dissolve in water and alcohol. In alkali metal iodide solutions, the compound dissolves easily to give a ruby red solution, forming complex salts. The compound decomposes when heated: :: Uses Iridium(IV) iodide can be used as a catalyst in organic chemistry. References Iridium compounds Iodides Platinum group halides {{inorganic-compound-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hexagonal Crystal Family
In crystallography, the hexagonal crystal family is one of the six crystal families, which includes two crystal systems (hexagonal and trigonal) and two lattice systems (hexagonal and rhombohedral). While commonly confused, the trigonal crystal system and the rhombohedral lattice system are not equivalent (see section crystal systems below). In particular, there are crystals that have trigonal symmetry but belong to the hexagonal lattice (such as α-quartz). The hexagonal crystal family consists of the 12 point groups such that at least one of their space groups has the hexagonal lattice as underlying lattice, and is the union of the hexagonal crystal system and the trigonal crystal system. There are 52 space groups associated with it, which are exactly those whose Bravais lattice is either hexagonal or rhombohedral. __TOC__ Lattice systems The hexagonal crystal family consists of two lattice systems: hexagonal and rhombohedral. Each lattice system consists of one Bravais l ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iridium Triiodide
Iridium(III) iodide is an iodide of iridium, with the chemical formula of IrI3. Preparation Iridium(III) iodide can be obtained by reducing iridium(IV) iodide with hydrogen at 210 °C. It can also be formed by the reaction of iridium dioxide or iridium(III) hydroxide with hydrogen iodide. Chemical properties Iridium(III) iodide is a dark brown solid that is insoluble in water. It is monoclinic like chromium trichloride Chromium(III) chloride (also called chromic chloride) describes any of several chemical compounds with the formula CrCl3, where can be 0, 5, and 6. The anhydrous compound with the formula CrCl3 is a violet solid. The most common form of the tri .... Its trihydrate is yellow and can be dehydrated into the dihydrate or anhydrous form on heating. Iridium(III) iodide also has a monohydrate. References {{Iodides Iridium compounds Iodides Platinum group halides ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Platinum Tetraiodide
Platinum(IV) iodide is a inorganic compound with the formula . A dark brown diamagnetic solid, it is one of several binary iodides of platinum. Synthesis The effect of iodine on platinum: : Also, decomposition of hydrogen hexaiodoplatinate(IV) at 80 °C: : Physical properties Platinum(IV) iodide forms dark brown crystals of several modifications: ''α''-, rhombic crystal system, spatial group ''P bca'', cell parameters a = 1.290 nm, b = 1.564 nm, c = 0.690 nm, Z = 8; ''β''-, cubic crystal system, spatial group ''P m3m'', cell parameters a = 0.56 nm, Z = 1; ''γ''-, tetragonal crystal system, spatial group ''I 41/a'', cell parameters a = 0.677 nm, c = 3.110 nm, Z = 8. decomposes in water. Soluble in alcohol, acetone, alkali, HI, KI, liquid . Chemical properties Decomposes when heated: : When dissolved in hydroiodic acid Hydroiodic acid (or hydriodic acid) is an aqueous solution of hydrogen iodide (HI). It is a strong acid, one that is ionized completely in an aqueo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iridium
Iridium is a chemical element with the symbol Ir and atomic number 77. A very hard, brittle, silvery-white transition metal of the platinum group, it is considered the second-densest naturally occurring metal (after osmium) with a density of as defined by experimental X-ray crystallography. It is one of the most corrosion-resistant metals, even at temperatures as high as . However, corrosion-resistance is not quantifiable in absolute terms; although only certain molten salts and halogens are corrosive to solid iridium, finely divided iridium dust is much more reactive and can be flammable, whereas gold dust is not flammable but can be attacked by substances that iridium resists, such as aqua regia. Iridium was discovered in 1803 among insoluble impurities in natural platinum. Smithson Tennant, the primary discoverer, named it after the Greek goddess Iris, personification of the rainbow, because of the striking and diverse colors of its salts. Iridium is one of the rarest ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iodide
An iodide ion is the ion I−. Compounds with iodine in formal oxidation state −1 are called iodides. In everyday life, iodide is most commonly encountered as a component of iodized salt, which many governments mandate. Worldwide, iodine deficiency affects two billion people and is the leading preventable cause of intellectual disability. Structure and characteristics of inorganic iodides Iodide is one of the largest monatomic anions. It is assigned a radius of around 206 picometers. For comparison, the lighter halides are considerably smaller: bromide (196 pm), chloride (181 pm), and fluoride (133 pm). In part because of its size, iodide forms relatively weak bonds with most elements. Most iodide salts are soluble in water, but often less so than the related chlorides and bromides. Iodide, being large, is less hydrophilic compared to the smaller anions. One consequence of this is that sodium iodide is highly soluble in acetone, whereas sodium chloride is not ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
American Elements
American Elements is a global manufacturer and distributor of advanced materials with a more than 35,000-page online product catalog and compendium of information on the chemical elements, advanced materials, and high technology applications. The company's headquarters and educational programs are based in Los Angeles, California. Its research and production facilities are located in Salt Lake City, Utah; Monterrey, Mexico; Baotou, China; and Manchester, UK. History American Elements began as a toll chemical manufacturer and refiner serving U.S. mining companies by producing metal-based chemicals from their deposits. In 1998, its two largest customers, the Unocal/ Molycorp rare-earth mine in Mountain Pass, California and the Rhodia rare-earth refinery in Freeport, Texas closed, ending domestic U.S. rare-earth production. In response, the company established mining joint ventures in Inner Mongolia, China and in 1999 became one of the first post-Cold War companies to export rare-e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
