Humulus Lupulus Hopfendolde-mit-hopfengarten
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Humulus Lupulus Hopfendolde-mit-hopfengarten
''Humulus'', or hop, is a small genus of flowering plants in the family (biology), family Cannabaceae. The hop is native plant, native to temperateness, temperate regions of the Northern Hemisphere. Hops are the female flowers (seed cones, strobiles) of the hop species ''Humulus lupulus, H. lupulus''; as a main flavor and aroma ingredient in many beer styles, ''H. lupulus'' is widely cultivated for use by the brewing industry. Description Although frequently referred to in American literature as the hops "vine", it is technically a bine (botany), bine; unlike vines, which use tendrils, suckers, and other appendages for attaching themselves, bines have stout stems with stiff hairs to aid in climbing. In British literature the term "vine" is generally reserved for the grape genus ''Vitis''. ''Humulus'' is described as a twining perennial plant, perennial herbaceous plant which sends up new shoots in early spring and dies back to the cold-hardy rhizome in autumn. Hop shoots grow ver ...
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Humulus Lupulus
''Humulus lupulus'', the common hop or hops, is a species of flowering plant in the hemp family, Cannabaceae. It is a perennial, herbaceous climbing plant which sends up new shoots in early spring and dies back to a cold-hardy rhizome in autumn. It is dioecious (having separate male and female plants) and native to West Asia, Europe and North America. As the female cone-shaped flowers (hops) are used to preserve and flavor beer, the species is widely cultivated for the brewing industry. Description ''Humulus lupulus'' is a perennial herbaceous plant up to tall, living up to 20 years. It has simple leaves with 3–5 deep lobes that can be opposite or alternate. The species is triggered by the longer summer days to flower, usually around July or August in the Northern Hemisphere. The plant is dioecious, with male and female flowers on separate plants. The fragrant flowers are wind-pollinated. The staminate (male) flowers do not have petals, while the pistillate (female) flowers ...
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Herbaceous Plant
Herbaceous plants are vascular plants that have no persistent woody stems above ground. This broad category of plants includes many perennials, and nearly all annuals and biennials. Definitions of "herb" and "herbaceous" The fourth edition of the '' Shorter Oxford English Dictionary'' defines "herb" as: # "A plant whose stem does not become woody and persistent (as in a tree or shrub) but remains soft and succulent, and dies (completely or down to the root) after flowering"; # "A (freq. aromatic) plant used for flavouring or scent, in medicine, etc.". (See: Herb) The same dictionary defines "herbaceous" as: # "Of the nature of a herb; esp. not forming a woody stem but dying down to the root each year"; # "BOTANY Resembling a leaf in colour or texture. Opp. scarious". Botanical sources differ from each other on the definition of "herb". For instance, the Hunt Institute for Botanical Documentation includes the condition "when persisting over more than one growing season, th ...
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Chalcone
Chalcone is the organic compound C6H5C(O)CH=CHC6H5. It is an α,β-unsaturated ketone. A variety of important biological compounds are known collectively as chalcones or chalconoids. They are widely known bioactive substances, fluorescent materials, and chemical intermediates. Chemical properties Chalcones have two absorption maxima at 280 nm and 340 nm. Biosynthesis Chalcones and chalconoids are synthesized in plants as secondary metabolites. The enzyme chalcone synthase, a type III polyketide synthase, is responsible for the biosynthesis of these compounds. The enzyme is found in all "higher" (vascular) and several "lower" ( non-vascular) plants. Laboratory synthesis Chalcone is usually prepared by an aldol condensation between benzaldehyde and acetophenone. : This reaction, which can be carried out without any solvent, is so reliable that it is often given as an example of green chemistry in undergraduate education. Potential pharmacology Chalcones and thei ...
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Prenylated
Prenylation (also known as isoprenylation or lipidation) is the addition of hydrophobic molecules to a protein or a biomolecule. It is usually assumed that prenyl groups (3-methylbut-2-en-1-yl) facilitate attachment to cell membranes, similar to lipid anchors like the GPI anchor, though direct evidence of this has not been observed. Prenyl groups (also called isoprenyl groups, having one hydrogen atom more than isoprene) have been shown to be important for protein–protein binding through specialized prenyl-binding domains. Protein prenylation Protein prenylation involves the transfer of either a farnesyl or a geranylgeranyl moiety to C-terminal cysteine(s) of the target protein. There are three enzymes that carry out prenylation in the cell, farnesyl transferase, Caax protease and geranylgeranyl transferase I. Farnesylation is a type of prenylation, a post-translational modification of proteins by which an isoprenyl group is added to a cysteine residue. It is an important ...
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Xanthohumol
Xanthohumol is a natural product found in the female inflorescences of ''Humulus lupulus'', also known as hops. This compound is also found in beer and belongs to a class of compounds that contribute to the bitterness and flavor of hops. Xanthohumol is a prenylated chalconoid, biosynthesized by a type III polyketide synthase (PKS) and subsequent modifying enzymes. Biosynthesis Xanthohumol is a prenylated chalconoid derived from a plant type III PKS, and is synthesized in the glandular trichromes of hop cones. Phenylalanine, L-Phenylalanine serves as the starting material, which is converted to cinnamic acid by the PLP-dependent Phenylalanine ammonia-lyase, phenylalanine ammonia lyase. Cinnamic acid is oxidized by Trans-cinnamate 4-monooxygenase, cinnamate-4-hydroxylase and loaded onto coenzyme A (CoA) by 4-Coumarate-CoA ligase, 4-coumarate CoA ligase to yield Coumaroyl-CoA, 4-hydroxy-cinnamoyl CoA, the starter unit for PKS extension. This molecule is extended three times with Mal ...
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Terpenophenolic
In organic chemistry, phenols, sometimes called phenolics, are a class of chemical compounds consisting of one or more hydroxyl groups (− O H) bonded directly to an aromatic hydrocarbon group. The simplest is phenol, . Phenolic compounds are classified as simple phenols or polyphenols based on the number of phenol units in the molecule. Phenols are both synthesized industrially and produced by plants and microorganisms. Properties Acidity Phenols are more acidic than typical alcohols. The acidity of the hydroxyl group in phenols is commonly intermediate between that of aliphatic alcohols and carboxylic acids (their pKa is usually between 10 and 12). Deprotonation of a phenol forms a corresponding negative phenolate ion or phenoxide ion, and the corresponding salts are called phenolates or phenoxides (aryloxides, according to the IUPAC Gold Book). Condensation with aldehydes and ketones Phenols are susceptible to electrophilic aromatic substitutions. Condensation with formal ...
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Vinylogy
In organic chemistry, vinylogy is the transmission of electronic effects through a conjugated organic bonding system. The concept was introduced in 1926 by Ludwig Claisen to explain the acidic properties of formylacetone and related ketoaldehydes. Formylacetone, technically , only exists in the ionized form or . Its adjectival form, vinylogous, is used to describe functional groups in which the standard moieties of the group are separated by a carbon–carbon double bond. For example, a carboxylic acid is defined as a carbonyl group () directly attached to a hydroxyl group (): O=C–OH. A vinylogous carboxylic acid has a vinyl unit (, vinylene) between the two groups that define the acid: O=C–C=C–OH. The usual resonance of a carboxylate can propagate through the alkene of a vinylogous carboxylate. Likewise, 3-dimethylaminoacrolein is the vinylogous-amide analog of dimethylformamide. Due to the transmission of electronic information through conjugation, ''vinylogous'' f ...
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Lupulone
Lupulone is an organic chemical compound with the molecular formula C26 H38 O4 and an appearance of a yellow powder which was historically used in beer brewing. History Since lupulone is found as a component of hops, the history of the compound can be traced back to 736 AD in southern Germany where hops plant were first cultivated. The commercial production of using lupulone in brewing was not until 1079 AD. The reason that lupulone was not utilized in beer brewing earlier on may be due to the fact that the hops plants has a bitter taste. However, brewers began to realize that beta acids of hops provided very little bitterness to the beer. Eventually, hops brewing with the use of lupulone made its way to the United States about 6 centuries later in 1629 after England introduced it. Synthesis A synthesis pathway of lupulone involves the alkenylation of 2-acylcyclohexane-1, 3, 5-triones with bromides and liquid ammonia in ether as a base, which yields 4,6,6-trialkenyl derivative ...
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Seed
In botany, a seed is a plant structure containing an embryo and stored nutrients in a protective coat called a ''testa''. More generally, the term "seed" means anything that can be Sowing, sown, which may include seed and husk or tuber. Seeds are the product of the ripened ovule, after the embryo sac is fertilization, fertilized by Pollen, sperm from pollen, forming a zygote. The embryo within a seed develops from the zygote and grows within the mother plant to a certain size before growth is halted. The formation of the seed is the defining part of the process of reproduction in seed plants (spermatophytes). Other plants such as ferns, mosses and marchantiophyta, liverworts, do not have seeds and use water-dependent means to propagate themselves. Seed plants now dominate biological Ecological niche, niches on land, from forests to grasslands both in hot and cold climates. In the flowering plants, the ovary ripens into a fruit which contains the seed and serves to disseminate ...
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Vegetative Reproduction
Vegetative reproduction (also known as vegetative propagation, vegetative multiplication or cloning) is a form of asexual reproduction occurring in plants in which a new plant grows from a fragment or cutting of the parent plant or specialized reproductive structures, which are sometimes called vegetative propagules. Many plants naturally reproduce this way, but it can also be induced artificially. Horticulturists have developed asexual propagation techniques that use vegetative propagules to replicate plants. Success rates and difficulty of propagation vary greatly. Monocotyledons typically lack a vascular cambium, making them more challenging to propagate. Plant propagation Plant propagation is the process of plant reproduction of a species or cultivar, and it can be sexual or asexual. It can happen through the use of vegetative parts of the plants, such as leaves, stems, and roots to produce new plants or through growth from specialized vegetative plant parts. W ...
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Dioecious
Dioecy ( ; ; adj. dioecious, ) is a characteristic of certain species that have distinct unisexual individuals, each producing either male or female gametes, either directly (in animals) or indirectly (in seed plants). Dioecious reproduction is biparental reproduction. Dioecy has costs, since only the female part of the population directly produces offspring. It is one method for excluding self-fertilization and promoting allogamy (outcrossing), and thus tends to reduce the expression of recessive deleterious mutations present in a population. Plants have several other methods of preventing self-fertilization including, for example, dichogamy, herkogamy, and self-incompatibility. In zoology In zoology, dioecy means that an animal is either male or female, in which case the synonym gonochory is more often used. Most animal species are gonochoric, almost all vertebrate species are gonochoric, and all bird and mammal species are gonochoric. Dioecy may also describe colonies ...
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