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Hypercolor
Hypercolor was a line of clothing, mainly T-shirts and shorts, that changed color with heat. They were manufactured by Generra Sportswear Company of Seattle and marketed in the United States as Generra Hypercolor or Generra Hypergrafix and elsewhere as Global Hypercolor. They contained a thermochromic pigment made by Matsui Shikiso Chemical of Japan, that changed between two colors—one when cold, one when warm. The shirts were produced with several color change choices beginning in 1991. The effect could easily be permanently damaged, particularly when the clothing was washed in hotter than recommended water, ironed, bleached, or tumble-dried. Generra Sportswear Co. had originally been founded as a men's sportswear distributor and importer in Seattle in 1980. The company was sold to Texas-based Farah Manufacturing Co. in 1984 and bought back by its founders in 1989. In 1986, the company added childrenswear and womenswear items to their portfolio. They struggled to meet the ...
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Thermochromism
Thermochromism is the property of substances to change color due to a change in temperature. A mood ring is an example of this property used in a consumer product although thermochromism also has more practical uses, such as baby bottles, which change to a different color when cool enough to drink, or kettles which change color when water is at or near boiling point. Thermochromism is one of several types of chromism. Organic materials Thermochromatic liquid crystals The two common approaches are based on liquid crystals and leuco dyes. Liquid crystals are used in precision applications, as their responses can be engineered to accurate temperatures, but their color range is limited by their principle of operation. Leuco dyes allow wider range of colors to be used, but their response temperatures are more difficult to set with accuracy. Some liquid crystals are capable of displaying different colors at different temperatures. This change is dependent on selective reflection of ...
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Leuco Dye
A leuco dye (from the Greek λευκό ''leuko'': white ) is a dye which can switch between two chemical forms, one of which is colorless. Reversible transformations can be caused by heat, light or pH, resulting in examples of thermochromism, photochromism and halochromism, respectively. Irreversible transformations typically involve reduction or oxidation.Chemistry and Applications of Leuco Dyes. Ramaiah Muthyala. 302 pag. Springer; 1997 edition. The colorless form is sometimes referred to as the leuco form. Leuco dyes form the basis of thermal printer papers and certain pH indicators. Examples The most common example is in applying sulfur dyes and vat dyes, with indigo being a classic case. This is characteristically purple but is also completely insoluble in water, meaning that it cannot be applied to clothes directly. It is instead reduced to indigo white (sometimes Leucoindigo), which is water-soluble but colorless. When a submerged fabric is removed from a dyebath o ...
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Matsui Shikiso Chemical
Matsui Shikiso Chemical Co., Ltd was founded in 1923 by Kenji Matsui when he opened a paint and dye shop in Kyoto, Japan. Decades later, in 1948, the company started producing crayons and painting materials. By the 1950s, Matsui Shikiso Chemical discontinued their crayons and painting materials lines to focus on offering water based inks and pigments targeted principally to the textile screen printing industry. In the early 1980s, Matsui Shikiso Chemical developed Chromicolor, the first thermochromic paints, thermochromic inks, and thermochromic plastics, broadcast on Japan's national public channel, NHK (Nippon Hosoku Kaisha), introducing thermochromism to the world. Matsui's continued success led to establishing a subsidiary in Los Angeles, California named Matsui and Company, Inc. to better service their growing international clientele. By the end of the decade, Matsui and Company, Inc. changed its name to Matsui International Co., Inc., to capitalize on international markets. ...
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Crystal Violet Lactone
Crystal violet lactone (CVL) is a leuco dye, a lactone derivate of crystal violet 10B. In pure state it is a slightly yellowish crystalline powder, soluble in nonpolar or slightly polar organic solvents. The central carbon in the leuco form is in a tetrahedral configuration, with four covalent bonds. In an acidic environment, the lactone ring is broken, with the oxygen detaching from the central carbon. This now-trivalent position is a planar carbocation that is resonance stabilized, interconnecting the π systems of the aromatic rings and the amino functional groups. This single large conjugated system is a chromophore with strong absorption in visible spectrum, giving this compound its distinctive color. This chemical is usually drawn in the resonance structure with the cation on nitrogen. : It was the first dye used in carbonless copy papers, and it is still widely used in this application. It is also the leuco dye component in some thermochromic dyes, e.g. in the Hypercolo ...
