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Hydroxylammonium Nitrate
Hydroxylammonium nitrate or hydroxylamine nitrate (HAN) is an inorganic compound with the chemical formula . It is a salt derived from hydroxylamine and nitric acid. In its pure form, it is a colourless hygroscopic solid. It has potential to be used as a rocket propellant either as a solution in monopropellants or bipropellants. Hydroxylammonium nitrate (HAN)-based propellants are a viable and effective solution for future "green" propellant-based missions, as it offers 50% higher performance for a given propellant tank compared to commercially used hydrazine. Properties The compound is a salt with separated hydroxyammonium and nitrate ions. Hydroxylammonium nitrate is unstable because it contains both a reducing agent (hydroxylammonium cation) and an oxidizer (nitrate), the situation being analogous to ammonium nitrate. It is usually handled as an aqueous solution with small amount of nitric acid as a stabilizer. The solution is corrosive and toxic, and may be carcinogenic. Solid ...
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Hydroxylammonium Sulfate
Hydroxylammonium sulfate is the inorganic compound with the formula H3OHsub>2SO4. A colorless solid, it is the sulfate salt of hydroxylamine. It is primarily used as an easily handled form of hydroxylamine, which is a volatile liquid. Production Hydroxylammonium sulfate is prepared industrially by protonation of hydroxylamine. The latter is produced by the hydrogenation of nitric oxide using a platinum catalyst: : Another route to is the Raschig process: aqueous ammonium nitrite is reduced by and at 0 °C to yield a hydroxylamido-''N'',''N''-disulfonate anion:: : This ammonium hydroxylamine disulfonate anion is then hydrolyzed to give hydroxylammonium sulfate: : Applications Almost all hydroxylamine and its salts are used to make precursors to nylons via cyclohexanone oxime. Many aldehydes and ketones undergo the same conversion to oximes. carboxylic acids and their derivatives (e.g. esters) convert to hydroxamic acids. Isocyanates to N-hydroxyureas. Nitriles react ...
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Monopropellant
Monopropellants are propellants consisting of chemicals that release energy through exothermic chemical decomposition. The molecular bond energy of the monopropellant is released usually through use of a catalyst. This can be contrasted with bipropellants that release energy through the chemical reaction between an oxidizer and a fuel. While stable under defined storage conditions, monopropellants decompose very rapidly under certain other conditions to produce a large volume of its own energetic (hot) gases for the performance of mechanical work. Although solid deflagrants such as nitrocellulose, the most commonly used propellant in firearms, could be thought of as monopropellants, the term is usually reserved for liquids in engineering literature. Uses The most common use of monopropellants is in low-impulse monopropellant rocket motors, such as reaction control thrusters, the usual propellant being hydrazine, p. 230 which is generally decomposed by exposure to an irid ...
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Nuclear Reprocessing
Nuclear reprocessing is the chemical separation of fission products and actinides from spent nuclear fuel. Originally, reprocessing was used solely to extract plutonium for producing nuclear weapons. With commercialization of nuclear power, the reprocessed plutonium was recycled back into MOX nuclear fuel for thermal reactors. The reprocessed uranium, also known as the spent fuel material, can in principle also be re-used as fuel, but that is only economical when uranium supply is low and prices are high. Nuclear reprocessing may extend beyond fuel and include the reprocessing of other nuclear reactor material, such as Zircaloy cladding. The high radioactivity of spent nuclear material means that reprocessing must be highly controlled and carefully executed in advanced facilities by specialized personnel. Numerous processes exist, with the chemical based PUREX process dominating. Alternatives include heating to drive off volatile elements, burning via oxidation, and fluoride vola ...
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Innovative Satellite Technology Demonstration-1
The Innovative Satellite Technology Demonstration Program is a series of spacecraft missions for testing technology and ideas put forward by universities and private companies. The program demonstrates various experimental devices and technology in space by providing flight opportunities. It is managed by the JAXA Research and Development Directorate. According to JAXA, the goal of this program is to test high risk, innovative technology that will lead to the space industry gaining competitiveness in the international field. Innovative Satellite Technology Demonstration-1 Innovative Satellite Technology Demonstration-1 was the first mission in the Innovative Satellite Technology Demonstration Program. The mission included several spacecraft, the largest being RAPIS-1, along with six smaller satellites. The call for proposals was announced in 2015, and selection results were announced in February 2016. A total of 14 projects were selected; however a proposal by IHI Corporation, t ...
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China Aerospace Science And Technology Corporation
The China Aerospace Science and Technology Corporation (CASC) is a main contractor for the Chinese space program. It is state-owned and has subsidiaries which design, develop and manufacture a range of spacecraft, launch vehicles, and ground equipment. It also has a division for strategic and tactical missile systems. History CASC was officially established in July 1999 as part of a Chinese government reform drive, having previously been one part of the former China Aerospace Corporation. Various incarnations of the program date back to 1956. Along with space and defense manufacture, CASC also produces machinery, chemicals, communications Communication is commonly defined as the transmission of information. Its precise definition is disputed and there are disagreements about whether Intention, unintentional or failed transmissions are included and whether communication not onl ... equipment, transportation equipment, computers, medical care products and Natural environm ...