CRC Press
The CRC Press, LLC is an American publishing group that specializes in producing technical books. Many of their books relate to engineering, science and mathematics. Their scope also includes books on business, forensics and information technology. CRC Press is now a division of Taylor & Francis, itself a subsidiary of Informa. History The CRC Press was founded as the Chemical Rubber Company (CRC) in 1903 by brothers Arthur, Leo and Emanuel Friedman in Cleveland, Ohio, based on an earlier enterprise by Arthur, who had begun selling rubber laboratory aprons in 1900. The company gradually expanded to include sales of laboratory equipment to chemists. In 1913 the CRC offered a short (116-page) manual called the ''Rubber Handbook'' as an incentive for any purchase of a dozen aprons. Since then the ''Rubber Handbook'' has evolved into the CRC's flagship book, the ''CRC Handbook of Chemistry and Physics''. In 1964, Chemical Rubber decided to focus on its publishing ventures ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Iodide
Potassium iodide is a chemical compound, medication, and dietary supplement. It is a medication used for treating hyperthyroidism, in radiation emergencies, and for protecting the thyroid gland when certain types of radiopharmaceuticals are used. In the third world it is also used for treating skin sporotrichosis and phycomycosis. It is a supplement used by people with low dietary intake of iodine. It is administered orally. Common side effects include vomiting, diarrhea, abdominal pain, rash, and swelling of the salivary glands. Other side effects include allergic reactions, headache, goitre, and depression. While use during pregnancy may harm the baby, its use is still recommended in radiation emergencies. Potassium iodide has the chemical formula K I. Commercially it is made by mixing potassium hydroxide with iodine. Potassium iodide has been used medically since at least 1820. It is on the World Health Organization's List of Essential Medicines. Potassium iodide is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Macmillan & Company
Macmillan Publishers (occasionally known as the Macmillan Group; formally Macmillan Publishers Ltd and Macmillan Publishing Group, LLC) is a British publishing company traditionally considered to be one of the 'Big Five' English language publishers. Founded in London in 1843 by Scottish brothers Daniel and Alexander MacMillan, the firm would soon establish itself as a leading publisher in Britain. It published two of the best-known works of Victorian era children’s literature, Lewis Carroll's ''Alice's Adventures in Wonderland'' (1865) and Rudyard Kipling's ''The Jungle Book'' (1894). Former Prime Minister of the United Kingdom, Harold Macmillan, grandson of co-founder Daniel, was chairman of the company from 1964 until his death in December 1986. Since 1999, Macmillan has been a wholly owned subsidiary of Holtzbrinck Publishing Group with offices in 41 countries worldwide and operations in more than thirty others. History Macmillan was founded in London in 1843 by Daniel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alfa Aesar
Alfa Aesar, headquartered in Ward Hill, Massachusetts, United States, is a supplier of reagents and materials for use in research and development, and analysis. They have facilities in many countries and manufacture many of the chemicals they sell. History The current Alfa Aesar setup - part of the Johnson Matthey Fine Chemicals & Catalysts Division - comes from a series of company mergers: * Alfa Inorganics was founded in 1962 by Alfred Bader, in a 50:50 venture between Aldrich Chemicals and Metal Hydrides Inc. The purpose was to provide a source of inorganic research chemicals to sit alongside the organic chemicals of Bader's other company: Aldrich Chemicals. It was created to market inorganics, organometallics, and others such as organoboron and organoarsenic reagents. Following the amalgamation of Aldrich and the Sigma Chemical Co, the joint venture was terminated with Alfa reverting to Metal Hydrides ownership (later Ventron, later again Thiokol). In the USA the business ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iridium Compounds
Iridium compounds are compounds containing the element iridium (Ir). Iridium forms compounds in oxidation states between −3 and +9, but the most common oxidation states are +1, +3, and +4. Well-characterized compounds containing iridium in the +6 oxidation state include and the oxides and . iridium(VIII) oxide () was generated under matrix isolation conditions at 6 K in argon. The highest oxidation state (+9), which is also the highest recorded for ''any'' element, is found in gaseous . Oxides Only one binary oxide is well-characterized: Iridium dioxide, . It is a blue-black solid. The compound adopts the TiO2 rutile structure, featuring six coordinate iridium and three coordinate oxygen. It adopts the fluorite structure. A sesquioxide, , has been described as a blue-black powder, which is oxidized to by . The corresponding disulfides, diselenides, sesquisulfides, and sesquiselenides are known, as well as . Another oxide, iridium tetroxide, is also known, with iridiu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iodides
An iodide ion is the ion I−. Compounds with iodine in formal oxidation state −1 are called iodides. In everyday life, iodide is most commonly encountered as a component of iodized salt, which many governments mandate. Worldwide, iodine deficiency affects two billion people and is the leading preventable cause of intellectual disability. Structure and characteristics of inorganic iodides Iodide is one of the largest monatomic anions. It is assigned a radius of around 206 picometers. For comparison, the lighter halides are considerably smaller: bromide (196 pm), chloride (181 pm), and fluoride (133 pm). In part because of its size, iodide forms relatively weak bonds with most elements. Most iodide salts are soluble in water, but often less so than the related chlorides and bromides. Iodide, being large, is less hydrophilic compared to the smaller anions. One consequence of this is that sodium iodide is highly soluble in acetone, whereas sodium chloride is n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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