Intramolecular Acyloin Condensation
Intramolecular describes a process or phenomenon that occurs ''within'' a molecule. It can refer to: *Intramolecular reaction *Intramolecular force An intramolecular force (from Latin ''intra-'' 'within') is any force that binds together the atoms making up a molecule. Intramolecular forces are stronger than the Intermolecular force, intermolecular forces that govern the interactions between ... See also

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Intramolecular Reaction
In chemistry, intramolecular describes a Chemical process, process or characteristic limited within the Chemical structure, structure of a single molecule, a property or phenomenon limited to the extent of a single molecule. Relative rates In intramolecular organic reactions, two reaction sites are contained within a single molecule. This configuration elevates the effective concentration of the reacting partners resulting in high reaction rates. Many intramolecular reactions are observed where the intermolecular version does not take place. Intramolecular reactions, especially ones leading to the formation of 5- and 6-membered rings, are rapid compared to an analogous intermolecular process. This is largely a consequence of the reduced entropic cost for reaching the transition state of ring formation and the absence of significant strain associated with formation of rings of these sizes. For the formation of different ring sizes via cyclization of substrates of varying tether ...
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