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Triethanolamine
Triethanolamine, or TEOA, is an organic compound with the chemical formula . It is a colourless, viscous liquid. It is both a tertiary amine and a triol. A triol is a molecule with three alcohol groups. Approximately 150,000 tonnes were produced in 1999. It is a colourless compound although samples may appear yellow because of impurities. Production Triethanolamine is produced from the reaction of ethylene oxide with aqueous ammonia, also produced are ethanolamine and diethanolamine. The ratio of the products can be controlled by changing the stoichiometry of the reactants. : Applications Triethanolamine is used primarily in making surfactants, such as for emulsifier. It is a common ingredient in formulations used for both industrial and consumer products. The triethanolamine neutralizes fatty acids, adjusts and buffers the pH, and solubilizes oils and other ingredients that are not completely soluble in water. Triethanolammonium salts in some cases are more soluble ...
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Glycine
Glycine (symbol Gly or G; ) is an amino acid that has a single hydrogen atom as its side chain. It is the simplest stable amino acid. Glycine is one of the proteinogenic amino acids. It is encoded by all the codons starting with GG (GGU, GGC, GGA, GGG). Glycine disrupts the formation of alpha-helices in secondary protein structure. Its small side chain causes it to favor random coils instead. Glycine is also an inhibitory neurotransmitter – interference with its release within the spinal cord (such as during a '' Clostridium tetani'' infection) can cause spastic paralysis due to uninhibited muscle contraction. It is the only achiral proteinogenic amino acid. It can fit into both hydrophilic and hydrophobic environments, due to its minimal side chain of only one hydrogen atom. History and etymology Glycine was discovered in 1820 by French chemist Henri Braconnot when he hydrolyzed gelatin by boiling it with sulfuric acid. He originally called it "sugar of ...
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Specific Impulse
Specific impulse (usually abbreviated ) is a measure of how efficiently a reaction mass engine, such as a rocket engine, rocket using propellant or a jet engine using fuel, generates thrust. In general, this is a ratio of the ''Impulse (physics), impulse'', i.e. change in momentum, ''per mass'' of propellant. This is equivalent to "thrust per massflow". The resulting unit is equivalent to velocity. If the engine expels mass at a constant exhaust velocity v_e then the thrust will be \mathbf = v_e \frac . If we integrate over time to get the total change in momentum, and then divide by the mass, we see that the specific impulse is equal to the exhaust velocity v_e . In practice, the specific impulse is usually lower than the actual physical exhaust velocity inefficiencies in the rocket, and thus corresponds to an "effective" exhaust velocity. That is, the specific impulse I_ in units of velocity *is defined by* : \mathbf = I_ \frac , where \mathbf is the average thrust. ...
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Green Propellant Infusion Mission
The Green Propellant Infusion Mission (GPIM) was a NASA technology demonstrator project that tested a less toxic and higher performance/efficiency chemical propellant for next-generation launch vehicles and CubeSat spacecraft. When compared to the present high-thrust and high-performance industry standard for orbital maneuvering systems, which for decades, have exclusively been reliant upon toxic hydrazine based propellant formulations, the "greener" hydroxylammonium nitrate (HAN) monopropellant offers many advantages for future satellites, including longer mission durations, additional maneuverability, increased payload space and simplified launch processing. The GPIM was managed by NASA's Marshall Space Flight Center in Huntsville, Alabama, and was part of NASA's Technology Demonstration Mission Program within the Space Technology Mission Directorate. The Green Propellant Infusion Mission launched aboard a SpaceX Falcon Heavy rocket on 25 June 2019, on a test mission called ...
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Iridium
Iridium is a chemical element; it has the symbol Ir and atomic number 77. This very hard, brittle, silvery-white transition metal of the platinum group, is considered the second-densest naturally occurring metal (after osmium) with a density of as defined by experimental X-ray crystallography. 191Ir and 193Ir are the only two naturally occurring isotopes of iridium, as well as the only stable isotopes; the latter is the more abundant. It is one of the most corrosion-resistant metals, even at temperatures as high as . Iridium was discovered in 1803 in the acid-insoluble residues of platinum ores by the English chemist Smithson Tennant. The name ''iridium'', derived from the Greek word ''iris'' (rainbow), refers to the various colors of its compounds. Iridium is one of the rarest elements in Earth's crust, with an estimated annual production of only in 2023. The dominant uses of iridium are the metal itself and its alloys, as in high-performance spark plugs, crucibles for ...
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Palladium
Palladium is a chemical element; it has symbol Pd and atomic number 46. It is a rare and lustrous silvery-white metal discovered in 1802 by the English chemist William Hyde Wollaston. He named it after the asteroid Pallas (formally 2 Pallas), which was itself named after the epithet of the Greek goddess Athena, acquired by her when she slew Pallas. Palladium, platinum, rhodium, ruthenium, iridium and osmium form together a group of elements referred to as the platinum group metals (PGMs). They have similar chemical properties, but palladium has the lowest melting point and is the least dense of them. More than half the supply of palladium and its congener platinum is used in catalytic converters, which convert as much as 90% of the harmful gases in automobile exhaust (hydrocarbons, carbon monoxide, and nitrogen dioxide) into nontoxic substances (nitrogen, carbon dioxide and water vapor). Palladium is also used in electronics, dentistry, medicine, hydrogen purification ...
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Silver
Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. Silver is found in the Earth's crust in the pure, free elemental form ("native metal, native silver"), as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite. Most silver is produced as a byproduct of copper, gold, lead, and zinc Refining (metallurgy), refining. Silver has long been valued as a precious metal. Silver metal is used in many bullion coins, sometimes bimetallism, alongside gold: while it is more abundant than gold, it is much less abundant as a native metal. Its purity is typically measured on a per-mille basis; a 94%-pure alloy is described as "0.940 fine". As one of the seven metals of antiquity, silver has had an enduring role in most human cultures. Other than in currency and as an in ...
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