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Gadolinium Gallium Garnet
Gadolinium gallium garnet (GGG, ) is a synthetic crystalline material of the garnet group, with good mechanical, thermal, and optical properties. It is typically colorless. It has a cubic lattice, a density of 7.08 g/cm3 and its Mohs hardness is variously noted as 6.5 and 7.5. Its crystals are produced with the Czochralski method. During production, various dopants can be added for colour modification. The material is also used in fabrication of various optical components and as a substrate material for magneto–optical films ( magnetic bubble memory).J. F. Greber "Gallium and Gallium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2012 Wiley-VCH, Weinheim. It also finds use in jewelry as a diamond simulant. GGG can also be used as a seed substrate for the growth of other garnets such as yttrium iron garnet. Another interesting aspect to this synthetic gemstone is that it exhibits both fluorescence under UV, and Phosphorescence (glow-in-the-dark) properties. See ...
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Gemological Institute Of America
The Gemological Institute of America (GIA) is a nonprofit institute based in Carlsbad, California. It is dedicated to research and education in the field of gemology and the jewelry arts. Founded in 1931, GIA's mission is to protect buyers and sellers of gemstones by setting and maintaining the standards used to evaluate gemstone quality. The institute does so through research, gem identification, diamond grading services, and a variety of educational programs. Through its library and subject experts, GIA acts as a resource of gem and jewelry information for the trade, the public and media outlets. In 1953 the GIA developed its International Diamond Grading System and the "four Cs" ( cut, clarity, color, and carat weight) as a standard to compare and evaluate the quality of diamonds. As of 2024, the institute is headquartered in Carlsbad, California, and operates in 13 countries, with 11 campuses, 9 laboratories, and 4 research centers. History GIA was founded in the 1920s by ...
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Phosphorescence
Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light (radiation) of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluorescence, a phosphorescent material does not immediately reemit the radiation it absorbs. Instead, a phosphorescent material absorbs some of the radiation energy and reemits it for a much longer time after the radiation source is removed. In a general sense, there is no distinct boundary between the emission times of fluorescence and phosphorescence (i.e.: if a substance glows under a black light it is generally considered fluorescent, and if it glows in the dark it is often simply called phosphorescent). In a modern, scientific sense, the phenomena can usually be classified by the three different mechanisms that produce the light, and the typical timescales during which those mechanisms emit light. Whereas fluorescent materials stop emitti ...
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Gadolinium Compounds
Gadolinium is a chemical element; it has symbol Gd and atomic number 64. It is a silvery-white metal when oxidation is removed. Gadolinium is a malleable and ductile rare-earth element. It reacts with atmospheric oxygen or moisture slowly to form a black coating. Gadolinium below its Curie point of is ferromagnetic, with an attraction to a magnetic field higher than that of nickel. Above this temperature it is the most paramagnetic element. It is found in nature only in an oxidized form. When separated, it usually has impurities of the other rare earths because of their similar chemical properties. Gadolinium was discovered in 1880 by Jean Charles de Marignac, who detected its oxide by using spectroscopy. It is named after the mineral gadolinite, one of the minerals in which gadolinium is found, itself named for the Finnish chemist Johan Gadolin. Pure gadolinium was first isolated by the chemist Félix Trombe in 1935. Gadolinium possesses unusual metallurgical properties, to t ...
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Gallium Compounds
Gallium compounds are compounds containing the element gallium. These compounds are found primarily in the +3 oxidation state. The +1 oxidation state is also found in some compounds, although it is less common than it is for gallium's heavier congeners indium and thallium. For example, the very stable GaCl2 contains both gallium(I) and gallium(III) and can be formulated as GaIGaIIICl4; in contrast, the monochloride is unstable above 0 °C, disproportionating into elemental gallium and gallium(III) chloride. Compounds containing Ga–Ga bonds are true gallium(II) compounds, such as GaS (which can be formulated as Ga24+(S2−)2) and the dioxan complex Ga2Cl4(C4H8O2)2.Greenwood and Earnshaw, p. 240 There are also compounds of gallium with negative oxidation states, ranging from −5 to −1, most of these compounds being magnesium gallides (MgxGay). Aqueous chemistry Strong acids dissolve gallium, forming gallium(III) salts such as (gallium nitrate). Aqueous solutions o ...
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Oxides
An oxide () is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of −2) of oxygen, an O2− ion with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials considered pure elements often develop an oxide coating. For example, aluminium foil develops a thin skin of (called a passivation layer) that protects the foil from further oxidation.Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford:Butterworth-Heinemann. . Stoichiometry Oxides are extraordinarily diverse in terms of stoichiometries (the measurable relationship between reactants and chemical equations of an equation or reaction) and in terms of the structures of each stoichiometry. Most elements form oxides of more than one stoichiometry. A well known example is carbon monoxide and carbon dioxide.Greenwood, N. N.; & Earnshaw, A. (1 ...
