Hans Meerwein
Hans Meerwein (May 20, 1879 in Hamburg, Germany – October 24, 1965 in Marburg, Germany) was a German chemist. Several reactions and reagents bear his name, most notably the Meerwein–Ponndorf–Verley reduction, the Wagner–Meerwein rearrangement, the Meerwein arylation reaction, and Meerwein's salt. Life and work His father was the architect, Wilhelm Emil Meerwein. He originally trained to be a chemistry technician or 'chemotechnician' at the Fresenius University of Applied Sciences (between 1898 and 1900) before studying for a chemistry degree at the University of Bonn. After finishing his PhD with Richard Anschütz he worked at the University of Berlin, before returning to Bonn where he became professor in 1914. From 1922 till 1928 he was professor for organic chemistry at the University of Königsberg. The last change in his academic career was to the University of Marburg. The war devastated the Institute and Meerwein was planning the rebuilding which was finis ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Hamburg
Hamburg (, ; ), officially the Free and Hanseatic City of Hamburg,. is the List of cities in Germany by population, second-largest city in Germany after Berlin and List of cities in the European Union by population within city limits, 7th-largest in the European Union with a population of over 1.9 million. The Hamburg Metropolitan Region has a population of over 5.1 million and is the List of EU metropolitan areas by GDP, eighth-largest metropolitan region by GDP in the European Union. At the southern tip of the Jutland Peninsula, Hamburg stands on the branching River Elbe at the head of a estuary to the North Sea, on the mouth of the Alster and Bille (Elbe), Bille. Hamburg is one of Germany's three city-states alongside Berlin and Bremen (state), Bremen, and is surrounded by Schleswig-Holstein to the north and Lower Saxony to the south. The Port of Hamburg is Germany's largest and Europe's List of busiest ports in Europe, third-largest, after Port of Rotterdam, Rotterda ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Isobornyl
Borneol is a bicyclic organic compound and a terpene derivative. The hydroxyl group in this compound is placed in an '' endo'' position. The exo diastereomer is called isoborneol. Being chiral, borneol exists as enantiomers, both of which are found in nature: ''d''-borneol (also written (+)-borneol) and ''l''-borneol (or (−)-borneol). Reactions Borneol is oxidized to the ketone (camphor). Occurrence The compound was named in 1842 by the French chemist Charles Frédéric Gerhardt. Borneol can be found in several species of '' Heterotheca'', '' Artemisia'', ''Rosmarinus officinalis'' (rosemary) ''Dipterocarpaceae'', ''Blumea balsamifera'' and ''Kaempferia galanga''. It is one of the chemical compounds found in castoreum. This compound is gathered from the beaver's plant food. Synthesis Borneol can be synthesized by reduction of camphor by the Meerwein–Ponndorf–Verley reduction (a reversible process). Industrially, a racemic mixture of camphor is used, leading to a rac ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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1965 Deaths
Events January–February * January 14 – The First Minister of Northern Ireland and the Taoiseach of the Republic of Ireland meet for the first time in 43 years. * January 20 ** Lyndon B. Johnson is Second inauguration of Lyndon B. Johnson, sworn in for a full term as President of the United States. ** Indonesian President Sukarno announces the withdrawal of the Indonesian government from the United Nations. * January 29 – Tampere Ice Stadium, Hakametsä, the first ice rink of Finland, is inaugurated in Tampere. * January 30 – The Death and state funeral of Winston Churchill, state funeral of Sir Winston Churchill takes place in London with the largest assembly of dignitaries in the world until the 2005 funeral of Pope John Paul II. * February 4 – Trofim Lysenko is removed from his post as director of the Institute of Genetics at the Russian Academy of Sciences, Academy of Sciences in the Soviet Union. Lysenkoism, Lysenkoist theories are now tr ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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1879 Births
Events January * January 1 ** The Specie Resumption Act takes effect. The United States Note is valued the same as gold, for the first time since the American Civil War. ** Brahms' Violin Concerto is premiered in Leipzig with Joseph Joachim as soloist and the composer conducting. * January 11 – The Anglo-Zulu War begins. * January 22 – Anglo-Zulu War – Battle of Isandlwana: A force of 1,200 British soldiers is wiped out by over 20,000 Zulu warriors. * January 23 – Anglo-Zulu War – Battle of Rorke's Drift: Following the previous day's defeat, a smaller British force of 140 successfully repels an attack by 4,000 Zulus. February * February 3 – Mosley Street in Newcastle upon Tyne (England) becomes the world's first public highway to be lit by the electric incandescent light bulb invented by Joseph Swan. * February 8 – At a meeting of the Royal Canadian Institute, engineer and inventor Sandford Fleming first proposes the global ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Otto Hahn Prize
The Otto Hahn Prize is awarded biennially jointly by the Society of German Chemists (), the German Physical Society () and the city of Frankfurt am Main for outstanding achievement in the field of chemistry, physics or applied engineering science. It was established in 2005 by the merger of the previous Otto Hahn Prize for Chemistry and Physics and the Otto Hahn Prize of the City of Frankfurt am Main. The award is presented in the St. Paul's Church, Frankfurt am Main. The award named after the German nuclear scientist and Nobel laureate Otto Hahn and consists of a gold medal and a prize of 50,000 euros. It is awarded alternatively for Chemistry and Physics. Recipients: Otto Hahn Prize for Chemistry and Physics *1955: Lise Meitner, Heinrich Otto Wieland, Heinrich Wieland *1959: Hans Meerwein *1962: Manfred Eigen *1965: Erich Hückel *1967: Georg Wittig *1974: Friedrich Hund *1979: Rolf Huisgen *1982: Walter Greiner *1986: Heinz Maier-Leibnitz *1989: Rudolf Hoppe *1998: Dieter Oest ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Josef Houben