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T-shirt
A T-shirt (also spelled tee shirt, or tee for short) is a style of fabric shirt named after the T shape of its body and sleeves. Traditionally, it has short sleeves and a round neckline, known as a '' crew neck'', which lacks a collar. T-shirts are generally made of stretchy, light, and inexpensive fabric and are easy to clean. The T-shirt evolved from undergarments used in the 19th century and, in the mid-20th century, transitioned from undergarments to general-use casual clothing. T-shirts are typically made of cotton textile in a stockinette or jersey knit, which has a distinctively pliable texture compared to shirts made of woven cloth. Some modern versions have a body made from a continuously knitted tube, produced on a circular knitting machine, such that the torso has no side seams. The manufacture of T-shirts has become highly automated and may include cutting fabric with a laser or a water jet. T-shirts are inexpensive to produce and are often part of fast fashi ...
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Crystal Violet Lactone Reaction
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, consisting of flat faces with specific, characteristic orientations. The scientific study of crystals and crystal formation is known as crystallography. The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification. The word ''crystal'' derives from the Ancient Greek word (), meaning both "ice" and "rock crystal", from (), "icy cold, frost". Examples of large crystals include snowflakes, diamonds, and table salt. Most inorganic solids are not crystals but polycrystals, i.e. many microscopic crystals fused together into a single solid. Polycrystals include most metals, rocks, ceramics, and ice. A third category of sol ...
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Microcapsule
Microencapsulation is a process in which tiny particles or droplets are surrounded by a coating to give small capsules, with useful properties. In general, it is used to incorporate food ingredients, enzymes, cells or other materials on a micro metric scale. Microencapsulation can also be used to enclose solids, liquids, or gases inside a micrometric wall made of hard or soft soluble film, in order to reduce dosing frequency and prevent the degradation of pharmaceuticals. In its simplest form, a microcapsule is a small sphere comprising a near-uniform wall enclosing some material. The enclosed material in the microcapsule is referred to as the core, internal phase, or fill, whereas the wall is sometimes called a shell, coating, or membrane. Some materials like lipids and polymers, such as alginate, may be used as a mixture to trap the material of interest inside. Most microcapsules have pores with diameters between a few nanometers and a few micrometers. Materials generally used ...
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Puget Sound Business Journal
American City Business Journals, Inc. (ACBJ) is an American newspaper publisher based in Charlotte, North Carolina. ACBJ publishes ''The Business Journals'', which contains local business news for 44 markets in the United States with each market's edition named for that market, and also publishes ''Hemmings Motor News'' and ''Inside Lacrosse''. The company is owned by Advance Publications and receives revenue from display advertising and classified advertising in its weekly newspaper and online advertising on its website and from a subscription business model. The bizjournals.com website, using the overarching online title ''The Business Journal'', contains local business news from various cities in the United States, along with an archive that contains more than 5 million business news articles published since 1996. it receives over 3.6 million readers each week. History American City Business Journals, Inc. was founded in 1982 by Mike K. Russell with the launch of the ''Kansa ...
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Benzotriazole
Benzotriazole (BTA) is a heterocyclic compound with the chemical formula . It can be viewed as the fusion of a benzene and triazole rings. It is a white solid, although impure samples can appear tan. It is used as a corrosion inhibitor for copper. Structure and synthesis : Benzotriazole features two fused rings. It can in principle exist as tautomers, but X-ray crystallography establishes the depicted structure. The N=N and HN-N distances are 1.306 and 1.340 Å. Benzotriazole can be prepared by the monodiazotization of o-Phenylenediamine, ''o''-phenylenediamine using sodium nitrite and acetic acid.Robert A. Smiley "Phenylene- and Toluenediamines" in ''Ullmann's Encyclopedia of Industrial Chemistry'', 2002, Wiley-VCH, Weinheim. Reactions Acid-base behavior BTA is a weak Bronsted acid with a pKa = 8.2. It is a weak Brønsted base, as indicated by the low pKa 0.1 μg/L. One source of this pollution is their use as anti-icing/deicing agents in airports. Benzotriazo ...
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Mood Ring
A mood ring is a finger ring that contains a thermochromic element, or "mood stone", that changes colors based on the temperature of the finger of the wearer. Finger temperature, as long as the ambient temperature is relatively constant, is significantly determined by peripheral blood flow. A mood ring contains liquid crystals that change color depending on the temperature. History The idea to use thermosensitive elements in jewelry first arose from the American jeweler Marvin Wernick in 1974 after reading a magazine article about the use of liquid crystal elements in medical thermometers. He found a compound that changed color from black to green, blue and deep blue in the range of 32–38 °C and in January 1975 developed a technique for using it in pendants and rings. Sales began in February. Wernick called the jewelry "magical", and his promotional materials claimed that the color of the pendant or ring is an indicator of the warmth of the wearer's character. Since Werni ...
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