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Synthetic Minerals
Synthetic may refer to: Science * Synthetic biology * Synthetic chemical or compound, produced by the process of chemical synthesis * Synthetic elements, chemical elements that are not naturally found on Earth and therefore have to be created in experiments * Synthetic organic compounds synthetic chemical compounds based on carbon (organic compounds). * Synthetic peptide * Synthetic population * Synthetic population (biology) Industry * Synthetic fuel * Synthetic oil * Synthetic marijuana * Synthetic diamond * Synthetic fibers, cloth or other material made from other substances than natural (animal, plant) materials Other * Synthetic position, a concept in finance * Synthetic-aperture radar, a type or radar * Analytic–synthetic distinction, in philosophy * Synthetic language in linguistics, inflected or agglutinative languages * Synthetic intelligence a term emphasizing that true intelligence expressed by computing machines is not an imitation or "artificial." * Synthetic ...
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Yttrium Aluminium Garnet
Yttrium aluminium garnet (YAG, Yttrium, Y3Aluminium, Al5Oxygen, O12) is a synthetic crystalline material of the garnet group. It is a Crystal system, cubic yttrium aluminium oxide phase, with other examples being YAlO3 (YAP) in a Crystal system, hexagonal or an orthorhombic, perovskite-like form, and the monoclinic Y4Al2O9 (YAM). Due to its broad optical transparency, low internal stress, high hardness, chemical and heat resistance, YAG is used for a variety of optics. Its lack of birefringence (unlike sapphire) makes it an interesting material for high-energy/high-power laser systems. Laser damage threshold, Laser damage levels of YAG ranged from 1.1 to 2.2 kJ/cm2 (1064 nm, 10 ns). YAG, like garnet and sapphire, has no uses as a laser medium when pure. However, after being doped with an appropriate ion, YAG is commonly used as a host material in various solid-state lasers. Rare earth elements such as neodymium and erbium can be doping (semiconductors), doped into ...
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Terbium Gallium Garnet
Terbium gallium garnet (TGG) is a kind of synthetic garnet, with the chemical composition . This is a Faraday rotator material with excellent transparency properties and is very resistant to laser damage. TGG can be used in optical isolators for laser systems, in optical circulators for fiber optic systems, in optical modulators, and in current and magnetic field sensors. TGG has a high Verdet constant which results in the Faraday effect. The Verdet constant increases substantially as the mineral approaches cryogenic temperatures. The highest Verdet constants are found in terbium doped dense flint glasses or in crystals of TGG. The Faraday effect is chromatic (i.e. it depends on wavelength) and therefore the Verdet constant is quite a strong function of wavelength. At 632 nm, the Verdet constant for TGG is reported to be , whereas at 1064 nm it falls to . This behavior means that the devices manufactured with a certain degree of rotation at one wavelength, will prod ...
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Micro-pulling-down
The micro-pulling-down (μ-PD) method is a crystal growth technique based on continuous transport of the melted substance through micro-channel(s) made in a crucible bottom. Continuous solidification of the melt is progressed on a liquid/solid interface positioned under the crucible. In a steady state, both the melt and the crystal are pulled-down with a constant (but generally different) velocity. Many different types of crystal are grown by this technique, including Y3Al5O12, Si, Si-Ge, LiNbO3, α-Al2O3, Y2O3, Sc2O3, LiF, CaF2, BaF2, etc. Crystal growth routine Standard routine procedure used in the growth of most of μ-PD crystals is well developed. The general stages of the growths include: * Charging of the crucible with starting materials (mixture of powders) * Heating of the crucible until starting materials in the crucible are completely melted * Upward displacement of the seed until its contact with the meniscus or crucible * Formation of the meniscus and ...
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Ultraviolet
Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of the total electromagnetic radiation output from the Sun. It is also produced by electric arcs, Cherenkov radiation, and specialized lights, such as mercury-vapor lamps, tanning lamps, and black lights. The photons of ultraviolet have greater energy than those of visible light, from about 3.1 to 12  electron volts, around the minimum energy required to ionize atoms. Although long-wavelength ultraviolet is not considered an ionizing radiation because its photons lack sufficient energy, it can induce chemical reactions and cause many substances to glow or fluoresce. Many practical applications, including chemical and biological effects, are derived from the way that UV radiation can interact with organic molecules. The ...
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Crystal
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, consisting of flat faces with specific, characteristic orientations. The scientific study of crystals and crystal formation is known as crystallography. The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification. The word ''crystal'' derives from the Ancient Greek word (), meaning both "ice" and " rock crystal", from (), "icy cold, frost". Examples of large crystals include snowflakes, diamonds, and table salt. Most inorganic solids are not crystals but polycrystals, i.e. many microscopic crystals fused together into a single solid. Polycrystals include most metals, rocks, ceramics, and ice. A third cat ...
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Yttrium Iron Garnet
Yttrium iron garnet (YIG) is a kind of synthetic garnet, with chemical composition , or Y3Fe5O12. It is a ferrimagnetic material with a Curie temperature of 560  K. YIG may also be known as yttrium ferrite garnet, or as iron yttrium oxide or yttrium iron oxide, the latter two names usually associated with powdered forms. Production Several methods are utilized for synthesis of yttrium iron garnet each with their pros and cons. The solid-state reaction method is a traditional approach for YIG synthesis, involving the high-temperature firing of a mixture of yttrium and iron oxides. This cost-effective technique can produce pure YIG crystals but requires careful control of temperature and atmosphere to prevent impurities. Liquid phase epitaxy (LPE) is another key method, especially for creating thin YIG films with excellent uniformity. Ideal for optical and microwave devices, LPE enables precise film growth on substrates. However, its high equipment costs and complex proced ...
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