Heinrich Hubert Maria Josef Houben (27 October 1875, in Waldfeucht (Rheinland) Germany – 28 June 1940, in Tübingen) was a German chemist. He made achievements within ketone synthesis, terpenes, and camphor studies. After being wounded several times on the front lines in World War I, Houben was made head of the war laboratory. He improved the Hoesch reaction which is now normally called Houben-Hoesch reaction. Houben organized and made a major rework of the book Methods of Organic Chemistry which is now referred to as Houben-Weyl Methods of Organic Chemistry. Life Houben studied at the University of Bonn and changed his subjects from mathematics and astronomy to chemistry under the influence of August Kekulé. He received his Ph.D. for work with Julius Bredt in 1898, and they collaborated on the initial 1902 publication of what became known as Bredt's Rule. After some time at the University of Aachen and University of Bonn Houben joined the laboratory of Emil Fischer at the ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Hydride
In chemistry, a hydride is formally the anion of hydrogen (H−), a hydrogen ion with two electrons. In modern usage, this is typically only used for ionic bonds, but it is sometimes (and has been more frequently in the past) applied to all chemical compound, compounds containing covalent bond, covalently bound H atoms. In this broad and potentially archaic sense, water (H2O) is a hydride of oxygen, ammonia is a hydride of nitrogen, etc. In covalent compounds, it implies hydrogen is attached to a less electronegative chemical element, element. In such cases, the H centre has nucleophilic character, which contrasts with the protic character of acids. The hydride anion is very rarely observed. Almost all of the elements form Binary compounds of hydrogen, binary compounds with hydrogen, the exceptions being helium, He, neon, Ne, argon, Ar, krypton, Kr, promethium, Pm, osmium, Os, iridium, Ir, radon, Rn, francium, Fr, and radium, Ra. exotic atom#exotic molecules, Exotic molecules ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Isobornyl Chloride
Borneol is a bicyclic organic compound and a terpene derivative. The hydroxyl group in this compound is placed in an '' endo'' position. The exo diastereomer is called isoborneol. Being chiral, borneol exists as enantiomers, both of which are found in nature: ''d''-borneol (also written (+)-borneol) and ''l''-borneol (or (−)-borneol). Reactions Borneol is oxidized to the ketone (camphor). Occurrence The compound was named in 1842 by the French chemist Charles Frédéric Gerhardt. Borneol can be found in several species of '' Heterotheca'', '' Artemisia'', ''Rosmarinus officinalis'' (rosemary) ''Dipterocarpaceae'', ''Blumea balsamifera'' and ''Kaempferia galanga''. It is one of the chemical compounds found in castoreum. This compound is gathered from the beaver's plant food. Synthesis Borneol can be synthesized by reduction of camphor by the Meerwein–Ponndorf–Verley reduction (a reversible process). Industrially, a racemic mixture of camphor is used, leading to a rac ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Racemization
In chemistry, racemization is a conversion, by heat or by chemical reaction, of an optically active compound into a racemic (optically inactive) form. This creates a 1:1 molar ratio of enantiomers and is referred to as a racemic mixture (i.e. contain equal amount of (+) and (−) forms). Plus and minus forms are called Dextrorotation and levorotation. The D and L enantiomers are present in equal quantities, the resulting sample is described as a racemic mixture or a racemate. Racemization can proceed through a number of different mechanisms, and it has particular significance in pharmacology inasmuch as different enantiomers may have different pharmaceutical effects. Stereochemistry Chiral molecules have two forms (at each point of asymmetry), which differ in their optical characteristics: The ''levorotatory form'' (the ''(−)-form'') will rotate counter-clockwise on the plane of polarization of a beam of light, whereas the ''dextrorotatory'' form (the ''(+)-form'') will rotate ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Carbocation
Carbocation is a general term for ions with a positively charged carbon atom. In the present-day definition given by the IUPAC, a carbocation is any even-electron cation with significant partial positive charge on a carbon atom. They are further classified in two main categories according to the coordination number of the charged carbon: three in the carbenium ions and five in the carbonium ions. Among the simplest carbocations are the methenium (a carbenium ion), methanium (a carbonium ion), acylium ions , and Vinyl cation, vinyl cations. Until the early 1970s, carbocations were called ''carbonium ions''. This nomenclature was proposed by George Andrew Olah, G. A. Olah. Carbonium ions, as originally defined by Olah, are characterized by a Three-center two-electron bond, three-center two-electron delocalized bonding scheme and are essentially synonymous with so-called 'non-classical carbocations', which are carbocations that contain bridging C–C or C–H σ-bonds. However ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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University Of Berlin
The Humboldt University of Berlin (, abbreviated HU Berlin) is a public research university in the central borough of Mitte in Berlin, Germany. The university was established by Frederick William III on the initiative of Wilhelm von Humboldt, Johann Gottlieb Fichte and Friedrich Daniel Ernst Schleiermacher as the University of Berlin () in 1809, and opened in 1810. From 1828 until its closure in 1945, it was named the (Royal) Friedrich Wilhelm University of Berlin (FWU Berlin; ). During the Cold War, the university found itself in East Berlin and was ''de facto'' split in two when the Free University of Berlin opened in West Berlin. The university received its current name in honour of Alexander and Wilhelm von Humboldt in 1949. The university is divided into nine faculties including its medical school shared with the Freie Universität Berlin. The university has a student enrollment of around 35,000 students, and offers degree programs in some 171 disciplines from und ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |